全文获取类型
收费全文 | 6781篇 |
免费 | 917篇 |
国内免费 | 543篇 |
专业分类
化学 | 2032篇 |
晶体学 | 76篇 |
力学 | 260篇 |
综合类 | 148篇 |
数学 | 2580篇 |
物理学 | 3145篇 |
出版年
2024年 | 16篇 |
2023年 | 57篇 |
2022年 | 137篇 |
2021年 | 146篇 |
2020年 | 161篇 |
2019年 | 170篇 |
2018年 | 173篇 |
2017年 | 215篇 |
2016年 | 254篇 |
2015年 | 204篇 |
2014年 | 394篇 |
2013年 | 546篇 |
2012年 | 374篇 |
2011年 | 425篇 |
2010年 | 365篇 |
2009年 | 427篇 |
2008年 | 475篇 |
2007年 | 496篇 |
2006年 | 403篇 |
2005年 | 330篇 |
2004年 | 306篇 |
2003年 | 320篇 |
2002年 | 260篇 |
2001年 | 209篇 |
2000年 | 213篇 |
1999年 | 177篇 |
1998年 | 156篇 |
1997年 | 162篇 |
1996年 | 138篇 |
1995年 | 95篇 |
1994年 | 62篇 |
1993年 | 52篇 |
1992年 | 46篇 |
1991年 | 35篇 |
1990年 | 37篇 |
1989年 | 18篇 |
1988年 | 26篇 |
1987年 | 17篇 |
1986年 | 23篇 |
1985年 | 24篇 |
1984年 | 19篇 |
1983年 | 7篇 |
1982年 | 25篇 |
1981年 | 13篇 |
1980年 | 3篇 |
1979年 | 12篇 |
1978年 | 9篇 |
1977年 | 4篇 |
1972年 | 1篇 |
1959年 | 1篇 |
排序方式: 共有8241条查询结果,搜索用时 46 毫秒
131.
Andreas Heimermann Christoph van Wüllen 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(61):15148-15158
Spin Hamiltonian parameters of a pentanuclear Os Ni cyanometallate complex are derived from ab initio wave function based calculations, namely valence-type configuration interaction calculations with a complete active space including spin-orbit interaction (CASOCI) in a single-step procedure. While fits of experimental data performed so far could reproduce the data but the resulting parameters were not satisfactory, the parameters derived in the present work reproduce experimental data and at the same time have a reasonable size. The one-centre parameters (local matrices and single-ion zero field splitting tensors) are within an expected range, the anisotropic exchange parameters obtained in this work for an Os−Ni pair are not exceedingly large but determine the low-T part of the experimental χT curve. Exchange interactions (both isotropic and anisotropic) obtained from CASOCI have to be scaled by a factor of 2.5 to obtain agreement with experiment, a known deficiency of such types of calculation. After scaling the parameters, the isotropic Os−Ni exchange coupling constant is cm−1 and the D parameter of the (nearly axial) anisotropic Os−Ni exchange is −1, so anisotropic exchange is larger in absolute size than isotropic exchange. The negative value of the isotropic J (indicating antiferromagnetic coupling) seemingly contradicts the large-temperature behaviour of the temperature dependent susceptibility curve, but this is caused by the negative g value of the Os centres. This negative g value is a universal feature of a pseudo-octahedral coordination with configuration and strong spin-orbit interaction. Knowing the size of these exchange interactions is important because Os(CN) is a versatile building block for the synthesis of / magnetic materials. 相似文献
132.
Using column-switching liquid chromatography/tandem mass spectrometry (LC-MS/MS), we developed an improved analytical method of urinary estriol glucuronides. This new method is derived predominantly from maternal and fetal precursors in pregnancy. We used in the following procedure: first, we filtered urine samples with a membrane filter. Next, we directly injected the 50 microL aliquot of urine samples onto a pre-column. Then, after activating the column-switching valve, we backflushed the loaded samples onto the C(18) analytical column. Urine samples can be assayed within 20 min without any sample preparation steps. We monitored separated estriol glucuronides by negative electrospray ionization (ESI) and selected-reaction monitoring (SRM). The calibration range of estriol-3-glucuronide (E3-3G) and estriol-16-glucuronide (E3-16G) was 0.1-20 microg/mL and the linearity of the method was 0.9984 for E3-3G and 0.9987 for E3-16G. The limits of detection at a signal-to-noise (S/N) ratio of 3 were 10 ng/mL (E3-3G) and 5 ng/mL (E3-16G). The analytical recovery was over 85% and, in general, inter-day and intra-day variability for precision and accuracy were less than 10%. When applied to a pregnancy urine sample to biomedical monitoring of the function of the maternal/fetal unit, the proposed method allowed rapid and sensitive screening for the detection of E3-3G and E3-16G. 相似文献
133.
Mikhail Ivanovich Barnik Ivan Vladimirovich Simdyankin Boris Alexandrovich Umanskii Serguei Petrovich Palto 《Liquid crystals》2020,47(2):273-283
ABSTRACT Electro-optical switching and the liquid crystal (LC) director distribution are studied in spatially periodic electric field for vertically aligned LC with negative dielectric anisotropy. Two electro-optical switching modes characterised by different switching times are observed. These modes are well distinguished optically by choosing proper geometry for the polarisers axes orientation. One of these modes is significantly faster as compared to the other. The fast switching is explained in terms of localised near-to-surface director reorientation. The 3D-numerical simulation shows very good agreement with the experiment: it points out the existence of the disclination lines and field-stabilised walls responsible for the localised director field switching and its relaxation. Possibilities of enhancing the fast mode for high-speed light modulators are discussed. 相似文献
134.
