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211.
E. S. Flitsiyan 《Radiation measurements》1997,28(1-6):369-378
The radiography method is developed for the investigation of ionizing radiation sources distribution on the sample surface by means of a two-dimensional image, produced in a photoemulsion or dielectric track detector. Its sensitivity is within a range of 10−2 - 10−7 g/mm2 and resolution from 0.01 to 100 μm. Statistical analysis and computer processing of the radiographic images have allowed us to solve the two main tasks of the method, namely, the determination the true distributions of ionizing radiation sources on the surface and the quantitative estimation of the local content of different chemical elements within a given accuracy. 相似文献
212.
P. Meyer J. E. Groetz M. Fromm A. Lacourt A. Chambaudet 《Radiation measurements》1997,28(1-6):423-428
In the Laboratory of Nuclear Microanalysis, we have developed two techniques for neutron dosimetry; the first for low fluence, the second for high fluence. These two techniques use a Solid State Nuclear Track Detector (SSNTD): the CR-39. The low fluence technique is based on the measurement of etched tracks resulting from a neutron-proton conversion. A Monte Carlo code performs a simulation of the (n,p) collision in the detector, and a numerical computer code of latent track etching allows the evaluation of the etched track parameters. The object of this is to obtain characteristics of a neutron fluence from the measured etched track parameters. When there is a high fluence and high doses, CR-39 is unsuited for optical microscopy analysis. This is because of track overlapping which makes it impossible to carry out counting and exploitation. We have therefore developed a new method permitting the reading of samples based on the measurement of the angular distribution of coherent light (He---Ne laser) transmitted through the irradiated etched SSNTD. We present these two techniques and our initial results. 相似文献
213.
Ternary Intermetallic Phases of Lithium, Transition Metals of the 4th Group and Elements of the 5th Maingroup with Statistical Metal Distribution in the ?Cation”?-Substructure The results of X-ray investigations and neutron diffraction on new and in some cases already known [1, 2] ternary intermetallic phases of Lithium with transition metals of the 4th group (b) and those of the 5th main group (X = P, As, Sb, Bi) will be reported. They crystallize in a partly ?filled”? antifluorite type structure with a statistical Li/B-distribution in the tetrahedral sites. The structures are obviously stabilized by small amounts of enclosed d-elements. 相似文献
214.
215.
216.
I. Kh. Abdukadyrova 《Journal of Applied Spectroscopy》1999,66(1):144-147
Using two crystal dielectrics (α-Al2O3 and α-SiO2) as examples, the author studied the effect of large neutron-radiation doses on their optical spectra. The variation in IR
spectra in the region of α-SiO2 stretching and deformation vibrations is investigated; its relation to changes in the structure of the irradiated crystal
is discussed.
Institute of Nuclear Physics, Academy of Sciences of the Republic of Uzbekistan, Ulugbek Settlement, Tashkent, 702132. Translated
from Zhurnal Prikladnoi Spektroskopii, Vol. 66, No. 1, pp. 135–138, January–February, 1999. 相似文献
217.
Neutron skin thickness of 90Zr and symmetry energy constrained by charge exchange spin-dipole excitations
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The charge exchange spin-dipole (SD) excitations of \begin{document}$ ^{90} $\end{document} ![]()
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Zr are studied using the Skyrme Hartee-Fock plus proton-neutron random phase approximation with SAMi-J interactions. The experimental value of the model-independent sum rule obtained from the SD strength distributions of \begin{document}$ ^{90} $\end{document} ![]()
![]()
Zr(p, n)\begin{document}$ ^{90} $\end{document} ![]()
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Nb and \begin{document}$ ^{90} $\end{document} ![]()
![]()
Zr(n, p)\begin{document}$ ^{90} $\end{document} ![]()
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Y is used to deduce the neutron skin thickness. The neutron skin thickness \begin{document}$ \Delta r_{np} $\end{document} ![]()
![]()
of \begin{document}$ ^{90} $\end{document} ![]()
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Zr is extracted as \begin{document}$ 0.083\pm0.032 $\end{document} ![]()
![]()
fm, which is similar to the results of other studies. Based on the correlation analysis of the neutron skin thickness \begin{document}$ \Delta r_{np} $\end{document} ![]()
![]()
and the nuclear symmetry energy J as well as its slope parameter L, a constraint from the extracted \begin{document}$ \Delta r_{np} $\end{document} ![]()
![]()
leads to the limitation of J to \begin{document}$ 29.2 \pm 2.6 $\end{document} ![]()
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MeV and L to \begin{document}$ 53.3 \pm 28.2 $\end{document} ![]()
![]()
MeV. 相似文献
218.
