大直径铌酸锂晶片的化学机械抛光研究

本文采用化学机械抛光方法,以SiO2作为抛光液的研磨介质,对76mm Z切向的铌酸锂晶片的抛光进行了深入的研究.分析了影响铌酸锂晶片抛光效果的因素,通过优化工艺参数,使铌酸锂的表面粗糙度Ra达到0.387nm,平面面形误差小于4μm.     

近化学计量比铌酸锂晶体的晶格振动和相变软模研究

在室温下,近化学计量比铌酸锂晶体(S-LN)的拉曼散射研究从理论和实验上揭示了晶格空位对于拉曼光谱的影响。高温下,随着温度的升高,软模(5的拉曼峰变化非常强烈。一个软光学声子模来源于在铌-氧平面内的三重简并对称弯曲振动。顺电-铁电结构相变发生在大约1170℃。     

Ca2+掺杂铌酸锶钡晶体的光折射变化特性研究

基于Ca²⁺掺杂铌酸锶钡晶体的透射特性,探讨了Ca²⁺在晶体中的电子行为机制，分析了Ca²⁺掺杂而引起的光致折射率变化特性.采用Michelson干涉装置测得了样品折射率随时间变化的特性曲线.实验结果分析表明，适当的Ca²⁺掺杂可以有效改善铌酸锶钡晶体的光折射特性. 关键词： 2+')" href="#">Ca²⁺ 铌酸锶钡 透射率 光折变     

Improved microstructure, dielectric and ferroelectric properties of microwave-sintered Sr0.5Ba0.5Nb2O6

Ferroelectric strontium barium niobate (SBN) powder was synthesized by solid-state route. The green compacts were sintered in the temperature range 1250–1350 °C in a microwave furnace. The microstructural study, using SEM, revealed the grain size in the range 2–20 μm without microcracks, depending on the sintering temperature. This is in contrast to that obtained conventionally for sintered SBN powder synthesized by solid-state route, which resulted in duplex microstructure with microcracks [N.S. VanDamme, A.E. Sutherland, L. Jones, K. Bridger, S.R. Winzer, J. Am. Ceram. Soc. 74 (1991) 1785; P.K. Patro, A.R. Kulkarni, C.S. Harendranath, Ceram. Int. 30 (2004) 1405; P.K. Patro, Trans. Ind. Inst. Metals 59 (2006) 229]. Impedance analyzer and ferroelectric hysteresis loop tracer were used for the dielectric, ferroelectric, I–V and electric fatigue measurements. Microwave sintering also resulted in a dielectric maxima ε_max 2590 at 1 kHz (compared to 1103 for conventional sintering [P.K. Patro, A.R. Kulkarni, C.S. Harendranath, Ceram. Int. 30 (2004) 1405]) for the sintering temperature of 1350 °C. Similar improvement in microwave-sintered SBN was observed depending on their sintering condition. The origin of this difference is attributed to microstructural differences arising from difference in heating method. In this paper the observed dielectric and ferroelectric behavior have been correlated with different sintering conditions and consequent microstructure due to microwave sintering.     

基于周期极化反转铌酸锂光波导高速非归零码到归零码的转换

研究了基于周期极化反转铌酸锂光波导级联二阶非线性效应实现非归零码到归零码高速全光码型转换的新方案，使用的是马赫-曾德尔干涉仪结构.转换原理是非归零码信号光在级联倍频和差频过程中受到的放大作用引起马赫-曾德尔干涉仪的不平衡，进而通过干涉相消产生归零码信号光输出.首先从耦合波方程出发，数值模拟了非归零码到归零码码型转换过程.然后分析了波导长度、光功率、相对时延对消光比的影响并对码型转换进行了优化设计.最后分析了转换带宽，模拟计算表明信号光在90nm的3dB带宽内可调谐，进而可以实现多信道的同时转换.     

Mode-selective coupler for wavelength multiplexing using LiNbO<Subscript>3</Subscript>:Ti optical waveguides

A mode-selective directional coupler based on titanium in-diffused channel waveguides in lithium niobate is investigated. This coupler may be utilized as a key part of an add-drop multiplexer for dense wavelength division multiplexing in optical network nodes. The proposed coupler is based on evanescent coupling of the fundamental mode of a single-mode channel to the first higher mode of a parallel bi-modal waveguide. Our experimental results show that a compact directional coupler with coupling efficiencies larger than 90%, large bandwidth around 1550 nm, and with negligible polarization dependence can be realized using electro-optic lithium niobate substrates. Presented at 9-th International Workshop on Nonlinear Optics Applications, NOA 2007, May 17–20, 2007, Świnoujście, Poland     

Dielectric waveguide modulators at 95 GHz using LiNbO3

We describe electro-optic modulators at 95 GHz using LiNbO₃ in an H-guide configuration. We have observed 70% amplitude modulation at l KHz in a bridge configuration, corresponding to an induced phase shift of ±29°. The prospects for improved device performance will be discussed.Supported in part by Subcontract #67-471915 with California Institute of Technology under Prime Contract N00014-79-C-0839 with Office of Naval Research.     

An EPMA Study on KNbO3 and NaNbO3 Single Crystals – Potential Reference Materials for Quantitative Microanalysis

Single crystals of KNbO₃ and NaNbO₃ were selected from the limited number of suitable alkali compounds that are available and evaluated as possible reference materials for the electron-probe microanalysis (EPMA) of alkaline niobates with a composition described by the general formula K_1–XNa_XNbO₃. The EPMA study verified that KNbO₃ and NaNbO₃ single crystals are stable under the electron beam and compositionally homogeneous. A quantitative microanalysis confirmed the composition of pure KNbO₃, while the NaNbO₃ crystal contained 0.3 mass fraction % of Ca. A significant improvement in the accuracy of the quantitative EPMA of polycrystalline potassium–sodium niobates was achieved using these single crystals as standards. The crystals can also be useful as reference materials for the analysis of sodium and potassium in other materials.     

Optical Properties of Li0.5Ln0.5Nb2O6 Compounds with REEs and Yttrium

By means of vibrational spectroscopy and crystal optic analysis, the symmetry of crystals with the structure of fersmite in the Li_0.5Ln_0.5Nb₂O₆ series, where Ln = Nd—Lu and Y, has been refined.     

金属片加热区熔法单晶生长及应用

在比较现有的各种溶体生长方法的基础上,针对氕物晶体生长的特点,提出了适合均匀生长非固液同成份氧化物晶体的金属片加热区溶法,对该方法的装置、优缺点以及国内外研究现状作了详细的介绍,报道并讨论了应用铂片加热区溶法生长化学计量比铌酸锂晶体的试验及结果。