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51.
以Se溶胶为模板,合成了多层核壳结构的Se@Pt@Au@Pt实心纳米粒子;采用化学与电化学相结合的除硒方法制得了(PtAuPt)HN/GC,并表征了(PtAuPt-Se)HN的表面形貌、结构与组成;以甲酸为探针分子,比较了(PtAuPt)HN/GC和Pt/C/GC对甲酸氧化的电催化行为,发现(PtAuPt)HN/GC催化甲酸氧化只有1个氧化峰,峰电位和峰电流分别约为0.35V和1.22mA/cm2,而Pt/C/GC则有2个氧化峰,在0.35V时所对应的电流密度仅约为0.30mA/cm2,前者在该电位时的电流密度是后者的4倍;在0.30mA/cm2的电流密度下,(PtAuPt)HN/GC对应的电极电位为0.01V,比Pt/C/GC负移了340mV;在600s时的计时电流分别为0.06和0.02mA/cm2.(PtAuPt)HN对甲酸氧化的电催化活性不但比Pt/C高,而且具有一定的抗CO中毒性能. 相似文献
52.
空穴传输层(HTLs)厚度对反式钙钛矿太阳能电池(PSCs)性能具有重大影响,因其显著影响太阳光透过和HTLs的空穴传输性能。几个纳米至十几个纳米厚度的超薄HTLs在减少伴生吸收、电荷传输损失和材料消耗等方面具有明显优势。目前,有许多成熟的制备超薄无机HTLs的方法,并在反式和叠层PSCs中得到广泛研究与应用。最近,一些关于有机超薄HTLs的新型制备方法也展现出良好的性能并逐渐引起相关领域研究者关注。在此,本文主要总结反式PSCs中超薄HTLs的研究进展与应用,关注其未来发展的挑战和方向,为该领域进一步的研究提供参考。 相似文献
53.
《Arabian Journal of Chemistry》2022,15(10):104157
We have investigated the effective utilization potential of carbon nanomaterials in the field of pour point depressants, and reported three kind of carbon-based hybrid nano-pour-point depressants with different dimensions. In this paper, poly-α-olefins-acrylate high-carbon ester pour point depressant (PAA-18) was prepared by esterification and polymerization as the basic pour point depressant. Then, the basic pour point depressant PAA18 was modified by solvothermal method with graphene oxide (GO), carbon nanospheres (Cna) and carbon nanotubes (OCNTs). The morphology and structure of the composites were analyzed by SEM, FTIR and XRD. The results showed that PAA18 was successfully in situ polymerized on GO, Cna and OCNTs. We took the simulated oil as the experimental object, and evaluated its pour point, rheological properties and wax crystal morphology, and achieved excellent results. In the three carbon-based hybrid nano-pour-point depressants with different carbon contents, the oxidation carbon nanotubes composite pour point depressant (PAA18-1 % OCNTs) with carbon content of 1 % had the best pour point and viscosity reduction effect when the dosage was 1250 ppm, which could make the pour point of the simulated oil containing wax decrease by 16 °C. PAA18-1 % OCNTs reduced the pour point by 5 °C more than PAA18. This paper provides reference for the application of carbon nanomaterials in the field of pour point depressant. 相似文献
54.
Electropolymerization is one of the most important methodologies to synthesize and develop conducting polymers. The complexity of the polymerization mechanism, ion doping processes and structural defects are considered to be symbiotic and unavoidable, making the stagnant state and huge band gap with advanced interdisciplinary research fields and important applications in the last three decades. Herein, we provide a point of view into controlled electropolymerization by regioselective activation reactions of monomers, where self-dimerizations instead of self-electropolymerizations were utilized. The resulting dimers play a role in the connections between functional building blocks to form functional polymers on demand. This account highlights the typical findings in controlled electropolymerizations as a forum for discussing new opportunities in exploiting novel designs and applications. 相似文献
55.
K-ion batteries (KIBs) attract considerable attention due to the abundance of K, high-working voltages, and chemical similarity with Li, enabling the utilization of mature Li-ion technology. However, shortage of high-performance anode materials is a critical obstacle for the development of KIBs. Through first-principles swarm-intelligence structural search, we identify a potential anode material, the C6S monolayer, which provides not only a remarkably high specific capacity of 1546 mAh/g but also a low diffusion barrier of 0.11 eV and a low open-circuit voltage of 0.21 V. Inherent metallicity originates from delocalized π electrons. 相似文献
56.
