Operation of the quasi-optical gyrotron at harmonics of the gyrofrequency

This paper investigates the performance of a quasioptical gyrotron, when the electron beam interacts with the radiation fields at harmonics of the gyrofrequency. The nonlinear equations of motion are obtained in the slow-timescale. The expression for the linear gain is derived and the conditions for excitation are given (frequency threshold, optimal operating point, bean current and resonator quality thresholds). In the nonlinear regime, it is shown that maximum efficiencies comparable to those at the fundemental (50%) are possible, albeit at a prohitively high radiation field amplitude, while realistically feasible field amplitudes can give somewhat smaller, but nevertheless still high efficiencies (15%). Finally, the results are suplemented by empirical scaling laws, useful for experimental designs.     

Separation of mixtures of solvents with wide bore capillary columns connected in series

The gas chromatographic separation of the components of a complex mixture of industrial solvents, not possible on a single stationary phase owing to coelution of some of the compounds, has been achieved on two serially connected wide bore capillary columns of different polarity. The analysis of a mixture of twenty five compounds was optimized using the serial gas chromatography theory of Purnell and Williams. The capacity factors of sample components measured with the two columns coupled in series were found to agree with those predicted by theory, regardless of the order in which they were connected.     

束变换环孔激光谐振腔的环束场传输差分计算

 通过使用新的坐标变量和光场的表达形式，推导了新坐标系下环束场传输的偏微分方程，给出了相应差分方程的截断误差和稳定性条件，使得环束场传输计算速度大幅提高；使用二阶精度的Crank-Nicolso差分方法对束变换环孔激光谐振腔的环束场传输进行了计算，并与W.D.Murphy和M.L.Bernabe所给M-B积分近似方法的计算结果进行了比较，证实了该方法无论计算速度和精度都优于M-B积分近似方法。     

基于耦合T型空腔的多重法诺共振现象

提出由T型空腔和挡板组成的两种金属-电介质-金属(MIM)波导结构,分别为:正T型空腔结构和倒T型空腔结构,并应用有限元法系统地研究了该结构的透射特性.对于正T型空腔结构,仿真结果出现了双重法诺共振现象,并且共振波长可以通过改变T型空腔长度和高度进行调节.该结构有助于设计成敏感度达到1 620nm/RIU、品质因数为5.4×10~4的纳米传感器.对于倒置T型空腔,在波导中产生了多重法诺共振现象,其敏感度可达1 560nm/RIU,品质因数为9.37×104.该结构有望在光学集成回路,特别是纳米传感器、光束分路器方面具有广泛应用.     

Coupling influence on the refractive index sensitivity of photonic wire ring resonator

By taking the coupling effect into consideration, we study the resonance condition of a photonic wire microring resonator (PWRR) sensor and compare our results with the previous work. Simulation results show that the resonant wavelength and sensitivity strongly depend on the coupling strength. The difference caused by the coupling effect can be up to tens of nanometers for the resonant peak position and tens of nm/RIU for the sensitivity in a silicon-on-insulator (SOI) PWRR. Such a giant influence from coupling effect cannot be disregarded and should be considered seriously for the design and application of PWRRs. It also shows an alternative tuning technique by controlling the coupling strength.     

Full four‐component relativistic calculations of the one‐bond 77Se–13C spin‐spin coupling constants in the series of selenium heterocycles and their parent open‐chain selenides

Four‐component relativistic calculations of ⁷⁷Se–¹³C spin–spin coupling constants have been performed in the series of selenium heterocycles and their parent open‐chain selenides. It has been found that relativistic effects play an essential role in the selenium–carbon coupling mechanism and could result in a contribution of as much as 15–25% of the total values of the one‐bond selenium–carbon spin‐spin coupling constants. In the overall contribution of the relativistic effects to the total values of ¹J(Se,C), the scalar relativistic corrections (negative in sign) by far dominate over the spin‐orbit ones (positive in sign), the latter being of less than 5%, as compared to the former (ca 20%). A combination of nonrelativistic second‐order polarization propagator approach (CC2) with the four‐component relativistic density functional theory scheme is recommended as a versatile tool for the calculation of ¹J(Se,C). Solvent effects in the values of ¹J(Se,C) calculated within the polarizable continuum model for the solvents with different dielectric constants (ε 2.2–78.4) are next to negligible decreasing negative ¹J(Se,C) in absolute value by only about 1 Hz. The use of the locally dense basis set approach applied herewith for the calculation of ⁷⁷Se–¹³C spin‐spin coupling constants is fully justified resulting in a dramatic decrease in computational cost with only 0.1–0.2‐Hz loss of accuracy. Copyright © 2014 John Wiley & Sons, Ltd.     

Elongated hexagonal ZnO micro-fence optical resonator

A highly symmetric ZnO micro-fence is prepared to form an optical resonator, which a symmetric array consisting of six elongated hexagonal microcolumns. It is found that the luminescence emission could be enhanced at the edge of ZnO micro-fence and the wavelength dependent light intensity could be influenced by its geometry. The optical characterization along with theoretical calculations and computer simulation analysis suggest that the Fabry-Perot and Cross-whispering gallery modes are generated in ZnO micro-fence. The individual ZnO micro-fence can regarded as an optical resonator structure. Furthermore, it is proposed that the source concentration around the substrate during the growth is a crucial factor for forming such a micro-fence.     

Jordan operator algebras revisited

Jordan operator algebras are norm‐closed spaces of operators on a Hilbert space with for all . In two recent papers by the authors and Neal, a theory for these spaces was developed. It was shown there that much of the theory of associative operator algebras, in particular, surprisingly much of the associative theory from several recent papers of the first author and coauthors, generalizes to Jordan operator algebras. In the present paper we complete this task, giving several results which generalize the associative case in these papers, relating to unitizations, real positivity, hereditary subalgebras, and a couple of other topics. We also solve one of the three open problems stated at the end of our earlier joint paper on Jordan operator algebras.     

材料表征方法理论与实践课程的改革与建设*

通过与超星专业慕课制作团队合作搭建网络教学平台,将线上慕课教学与线下实验教学相结合,对材料表征方法理论与实践课程进行了全方位的改革。与传统实验教学相比,改革后的课程不仅能够激发学生的学习兴趣,实现时间空间的相对自由,还可以完善考核机制,提升教学质量,从而为高校化学研究生实验课程的改革提供一定的借鉴意义。