Vesselin Dimitrov 《Journal of solid state chemistry》2005,178(3):831-846
A classification of binary oxide glasses has been proposed taking into account the values obtained on their refractive index-based oxide ion polarizability αO2−(n0), optical basicity Λ(n0), metallization criterion M(n0), interaction parameter A(n0), and ion's effective charges as well as O1s and metal binding energies determined by XPS. Four groups of oxide glasses have been established: glasses formed by two glass-forming acidic oxides; glasses formed by glass-forming acidic oxide and modifier's basic oxide; glasses formed by glass-forming acidic and conditional glass-forming basic oxide; glasses formed by two basic oxides. The role of electronic ion polarizability in chemical bonding of oxide glasses has been also estimated. Good agreement has been found with the previous results concerning classification of simple oxides. The results obtained probably provide good basis for prediction of type of bonding in oxide glasses on the basis of refractive index as well as for prediction of new nonlinear optical materials. 相似文献
135.
建立了处理双原子分子-表面相互作用的推广的LEPS势.借助推广的LEPS势,系统研究了一氧化碳分子在铂低指数表面吸附的动力学特性,重现了低指数表面的分子吸附热、吸附几何及本征振动等实验数据;鉴定了某些不合理的文献信息,预测了实验尚未探测到的重要信息:预测到Pt(100)表面四重洞位的C-O伸缩振动频率为1 962.60 cm-1;预测到Pt(110)表面吸附态的C-O及C-Pt键长分别为115.1、147 pm. 相似文献
136.
A. Voelkel 《Chromatographia》1987,23(3):195-198
Summary The possibility of evaluation of the parameters representing the dispersive solute-solvent interactions is presented. BN and Bs values can be used to describe the liquid phase polarity and to predict the retention indices of alcohols when the model
polyxyethylene glycol dialkyl ethers and their sulphur analogs are used as stationary phases. The possibility of the first
ionization potentials estimation is also presented. 相似文献
137.
Zusammenfassung In der vorliegenden Arbeit wird eine Methode zur Retentionsindex-Bestimmung beschrieben, die von einem kubischen Zusammenhang zwischen Bruttoretentionszeit-Differenzen der Referenzhomologen und der Kohlenstoffzahl ausgeht. Hieraus ergeben sich direkt die Nettoretentionszeiten. Der Fehler der Totzeitbestimmung entfällt bei dieser Methode. Mit den so gewonnenen Nettoretentionszeiten erhält man über einen kubischen Zusammenhang zwischen 1g ts=f(C) die Retentionsindices. Extrapolationen und Interpolationen sind über 300 Retentionsindexeinheiten mit einem mittleren Fehler von ±0,02 Retentionsindexeinheiten möglich. Das Verfahren bietet sich für eine automatische Berechnung der I-Werte mittels on-line-Datenverarbeitung an.
Cubic calculation of retention indices without determining the dead-time tm
Summary The method for the calculation of retention indices described here is based on a third order relationship between the logarithm of differences of unadjusted retention times of homologues and the carbon number. From this adjusted retention times are directly calculated. A determination of the dead-time is not necessary thus avoiding the errors connected with this factor. A cubic equation for the logarithm of the adjusted retention time lg ts as a function of carbon number Cn is used for the retention index calculation. Extrapolations and interpolations can be done over a range of 300 index units with an average deviation of ±0.02 i.u.. The method offers the possibility of an automated on-line calculation of retention indices by computer merely on the basis of unadjusted retention times.相似文献
138.
Summary The separation of C1–C4 alkyl tert-butyl ethers with the general formula (CH3)3C–O–R (R-alkyl substituent) on fused-silica capillary columns coated with dimethylsilicone and cyanopropylmethylsilicone stationary phases was investigated. Retention indices were determined at two temperatures in order to understand their chromatographic behaviour. The respective standard deviations were 0.3 and 0.5 i.u. 相似文献
139.
基于构建的数字经济发展水平评价指标体系与2010~2018年全国30个省市(除西藏、港澳台)的面板数据,对中国数字经济发展水平的时空特征、动态演化与区域差异原因进行探究。研究发现:全国及三大区域的数字经济发展水平均呈现稳步上升态势,并伴有明显的空间相关性、空间集聚性和区域差异性,且东部相较于中西部区域内差异更大。数字经济发展速度动态演化显示,整体上中国各省市数字化发展水平变化速度状态表现为上升趋势,相较于中西部,东部拥有更大的速度变化状态。地区前期数字化基础、经济发展的一阶滞后、政府科技投入均会促进区域数字经济的发展,对外开放水平会抑制数字经济发展,地区规模对数字经济的影响表现为非线性。此外,不同线性影响因素在不同区域内对数字经济发展水平具有不同的影响力。 相似文献
140.
Ruggero Freddi 《分析论及其应用》2022,38(1):26-78
In this paper we consider the Dirichlet problemwhere $\rho$ is a small parameter and $\Omega$ is a $C^2$ bounded domain in $\mathbb{R}^2$. In [1], the author proves the existence of a $m$-point blow-up solution $u_\rho$ jointly with its asymptotic behaviour. We compute the Morse index of $u_\rho$ in terms of the Morse index of the associated Hamilton function of this problem. In addition, we give an asymptotic estimate for the first $4m$ eigenvalues and eigenfunctions. 相似文献