通过后合成修饰方法(PSM)构筑了空心纳米球(Void@UiO-66-Ⅰ)和实心块(UiO-66-Ⅰ) 2种形貌的季铵盐功能化UiO-66-NH2(Zr), 得到兼具酸碱活性位点和氢键给体的新型功能化金属-有机框架材料. 通过一系列表征证明2种催化剂的成功合成, 并将它们用于催化转化CO2和氧化苯乙烯的环加成反应. 由于Void@UiO-66-Ⅰ催化剂的季铵盐部分含有大量的羟基和卤素阴离子, 可以通过氢键和亲核攻击与环氧化合物连接, 诱导环氧化合物开环, 促使反应顺利进行, 且催化剂的中空结构有利于物质进出催化剂, 起到加快反应速率的作用, 使得该催化剂在CO2与氧化苯乙烯环加成反应中表现出比实心块UiO-66-Ⅰ催化剂更好的催化性能. Void@UiO-66-Ⅰ催化剂在120 ℃, CO2压力为1.2 MPa, 反应时间为6 h, 无溶剂和助催化剂的反应条件下, 碳酸苯乙烯酯的收率和选择性分别为85.5%和95%. 相似文献
57.
Hao Huang Cuicui Du Hongyan Shi Xun Feng Jin Li Yanlei Tan Wenbo Song 《Particle & Particle Systems Characterization》2015,32(1):72-79
Uniform water‐soluble monolayer MoS2 quantum dots (MQDs) with lateral sizes of ≈2.1 nm, a clearly zigzag‐terminated edge, and a hexagonal lattice structure are achieved using ammonium molybdate, thiourea, and N‐acetyl‐l ‐cysteine (NAC) as precursors and the capping reagent in a facile one‐pot hydrothermal approach. MQDs have good dispersity and high stability in aqueous suspension and exhibit a significantly larger direct bandgap (3.96 eV) compared to monolayer MoS2 nanosheets (1.89 eV). Pronounced blue‐shifts in the wavelengths of both the excitonic absorption and intrinsic state emission with activated strong luminescence at room temperature beyond monolayer MoS2 nanosheets is demonstrated. Unusual upconversion photoluminescence is also observed and is caused by two successive transfers of energy from the near‐infrared (NIR) absorption generated by the NAC capping reagent to the hexagonal structure of MQDs. Additional optical properties of MQDs may provide numerous exciting technological applications. Here, MQDs are demonstrated as a highly selective fluorescent reagent for detecting tetracycline hydrochloride under UV and NIR irradiation. 相似文献
58.
Point‐of‐Care Amperometric Testing of Diabetic Marker (HbA1c) Using Specific Electroactive Antibodies
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Specific immune detection of glycated hemoglobin is still a great challenge owing to the small epitopic difference between Hemoglobin (Hb) and HbA1c. We report a new electrochemical immunoassay format for point of care testing of HbA1c. A conducting self‐assembled monolayer of mercaptophenyl boronic acid (MPBA) was used as a capture layer for binding of glycated proteins and ferrocene tagged anti‐HbA1c antibody (FcAb) as a tracer molecule on a gold screen printed electrode. Validation of the new HbA1c assay was carried out using 6 clinical samples with known HPLC values and a correlation coefficient of 98 % was observed. 相似文献
59.
Unconventional Assembly of Bimetallic Au–Ni Janus Nanoparticles on Chemically Modified Silica Spheres
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Dr. Lei Jia Dr. Xiaowei Pei Prof. Feng Zhou Prof. Weimin Liu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(7):2065-2070
This paper reports that Janus Au?Ni nanoparticles (JANNPs) can self‐assemble onto silica spheres in a novel way, which is different from that of single‐component isotropic nanoparticles. JANNPs modified with octadecylamine (ODA) assemble onto catechol‐modified silica spheres (SiO2?OH) to form a very special core–loop complex structure and finally the core–loop assemblies link each other to form large assemblies through capillary force and the hydrophobic interaction of the alkyl chains of ODA. The nanocomposites disassemble in the presence of vanillin and oleic acid because of the breakage of the catechol–metal link. Vanillin‐induced disassembly enables the JANNPs to reassemble into a core–loop structure upon ODA addition. The assembly of SiO2?OH and isotropic Ni or Fe3O4 particles generates traditional core–satellite structures. This unconventional self‐assembly can be attributed to the synergistic effect of Janus specificity and capillary force, which is also confirmed by the assembly of thiol‐terminated silica spheres (SH?SiO2) with anisotropic JANNPs, isotropic Au, and Ni nanoparticles. These results can guide the development of novel composite materials using Janus nanoparticles as the primary building blocks. 相似文献
60.
We present a coarse-grained molecular dynamics simulation study of phase behavior of amphiphilic monolayers at the liquid crystal (LC)/water interface. The results revealed that LCs at interface can influence the lateral ordering of amphiphiles. Particularly, the amphiphile tails along with perpendicularly penetrated LCs between tails undergo a two-dimension phase transition from liquid-expanded into a liquid-condensed phase as their area density at interface reaches 0.93. While, the liquid-condensed phase of the monolayer never appears at oil/water interface with isotropic shape oil particles. These findings reveal the penetration of anisotropic LC can promote ordered lateral organization of amphiphiles. Moreover, we find the phase transition point is shifted to lower surface coverage of amphiphiles when the LCs have larger affinity to the amphiphile tails. 相似文献