类钴氙离子入射Ni表面激发的红外光谱线和X射线谱

当高电荷态类钴氙离子（cobalt like -Xe, Xe²⁷⁺）入射金属Ni表面过程中,共振电子俘获释放势能完成中性化,形成多激发态的Xe原子,其外壳层电子退激辐射红外光谱线.入射离子特殊的势能释放方式、离子动能和金属表面引起离子增益的能量在极短的时间（飞秒量级）沉积靶平方纳米尺度的空间范围,引起靶表面原子激发和电离,形成复杂组态之间的跃迁,特别是偶极禁戒跃迁（电四极跃迁、磁偶极跃）和X射线发射.单离子X射线产额随入射离子的动能增加而增加. 关键词： 高电荷态离子 红外光谱线 X射线 禁戒跃迁     

H+和Ar11+激发Si的K壳层X射线发射研究

测量了50–250 keV H⁺和1.0–3.0 MeV Ar¹¹⁺ 轰击Si表面过程中辐射的X射线. 结果表明, 在Ar¹¹⁺入射的情况下, 引起了Si的L壳层上3, 4个电子的多电离.计算了Si的K壳层X射线产生截面, 并将两体碰撞近似(BEA), 平面波恩近似, ECPSSR理论计算与实验值进行了对比. ECPSSR理论与质子产生的截面数据能够很好地符合; 而考虑多电离后, BEA理论与Ar¹¹⁺的实验结果符合较好. 关键词： X射线 高电荷态重离子 多电离     

宽音频扫描加载的电子剪切散斑技术在多层粘接板结构无损检测中的应用

本文利用宽音频自动扫描加载的电子剪切散斑干涉技术对多层粘接板结构进行了时实检测，结果表明，这种方法能够同时测定板的多个位置、大小和形状各不相同缺陷，迅速准确地对多层粘接板结构质量作出判断，同时根据到试过程中记录的共振频率等各种信息，可以进一步对被测部分的振动位移及缺陷深度进行定量分析．     

SnTiO_3:Mn~(4+)晶体中荷移激发态对EPRg和零场分裂D贡献的研究

构建了四方八面体(MnO6)8-络离子g因子和零场分裂D的完全高阶微扰公式.在这些公式中,除了中心离子Mn4+和配体离子O2-自旋-轨道耦合对g因子和D的贡献(双SO耦合参数模型)外,也考虑了荷移激发态(与电荷转移谱有关)与基态混合对EPR参量的贡献.用此公式算得SnTiO3:Mn4+的g因子和D与实验值较一致.而单SO耦合参数模型和双SO耦合参数模型获得的g因子和D较大地偏离了实验值.这说明SnTiO3:Mn4+晶体g因子的计算中荷移激发态与基态的相互作用不能被忽略.     

Materials parameters and ion-induced track formation

ABSTRACT

The role of various materials parameters in track formation is discussed. Experimental information is utilized showing a direct quantitative relationship in different solids between the melting points T_m and the ion-induced track radii R_e without involving other materials parameters. It is shown for Θ?=?T_m???T_ir (T_ir – irradiation temperature) that Θ～exp{?R_e²/w²} for S_e/N?=?constant, where S_e and N are the electronic stopping power and the number density of atoms and w?=?4.5?nm. The validity of this universal-type relation is demonstrated for 14 different insulators including LiNbO₃ and BaFe₁₂O₁₉. It is shown that the thermal diffusivity D, the heat of fusion L the band gap energy E_g and the absorption radius α_e of the electron distribution must not affect the track sizes as this would not be coherent with this identical behavior. Original reports on LiNbO₃ and BaFe₁₂O₁₉ with opposite conclusions are critically analyzed. It is shown that an arbitrary value of the ion energy was used in the analysis that modified substantially the results leading to an undue justification of the contribution of L and E_g in apparent agreement with the experimental data.     

类镍铱离子光谱跃迁研究

重元素高电离的离子特性对研究激光核聚变和Ｘ射线激光等都很重要，本文用３ｄ＾９４ｓ，３ｄ＾９４ｄ，３ｄ＾９４ｐ，３ｄ＾９４ｆ组态相互作用研究了类镍铱离子光谱跃迁。     

2-Trifluoromethyl-1,3-dithianylium triflate: a convenient ‘masked’ electrophilic pentafluoroethylation reagent

With 2-trifluoromethyl-1,3-dithianylium triflate for the first time the synthesis, isolation and full structural characterization of an α-perfluoroalkylcarbenium salt was achieved. The title compound can be easily obtained on a preparative scale. The thermally stable dithianylium salt in combination with fluorodesulfurization chemistry is a promising novel reagent for the electrophilic polyfluoroalkylation of organic substrates, demonstrated by the pentafluoroethylation of O-nucleophiles.     

Helium atom in the monochromatic electromagnetic field

We apply a non-perturbative procedure for the calculation of the total photoionization cross-section of two-electron atomic systems. The procedure is based on the Floquet-Fourier representation of the time-dependent Schr?dinger equation. With the use of the Hylleraas-type basis functions, the total photoionization cross-sections obtained are within the accuracy of a fraction of a percent, which, we believe, is the most accurate estimate for the cross-sections available. The total photoionization cross-sections for neutral helium deviate notably from the benchmark experimental data [J.A.R. Samson et al., J. Phys. B 27, 887 (1994)].     

稀土元素掺杂长余辉发光材料研究的最新进展

介绍了长余辉材料的历史和近几年的发展.对长余辉材料中的一些问题,如余辉机理等进行了总结和探讨.从稀土元素变价化学的角度出发讨论了稀土离子在长余辉材料中的作用,介绍了长余辉材料设计的一些想法.提出了对长余辉材料今后发展的看法.