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21.
M. Jesús Rodríguez M. Isabel Fernndez Ana M. Gonzlez‐Noya Marcelino Maneiro Rosa Pedrido Miguel Vzquez Bruno Donnadieu Manuel R. Bermejo 《无机化学与普通化学杂志》2005,631(11):2161-2166
M(HL)(H2O)n complexes have been obtained by the electrochemical reaction of Fe, Co, Ni, Cu, Zn and Cd anodes with the potentially pentadentate and trianionic asymmetrical Schiff base 3‐aza‐N‐{2‐[1‐aza‐2‐(5‐nitro‐2‐hydroxylphenyl)‐vinyl]phenyl}‐4‐(5‐nitro‐2‐hydroxyphenyl)but‐3‐enamide (H3L), containing a hard amido donor atom. The complexes have been characterized by elemental analysis, mass spectrometry, IR and 1H NMR spectroscopies, magnetic measurements and molar conductivities. Co(HL)(H2O) ( 2 ) has been found to rearrange in DMF solution into a crystallographically solved octahedral complex, CoL1(H2O)2 ( 7 ) [where H2L1 is the symmetrical Schiff base ligand N,N′‐(1,2‐phenylene)‐bis(5‐nitro‐3‐hydroxysalicylidenimine)]. A hydrolysis mechanism is discussed to explain this rearrangement. 相似文献
22.
The experimental values of the gas-phase proton affinities for a variety of 4-substituted benzonitriles, 4-substitutedN, N-dimethylanilines, and 4-substituted benzaldehydes have been examined by means of correlation analysis techniques and by ab initio quantum mechanical methods (MP2/ 6-31G(d) level). From this study it is concluded that in the gas phase, 4-(dimethylamino)-benzonitrile essentially protonates on the dimethylamino group, while protonated 4-cyanobenzaldehyde is very nearly a 21 mixture of the carbonyl- and cyano-protonated forms.This work is dedicatedin memoriam to Professor Robert W. Taft. 相似文献
23.
Matilde Fondo Ana M. García Deibe Noelia Ocampo Manuel R. Bermejo Jesús Sanmartín 《无机化学与普通化学杂志》2005,631(11):2041-2045
The heptadentate Schiff base H3L reacts with cobalt(II) acetate in methanol to form the discrete dinuclear complex Co2L(OAc)2(OMe)(H2O)2 ( 1 ·2H2O). The reaction of 1 ·2H2O with NMe4OH·5H2O in methanol gives rise to displacement of the acetate by methanolate groups, yielding Co2L(OMe)3(H2O) ( 2 ·1H2O). Recrystallizations of the Schiff base, 1 ·2H2O and 2 ·H2O in different solvents, produce single crystals of H3L, 1 ·2.5H2O and 2 ·2MeOH, respectively. The crystal structures of 1 ·2.5H2O and 2 ·2MeOH show the cobalt atoms double bridged by and endogenous phenol oxygen atom and an exogenous methanolate oxygen donor, giving rise to Co2O2 cores with Co···Co distances of ca. 2.87 Å. 相似文献
24.
G. G. Danagulyan D. A. Tadevosyan F. S. Kinoyan 《Chemistry of Heterocyclic Compounds》2006,42(6):782-787
Intermediate recyclization products were obtained in a study of the Kost-Sagitullin rearrangement of a series of 1,2-dialkylpyrimidinium
iodides. The initial attack of the nucleophile leads to the formation of products of the addition of the hydroxyl group, namely,
the corresponding pseudo bases. Heating one of these intermediates in ethanol or in the presence of primary amines leads to
rearrangement to give a pyridone derivative. Upon heating in chloroform, the pseudo bases readily lose a water molecule and
are converted to anhydro bases, namely, derivatives of 1-alkyl-1,2-dihydro-2-methylidenepyrimidine.
__________
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 894–900, May, 2006. 相似文献
25.
Square planar mixed ligand complexes of the type [CuLL′] where L = 5-chlorosalicylaldehyde and L′ = acetoacetanilide, have
been synthesized on treatment with ammonia. Amine exchange of the above Schiff base complexes has been carried out on treatment
with different amines. The reaction with ethanol amine is quite interesting compared to other amines. It reacts with 5-chlorosalicylaldehyde
to form a Schiff base, while the β-diketone part is removed in the complex formation. All the complexes were characterized
by elemental analysis, spectral studies, magnetic measurement, TLC, and conductane. 相似文献
26.
Donia A. M. El-Boraey H. A. El-Samalehy M. F. 《Journal of Thermal Analysis and Calorimetry》2003,73(3):987-1000
Manganese and iron complexes of Schiff bases derived from 6-formylkhellin were prepared and characterized. Complexes of o-phenylenediamine derivative (ligand (I)) are monomeric or dimeric whereas those of p-phenylenediamine derivative (ligand (II)) are polymeric. The complexes obtained are characterized by a lower magnetic moment
values. The complexes also have different solvent of crystallization with different nature of interaction. The thermal behaviour
of the ligands and their metal complexes was investigated by means of DTA, TG, IR and X-ray diffraction spectroscopy. Ligand
(I) shows different thermal behaviour from that of ligands (II) and (III). The complexes of ligand (II) give abnormal oxides
as a final product during their thermal decomposition.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
27.
用上升液滴法测定了2-乙基己基膦酸单(2-乙基己基)酯-正辛烷从硝酸介质中萃取镁、钙、锌、镍、铜和铅等二价金属离子的正向初始速率,建立了速率方程,计算出正向萃取反应的速率常数、活化能及活化熵,首次将软硬酸碱规则与金属溶萃取速率常数关联。结果表明,在萃取机理相同时,萃取速率常数的大小与金属离子的软硬酸碱标度一致,即萃取过程中,作为酸的被萃取金属离子,其硬度越大,萃取速率常数亦越大,萃取反应的活化能… 相似文献
28.
β-Aminopropionohydroxamic acid reacts with aliphatic aldehydes or ketones to give 2-substituted 1-hydroxytetrahydropyrimidin-6-ones,
while its reaction with aromatic carbonyl compounds leads to either the same products or Schiff's bases, which can exist in
tautomeric equilibrium in solution.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 691–694, April, 1998. 相似文献
29.
Liliana Cseh Carol Csunderlik Ingo Pantenburg Gerd Meyer Otilia Costisor 《无机化学与普通化学杂志》2003,629(6):985-988
The complex Co(C14H13NO)2Cl2 with the protonated N‐salicylidene‐p‐toluidine ligand was synthesized from an ethanolic solution of CoCl2·6H2O and N‐salicylidene‐p‐toluidine. The crystal structure was determined from X‐ray single crystal data (monoclinic, space group Cc, a = 1496.2(3) pm, b = 1257.4(4) pm, c = 1544.6(3) pm, β = 115.01(1)°, Z = 4). Co2+ adopts a distorted tetrahedral geometry. The UV‐Vis and IR spectra of the complex are discussed. 相似文献
30.
A chiral base route to a range of highly functionalised amino cyclopentenes has been developed. The key asymmetric step involved the chiral lithium amide base-mediated rearrangement of a protected trans-4-hydroxy cyclopentene oxide to give an allylic alcohol (88% ee). Subsequent Overman rearrangement gave a protected trans-1,2-aminocyclopentenol whereas Mitsunobu substitution with BocNHNs gave a protected cis-amino cyclopentenol. Both are proven intermediates for natural product synthesis. The protected cis-aminocyclopentenol was transformed in a few steps into a precursor of the cyclopentene core of nucleoside Q, a natural product whose deficiency in animals is related to tumour growth. 相似文献