Synthesis,Structure, and Properties of SrC(NH)3, a Nitrogen‐Based Carbonate Analogue with the Trinacria Motif
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M. Sc. Ronja Missong M. Sc. Janine George Dr. Andreas Houben Dr. Markus Hoelzel Prof. Dr. Richard Dronskowski 《Angewandte Chemie (International ed. in English)》2015,54(41):12171-12175
Strontium guanidinate, SrC(NH)3, the first compound with a doubly deprotonated guanidine unit, was synthesized from strontium and guanidine in liquid ammonia and characterized by X‐ray and neutron diffraction, IR spectroscopy, and density‐functional theory including harmonic phonon calculations. The compound crystallizes in the hexagonal space group P63/m, constitutes the nitrogen analogue of strontium carbonate, SrCO3, and its structure follows a layered motif between Sr2+ ions and complex anions of the type C(NH)32?; the anions adopt the peculiar trinacria shape. A comparison of theoretical phonons with experimental IR bands as well as quantum‐chemical bonding analyses yield a first insight into bonding and packing of the formerly unknown anion in the crystal. 相似文献
219.
Diselenophosphate‐Induced Conversion of an Achiral [Cu20H11{S2P(OiPr)2}9] into a Chiral [Cu20H11{Se2P(OiPr)2}9] Polyhydrido Nanocluster
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Dr. Rajendra S. Dhayal Jian‐Hong Liao Dr. Xiaoping Wang Dr. Yu‐Chiao Liu Dr. Ming‐His Chiang Dr. Samia Kahlal Prof. Jean‐Yves Saillard Prof. C. W. Liu 《Angewandte Chemie (International ed. in English)》2015,54(46):13604-13608
A polyhydrido copper nanocluster, [Cu20H11{Se2P(OiPr)2}9] ( 2H ), which exhibits an intrinsically chiral inorganic core of C3 symmetry, was synthesized from achiral [Cu20H11{S2P(OiPr)2}9] ( 1H ) of C3h symmetry by a ligand‐exchange method. The structure has a distorted cuboctahedral Cu13 core, two triangular faces of which are capped along the C3 axis, one by a Cu6 cupola and the other by a single Cu atom. The Cu20 framework is further stabilized by 9 diselenophosphate and 11 hydride ligands. The number of hydride, phosphorus, and selenium resonances and their splitting patterns in multinuclear NMR spectra of 2H indicate that the chiral Cu20H11 core retains its C3 symmetry in solution. The 11 hydride ligands were located by neutron diffraction experiments and shown to be capping μ3‐H and interstitial μ5‐H ligands (in square‐pyramidal and trigonal‐bipyramidal cavities), as supported by DFT calculations on [Cu20H11(Se2PH2)9] ( 2H′ ) as a simplified model. 相似文献
220.
[Cu32(H)20{S2P(OiPr)2}12]: The Largest Number of Hydrides Recorded in a Molecular Nanocluster by Neutron Diffraction
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Dr. Rajendra S. Dhayal Jian‐Hong Liao Dr. Samia Kahlal Dr. Xiaoping Wang Dr. Yu‐Chiao Liu Dr. Ming‐Hsi Chiang Prof. Werner E. van Zyl Prof. Jean‐Yves Saillard Prof. C. W. Liu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(23):8369-8374
An air‐ and moisture‐stable nanoscale polyhydrido copper cluster [Cu32(H)20{S2P(OiPr)2}12] ( 1H ) was synthesized and structurally characterized. The molecular structure of 1H exhibits a hexacapped pseudo‐rhombohedral core of 14 Cu atoms sandwiched between two nestlike triangular cupola fragments of (2×9) Cu atoms in an elongated triangular gyrobicupola polyhedron. The discrete Cu32 cluster is stabilized by 12 dithiophosphate ligands and a record number of 20 hydride ligands, which were found by high‐resolution neutron diffraction to exhibit tri‐, tetra‐, and pentacoordinated hydrides in capping and interstitial modes. This result was further supported by a density functional theory investigation on the simplified model [Cu32(H)20(S2PH2)12]. 相似文献