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141.
The mechanism of magnetic exchange interaction in an interesting CuII coordination polymer with the CuI2X2 (X = I or Br) moiety bridge is investigated by the calculations based on density functional theory combined with the broken-symmetry approach (DFT-BS). Surprisingly, different from the experiment results, the calculations reveal that the complex between the magnetic CuII centers has a fairly weak antiferromagnetic interaction for the long distance (∼10 Å). The analyses show of the molecular orbitals and the spin density distribution favor the very weak antiferromagnetic coupling interactions of the systems. 相似文献
142.
In this paper, we will propose a passive automatic exposure mechanism. Different from general automatic exposure mechanism, the passive exposure mechanism directly searches suitable exposure images through the content of images. As exposure is one of the main factors to successfully take pictures, how to find an accurate exposure value is an important issue. Passive automatic exposure is the new trend and key issue of image processing. We will experiment and prove that the method we propose is effective. 相似文献
143.
A useful pulse sequence for measuring long‐range C? H coupling constants (JC? H) named high resolution‐HMBC (HR‐HMBC) has been developed. In this pulse sequence, the J‐scaling pulse [(nt1)/2? 180° (H/C) ? (nt1)/2] is incorporated after the spin evolution period, and then followed by an 1H 180° pulse to reverse the magnetization of JC? H couplings. As a result, splittings of the cross peaks due to the long‐range JC? H are realigned with separations of nJC? H along the F1 dimension, and thus even the small long‐range JC? H values can easily be determined. The efficiency of measuring the long‐range JC? H using the proposed pulse sequences has been demonstrated in application to the complicated natural product, portmicin. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
144.
Cheman Cheng Xiaoqing Jin Vaikuong Sin 《高等学校计算数学学报(英文版)》2007,16(1):28-36
A matrix is said to be stable if the real parts of all the eigenvalues are negative. In this paper, for any matrix An, we discuss the stability properties of T. Chan's preconditioner cU(An) from the viewpoint of the numerical range. An application in numerical ODEs is also given. 相似文献
145.
Zhang Xiaolin 《International Journal of Infrared and Millimeter Waves》1992,13(4):559-568
Typical IR systems' sensitivity equations have been established for decades, these include the NETD equation for IR imaging systems, and the acquisition and tracking range equations for IR searching and tracking systems, but they only fit the specific or simplified conditions. For example, the NETD equation can only be used for systems tested under the standard condition. In the field application, we must deal with the noise equivalent radiance difference NELD, not the NETD, and give out its explicit equation for concrete calculation. For the range equation, when the small target, often called a point source, is not strong enouph, i. e., when the target contrast is seriously decreased, we must consider the unneglectable background effect. In this paper, we summarrize some more general and valuable IR systems' sensitivity equations, which can be used for the practical engineering analysis and projection effectively. 相似文献
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149.
This study examined intensity range as a function of elicitation task (reading and automatic speech sequences), musical training, and the interaction between task and musical training in 31 college students. The results indicated significant differences in loudness range by experiental task. Intensity range for the descending automatic sequence was significantly greater than that for the ascending and reading tasks. While the overall effect of musical training was nonsignificant, there was a significant interaction between task and training, with musicians having a significantly greater mean range on the ascending task. A comparison between ascending and descending tasks indicated a significant mean difference between lower limits and no significant mean difference between upper limits. The range for the reading probe was located approximately in the middle of the total available intensity range. 相似文献
150.