用BP神经网络模型评价养殖区水域的富营养化——以湖州地区为例

根据养殖区水域富营养化程度主要影响因素和评价标准,用足够多的BP神经网络训练样本、检验样本和测试样本进行模拟学习,给出了区分养殖区富营养化程度的分界值,能够直观地进行不同等级富营养化程度的划分.所得到的神经网络模型具有较好的泛化能力和预测能力,减少了人为主观因素的影响,该模型有一定的客观性、通用性和实用性.实例分析表明,湖州地区养殖区外荡水域富营养化程度比较严重,处于富营养化和重富营养化状态.     

Homoclinic bifurcation and chaos control in MEMS resonators

The chaotic dynamics of a micromechanical resonator with electrostatic forces on both sides are investigated. Using the Melnikov function, an analytical criterion for homoclinic chaos in the form of an inequality is written in terms of the system parameters. Detailed numerical studies including basin of attraction, and bifurcation diagram confirm the analytical prediction and reveal the effect of parametric excitation amplitude on the system transition to chaos. The main result of this paper indicates that it is possible to reduce the electrostatically induced homoclinic and heteroclinic chaos for a range of values of the amplitude and the frequency of the parametric excitation. Different active controllers are applied to suppress the vibration of the micromechanical resonator system. Moreover, a time-varying stiffness is introduced to control the chaotic motion of the considered system. The techniques of phase portraits, time history, and Poincare maps are applied to analyze the periodic and chaotic motions.     

基于Kerr效应的微环谐振腔延时器件

对基于光学Kerr效应的微环谐振腔延时器件进行了研究.采用耦合模式理论计算了波导与微环谐振腔间的耦合系数,给出了所研究器件的材料及各层组分,提出不同阶数微环的情况下延时数值的控制方法.结果表明:微环谐振腔半径为300μm,波导截面尺寸为450×1 000nm2,在小于±5ps抖动的条件下,每个通道达到超过130ps的延时数值,同时延时带宽达20GHz,自由光谱范围达50GHz,工作波段在1 550nm附近,满足密集波分复用系统的要求.整个结构全光控制,且能耗不超过0.8dBm,响应速度达到ps量级,体积不超过3mm3,便于集成,满足多信道光学延时的要求,为全光通信网络中延时线的研究提供了参考.     

Laser performance and thermal lens of diode-pumped Nd,Y-codoped:SrF_2 single crystals

We demonstrate the laser performances of Nd, Y：SrF2 crystals with Nd＇3＋ concentrations of 0.15 and 0.43 at.%. The sample with 0.43 at.% Nd3＋ concentration yields a maximum output power of 1.023 W at 1056.9 nm with a slope efficiency of 53%. The focal length of the thermal lens is analyzed for the 0.15 at.% Nd3＋-doped crystal sample. An improved cavity is designed considering the thermal lens. The maximum output power is 464 mW at 1056.9 nm, with a slope efficiency of 36.1%. The wavelength is tuned within the range of 1049.74-1059.13 nm.     

WILDLIFE RESERVES,POPULATIONS, AND HUNTING OUTCOME WITH SMART WILDLIFE

We consider a hunting area and a wildlife reserve and answer the question: How does clever migration decision affect the social optimal and the private optimal hunting levels and population stocks? We analyze this in a model allowing for two‐way migration between hunting and reserve areas, where the populations’ migration decisions depend on both hunting pressure and relative population densities. In the social optimum a pure stress effect on the behavior of smart wildlife exists. This implies that the population level in the wildlife reserve tends to increase and the population level in the hunting area and hunting levels tend to decrease. On the other hand, the effect on stock tends to reduce the population in the wildlife reserve and increase the population in the hunting area and thereby also increase hunting. In the case of the private optimum, open‐access is assumed and we find that the same qualitative results arise when comparing a situation with and without stress effects, but of course at a higher level of hunting. We also show that when net social benefits of hunting dominate the net social benefits of populations, wildlife reserves are optimally placed in areas of low carrying capacity and vice versa.     

