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91.
The present study investigated the modification of mesoscale inhomogeneous distribu-tion of soil wetness, resulting from mesoscale irrigation over arid or semiarid lands in mid-latitude in the later summer or early autumn, on mesoscale climate under conditions withand without synoptic flow influence, using an interactive model between soil and atmo-sphere. The simulations indicated that after a mesoscale irrgation, a wet soil breeze circu-lation was thermally forced, which was, in many features, similar to that of the sea breezecirculation. The influence of synoptic flows on the structure of thermally--induced wet soilbreeze circulation was also discussed. 相似文献
92.
93.
The radical addition reactions of α-substituted β,β-difluorovinyl sulfones 1 with α-oxy and acyl radical species, such as 1,3-dioxolane, tetrahydrofuran, 1,4-dioxane, butanal and hexanal, afforded radical addition products 2--16 in good yields. 相似文献
94.
Densification of boron carbide during sintering may be improved by a two-stage process, namely heating to 2000°C under vacuum and sintering at 2190°C under argon. This sintering regime allows achieving a relative density of the ceramic bodies fabricated from a fine powder higher than 95%. The nitrogen treatment of the boron carbide phase at 1900°C leads to the formation of the BN phase and precipitation of graphite. Vacuum treatment of these samples at 2000°C leads to decomposition of the boron nitride phase. The liberated free boron may again react with graphite to form in situ boron carbide particles. The experimental investigations of the sintering behavior of the boron carbide phase under various atmospheres supported the thermodynamic predictions regarding the phase transformation. No evidence, however, was found for enhanced sintering under a nitrogen atmosphere. 相似文献
95.
氧气氛中紫外光辐照官能化HDPE的结构与性能研究 总被引:2,自引:0,他引:2
采用FT-IR,XPS,WAXD,DXC,凝胶和表面自由能力分析,研究了氧化氛中紫外辐照官能化高密度聚乙烯(HDPE)的化学结构、晶体结构和表面自由能的变化。与空气相比,在氧气氛中紫外辐照HDPE能提高C-O,C(=O)O和C=O等含氧基团的引入速度,同时又能降低HDPE中的凝胶含量,在空气和氧气氛中紫外辐照后,HDPE的晶型没有发生变化,仍为正交晶系;HDPE的晶胞参数a,b,c以及(110),(200),(020),(011),(111)等晶面间距基本保持不变;HDPE的熔融温度下降,但熔融热焓升高,结晶度增大,表面自由能增大,且在氧气氛中辐照HDPE的变化幅度较大。 相似文献
96.
《Analytical letters》2012,45(2):308-317
A simple and cost-effective variant of laser induced breakdown spectroscopy is presented that involves a double simultaneous pulse configuration employing a single laser source. Its performance is compared with conventional single pulse configuration. Double simultaneous pulses were accomplished by splitting a Nd:YAG laser (1064 nm, 6 ns, 360 mJ) beam into two components that were focused on the sample surface to produce two concurrent breakdowns. Experiment was repeated for single pulse and double simultaneous pulses under different ambient pressures. The performance was evaluated on the basis of self-absorption, signal-to-noise ratio (SNR), and relative standard deviation (RSD) of the Mg II doublet (280.2704 nm, 279.553 nm). Optically thin emission lines of better profiles with higher signal-to-noise ratio resulted from double simultaneous pulses. The lowest relative standard deviations obtained by single pulse and double simultaneous pulse configurations were 18.89% and 12.01%, respectively. In fact, double simultaneous pulses have performed better than single pulse in all respects within the studied regime. 相似文献
97.
《Analytical letters》2012,45(9):1785-1799
Abstract Multiwalled carbon nanotubes (MWNTs) were treated with a mixture of concentrated sulfuric and nitric acid to introduce carboxylic acid groups to the nanotubes. Conducting polymer film was prepared by electrochemical polymerization of neutral red (NR). By using a layer‐by‐layer method, homogeneous and stable MWNTs and poly (neutral red) (PNR) multilayer films were alternately assembled on glassy carbon (GC) electrodes. With the introduction of PNR, the MWNTs/PNR multilayer film system showed synergy between the MWNTs and PNR, with a significant improvement of redox activity due to the excellent electron‐transfer ability of carbon nanotubes (CNTs) and PNR. The electropolymerization is advantageous, providing both prolonged long‐term stability and improved catalytic activity of the resulting modified electrodes. The MWNTs/PNR multilayer film modified glassy carbon electrode allows low potential detection of hydrogen peroxide with high sensitivity and fast response time. As compared to MWNTs and PNR‐modified GC electrodes, the magnitude of the amperometric response of the MWNTs/PNR composite‐modified GC electrode is more than three‐fold greater than that of the MWNTs modified GC electrode, and nine‐fold greater than that of the PNR‐modified GC electrode. With the immobilization of glucose oxidase onto the electrode surface using glutaric dialdehyde, a biosensor that responds sensitively to glucose has been constructed. In pH 6.98 phosphate buffer, nearly interference‐free determination of glucose has been realized at ?0.2 V vs. SCE with a linear range from 50 µM to 10 mM and response time <10s. The detection limit was 10 µM glucose (S/N=3). 相似文献
98.
Jóna E. Kubranová M. Sirota A. Šimon P. 《Journal of Thermal Analysis and Calorimetry》1998,52(2):373-382
The stoichiometry of thermal decomposition and enthalpy and structural changes were studied for the compounds formed by penetration
of [Ni(4-Etpy)4(NCS)2] (I) into Ca-montmorillonite (II) or Cr-, Zr- and Al-pillared analogues (III, IV and V, respectively).
The mass fractions of complex I in II, III, IV or V are different. It was found for all studied compounds that the release
of L (L=4-Etpy) is a three-step process (-2L, -1L, -1L), and differences occurred in enthalpy changes (δH in kJ per mole of
I) corresponding to the individual processes. These differences and the changes in diffraction and spectral properties of
the species formed after intercalation are assumed to have their roots in different intramolecular guest-host interactions
in the studied compounds.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
99.
聚中性红膜修饰电极测定痕量NO2^—的研究 总被引:4,自引:1,他引:4
研究了聚中性红膜修饰电极对NO-2的催化氧化性能,建立了测定NO-2的新方法。NO-2的浓度在2.0×10-6~5.0×10-3mol/L范围内与催化氧化峰电流呈良好的线性关系,检测限为6.0×10-7mol/L。若利用计时电流法分析,检测限可达8.0×10-8mol/L。 相似文献
100.
The studies were devoted to determination of the effect of gas atmosphere and its pressure on the second step of decomposition
of hydrated titanium dioxide (HTD) promoted by sulfate groups.
It has been found that thermal decomposition of HTD at temperatures above 300°C consists of a number of processes such as
dehydroxylation, desulfuration, recrystallization and sintering of solid grains, photochemical processes (if the decomposition
proceeds in the presence of light) and adsorption of gas phase components (in the presence of air or SO2).
Kinetic parameters characterizing this step of decomposition have been determined for processes carried out in vacuum and
in argon or air atmospheres (at a pressure of 13.33hPa). The kinetic curves of decomposition carried out in the presence of
gases capable of being adsorbed on the surface of partly dehydrated HTD are featured by local extrema due to simultaneous
processes of decomposition and adsorption of gas components.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献