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51.
Point‐to‐Plane Nonhomogeneous Electric‐Field‐Induced Simultaneous Formation of Giant Unilamellar Vesicles (GUVs) and Lipid Tubes
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Chuntao Zhu Ying Zhang Yinan Wang Qingchuan Li Dr. Wei Mu Prof. Dr. Xiaojun Han 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(9):2906-2909
It is well‐known that homogeneous electric fields can be used to generate giant unilamellar vesicles (GUVs). Herein we report an interesting phenomenon of formation of GUVs and lipid tubes simultaneously using a nonhomogeneous electric field generated by point‐to‐plane electrodes. The underlying mechanism was analyzed using finite element analysis. The two forces play main roles, that is, the pulling force (F) to drag GUVs into lipid tubes induced by fluid flow, and the critical force (Fc) to prevent GUVs from deforming into lipid tubes induced by electric fields. In the center area underneath the needle electrode, the GUVs were found because F is less than Fc in that region, whereas in the edge area the lipid tubes were obtained because F is larger than Fc. The diffusion coefficient of lipid in the tubes was found to be 4.45 μm2 s?1 using a fluorescence recovery after photobleaching (FRAP) technique. The method demonstrated here is superior to conventional GUV or lipid tube fabrication methods, and has great potential in cell mimic or hollow material fabrication using GUVs and tubes as templates. 相似文献
52.
Vicari L 《The European physical journal. E, Soft matter》2002,9(4):335-340
We present a new pump probe laser beams configuration for the nonlinear optical characterization of microemulsions. We detect
the variation of the on-axis optical intensity of the probe beam as generated by the concentration profile induced in an optically
thin film of microemulsion by the pump beam. A mathematical model has been introduced to describe the phenomenon. The technique
allows the determination of both Kerr-like optical nonlinearity and time constants and, therefore, it gives information both
on cluster dimension and their shape. We discuss its application to WAD (water/AOT/decane, where AOT denotes sodium-bis-di-ethyl-sulfosuccinate)
with the application of a strong electric field of optical source. Comparison between theoretical predictions and experimental
results confirms the presence of giant optical nonlinearity in the absence of turbidity divergence. Chainlike shape of clusters,
of the kind already reported with the application of strong electric field, could justify this result.
Received 26 October 2002
RID="a"
ID="a"e-mail: vicari@na.infn.it 相似文献
53.
Koga T 《The European physical journal. E, Soft matter》2005,17(3):381-388
The formation of intramolecular micelles in copolymers with periodic sequence, where hydrophobic units (stickers) are periodically placed along the chain, is studied by using multicanonical Monte Carlo computer simulations for an off-lattice bead-rod model in three dimensions. With decreasing the temperature, a transition from random-coil conformations to micelles occurs and flower-type micelles are formed via the transition. The number of stickers forming a micelle core is limited by the excluded-volume effect of loop chains around micelle cores. By this effect, two intramolecular micelles are formed for long polymer chains with 60 bonds via the coil-to-micelle transition. By further decreasing the temperature, we find that another transition, i.e., a micelle-to-micelle transition, takes place. At this transition point, the two intramolecular micelles merge into one micelle. Furthermore, we extend the multicanonical MC method to study elastic properties of single polymer chains with strong attractive interactions under external force fields, and study how the intramolecular micellization affects the elastic property of single polymer chains. 相似文献
54.
We investigate the structural behavior of a poly(styrene)-block-poly(acrylic acid) diblock copolymer which forms hexagonally-packed PS cylinders (C-phase) in the melt state. The water dispersion of this structure provides hairy cylinders which comprise a PAA swollen cylindrical brush with a height h tunable via its degree of ionization and the ionic strength in the solution, and a water-free, PS cylindrical core of constant radius RC. Such system constitutes an out-of-equilibrium frustrated model system: the selective swelling of the PAA brush results in a frustration of the interface curvature, which the ratio h/RC allows to quantify. Upon heating at a temperature higher than the glass transition temperature of the PS core, the glassiness of the core is relieved and the mechanical constraints arising from the selective swelling of the structure can be relaxed: the cylinders undergo a cylinder-to-sphere transition upon annealing at high temperature, when above a frustration threshold h/RC 1.8. Thanks to a careful mapping of the transition diagram, an undulating cylindrical morphology (UC) is identified between unchanged cylinders ( h/RC
1.8) and spheres ( h/RC 2.0), which appears to result from a Rayleigh-like pearling instability of the copolymer cylinders. 相似文献
55.
56.
Menger FM Bian J Seredyuk VA 《Angewandte Chemie (International ed. in English)》2004,43(10):1265-1267
57.
58.
Self-assembled microarrays of attoliter molecular vessels 总被引:1,自引:0,他引:1
Stamou D Duschl C Delamarche E Vogel H 《Angewandte Chemie (International ed. in English)》2003,42(45):5580-5583
59.
Oelschlaeger C Buhler E Waton G Candau SJ 《The European physical journal. E, Soft matter》2003,11(1):7-20
The mixed micellization between the cationic gemini surfactant [ C12H25( CH3)2N+( C2H4) N+( CH3)2 C12H25•2Br-] and the cationic cetyltrimethylammonium bromide (CTAB) in 150 mM KBr solutions has been investigated. The variation of the
cmc of the mixtures, measured by surface tension experiments, with composition revealed synergism in micelle formation. T-Jump
and light scattering experiments performed in the vicinity of the crossover volume fraction showed the existence of two micellar
populations, possibly linear and toroidal micelles. Rheological and dynamic light scattering experiments allowed to fully
characterize the linear viscoelasticity of the mixtures. These measurements revealed synergistic gains in viscoelastic properties
with a maximum of the stress-relaxation time around the equimolar composition. These effects are ascribed to a progressive
intermicellar crosslinking resulting from a continuous increase of the end-cap energy with the 12-2-12 content in the mixture.
Received: 18 November 2002 / Accepted: 8 April 2003 / Published online: 27 May 2003
RID="a"
ID="a"e-mail: candau@fresnel.u-strasbg.fr 相似文献
60.
We studied the formation of actin scaffolds in giant vesicles of dimyristoylphosphatidylcholine (DMPC). Polymerization of
actin was induced at low ionic strength through ionophore-mediated influx of Mg2+ (2 mM). The spatial organization of the filamentous actin was visualized by confocal and epifluorescence microscopy as a
function of the filaments length and membrane composition, by including various amounts of cholesterol or lipids with neutral
and positively charged polyethyleneglycol headgroups (PEG lipopolymers). In vesicles of pure DMPC, the newly polymerized actin
adsorbs to the membrane and forms a thin shell. In the presence of 2.5 mol% lipopolymers or of cholesterol at a molar fraction
x = 0.37, formation of a thin adsorbed film is impeded. A fuzzy cortex is predominantly formed in vesicles of diameter d smaller than the filament persistence length ( d ⩽ 15μm) while for larger vesicles a homogeneous network formation is favoured in the bulk of the vesicle. The fuzzy-cortex
formation is interpreted as a consequence of the reduction of the bending energy if the actin filaments accumulate close to
the vesicle wall.
Received: 17 January 2002 / Accepted: 21 March 2003 / Published online: 24 April 2003
RID="a"
ID="a"e-mail: Laurent_Limozin@ph.tum.de 相似文献