Hydrophilic interaction 10 microm I.D. porous layer open tubular columns for ultratrace glycan analysis by liquid chromatography-mass spectrometry

The sensitivity of glycan analysis using nano-liquid chromatography interfaced with electrospray ionization mass spectrometry (ESI-MS) increases with the decrease of the mobile phase flow rate, accompanied by reduced ion suppression. In this study, we describe the preparation and performance of high efficiency 10 microm I.D. amine-bonded poly(vinylbenzyl chloride-divinylbenzene) hydrophilic interaction (HILIC) porous layer open tubular (PLOT) columns operated at 20 nL/min for the separation and analysis of glycan mixtures. HILIC-PLOT columns with a uniform porous polymer layer were reproducibly prepared ( approximately 4% RSD in retention time from column-to-column) via in situ polymerization, followed by one step modification with ethylenediamine. When coupled on-line with negative ESI-MS, low detection limits (0.3fmol) for a 3-sialyl-tetrasaccharide were achieved using a 2.5mx10 microm I.D. HILIC-PLOT column. A dextran ladder standard was used to evaluate the performance of the column, and high efficiency separation was achieved with detection of the dextrans up to G22 from approximately 50 fmol amounts injected. As an example of the high sensitivity of the column, MS(6) characterization of glycan structures was possible from the injection of 10 fmol of a neutral and sialylated glycan. As another example of high sensitivity LC-MS analysis of 3 ng of a PNGase F digest of ovalbumin allowed 28 N-linked glycans to be confidently identified from a single analysis. High quality MS/MS spectra for each ovalbumin glycan were acquired and manually interpreted for structure analysis. The HILIC-PLOT column is a very promising approach for LC-MS analysis of glycans at the ultratrace level.     

Spin Multiplicity Dependence of Nonlinear Optical Properties

Spin‐restricted time‐dependent DFT for open‐shell systems is used to study the spin multiplicity dependence of nonlinear optical coefficients. Calculations are performed for various spin states of the pyrrole radical (see figure). The results indicate a substantial dependence on spin multiplicity of the NLO properties, which are sensitive to the basis set compared to closed shells at the DFT level of theory.

     

Large open-circuit voltage polymer solar cells by poly(3-hexylthiophene) with multi-adducts fullerenes

Polymer solar cells (PSCs) made by poly(3-hexylthiophene) (P3HT) with multi-adducts fullerenes, [6,6]-phenyl-C61-butyric acid methyl ester (PC61BM), PC61BM-bisadduct (bisPC61BM) and PC61BM-trisadduct (trisPC61BM), were reported. Electrochemistry studies indicated that PC61BM, bisPC61BM and trisPC61BM had step-up distributional lowest unoccupied molecular orbital (LUMO) energy. PSCs made by P3HT with above PC61BMs show a trend of enlarged open-circuit voltages, which is in good agreement with the energy difference between the LUMO of PC61BMs and the HOMO of P3HT. On the contrary, reduced short-circuit currents (Jsc) were observed. The investigation of photo responsibility, dynamics analysis based on photo-induced absorption of composite films, P3HT:PC61BMs and n-channel thin film field-effect transistors of PC61BMs suggested that the short polaron lifetimes and low carrier mobilities were response for reduced Jsc. All these results demonstrated that it was important to develop an electron acceptor which has both high carrier mobility, and good compatibility with the electron donor conjugated polymer for approaching high performance PSCs.     

基于对称结构的光纤谐振环辅助马赫曾德尔干涉仪型梳状滤波器的研究

为了改善常规马赫曾德尔干涉仪(MZI)型滤波器的输出特性, 提出了一种由双耦合器和单模光纤构成的“8”字形谐振环,将该光纤谐振环与一个3 dB光纤方向耦合器相结合,利用光纤谐振环反馈回路引入的相位调节效应,选择合适的谐振环耦合角,设计出一种基于对称结构的光纤谐振环梳状滤波器,具有平坦滤波响应的输出光谱。与普通MZI型梳状滤波器和双级级联MZI型梳状滤波器相比,阻带抑制和过渡带滚降特性明显加强;与不对称结构的光纤谐振环辅助MZI型梳状滤波器相比,在考虑传输损耗的情况下,相干涉的两束光信号不存在幅度差异,降低了传输损耗对梳状滤波器消光特性的影响。