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341.
Using the methods of molecular simulation and HyperChem v.5.0 programs (PM3 method), we carried out calculations of the principal spectroscopic characteristics and of the structure of the laurdan molecule in the ground and the first excited electronic states. The thermal static distribution of molecules over various possible orientations of the plane of methyl groups relative to the plane of the naphthalene bicycle was taken into account. The energies and dipole moments of these electronic states have been calculated as functions of the torsion angle of methyl groups. The existence of an additional mechanism of electronic spectrum broadening is shown; it is associated with thermal mismatch of the equilibrium orientations of the rotational fragment of the molecule and with the dependence of the electron transition frequency on the degree of deviation of the angle from the equilibrium value. The dependence of dipole moments on this angle has been found and calculated. This dependence is the strongest for the ground state. The maximum values of dipole moments in the ground and excited states are 4.0 and 7.6 D. 相似文献
342.
提出了一种新结构的高功率径向强流速调管振荡器,该器件利用折叠式同轴谐振腔的微波场与接近空间电荷限制电流的径向电子束强烈相互作用产生高功率微波。首先对这种器件的实现机理进行了初步的分析,提出了有间隙电压情况时的径向同轴间隙的空间电荷限制电流1维近似估计模型。分析表明:对于电子束直流接近但小于直流空间限制电流的径向速调管,当有调制间隙电压时,空间限制电流要小于无调制间隙电压情况下的直流空间限制电流,径向强流电子束电流接近和超过空间电荷限制电流时会出现强烈的调制。然后用PIC程序对其特性进行了粒子模拟,在二极管输入电压500 kV、电子束电流为30 kA条件下,最终得到了峰值功率6 GW、频率1.3 GHz的微波输出。 相似文献
343.
Theory of the multilayer charged structures adjacent to an electrode surface in nonpolar dielectric liquids with low conductivity under the action of an electric field is developed. Structures of this kind have been revealed by the probe measurements of the field strength in the vicinity of the flat electrode in hydrocarbon liquids. 相似文献
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347.
Charge transport in poly(methylphenylsilane): The case for superimposed disorder and polaron effects
H. Bssler P. M. Borsenberger R. J. Perry 《Journal of Polymer Science.Polymer Physics》1994,32(9):1677-1685
Careful analysis of the temperature dependence of the hole mobility in poly (methylphenylsilane) indicates that the functional dependence is between an Arrhenius law and a ln μ ∝ T?2 law as predicted by a model of disorder-controlled hopping. This is attributed to the superposition of disorder and polaron effects. A method is presented for separating the two contributions. The evolution of time-of-flight photocurrent transients with decreasing temperature is consistent with the disorder parameter derived from the temperature dependence of the mobility. © 1994 John Wiley & Sons, Inc. 相似文献
348.
A relativistic model of independent quarks based on Dirac equation with an equally mixed scalar-vector square root confining
potential is used to compute the quark core contributions to the static properties like magnetic moments, charge radii and
axial vector coupling constant ratios of the baryon octet. The results obtained with appropriate corrections due to centre-of-mass
motion agree fairly well with experimental values. The model is also extended to the study of magnetic moments of the quark
core of baryons in the charmed andb-flavoured sectors and the overall predictions so obtained compare well with other model predictions. 相似文献
349.
The thermoluminescence of x-irradiated CaSO4: Dy phosphors has been studied for diverse activator concentrations. The concentration-dependence of these phosphors on the
increase of glow peak intensities has been found to be remarkable. For higher concentration of dysprosium the concentration
quenching effect has been observed. This has been attributed to the resonant transfer of energy from one activator atom to
another, bringing the possible migration of energy in a solid, which is likely to get dissipated without luminescence, at
the quenching site itself. The effect of irradiation time on the glow peak intensities reveals the initial linearity and a
subsequent decrease indicating the possible radiation damage. The role of Na2SO4 as a charge compensator has been studied in detail. An attempt has been made to unravel the type of kinetics involved in
the process, by calculating the activation energies by different methods. It has been concluded that the type of kinetics
involved in the process is bimolecular. 相似文献
350.
A conformally flat accelerated charge metric is found in an arbitrary dimension D. It is a solution of the Einstein-Maxwell-null fluid equations with a cosmological constant in D ≥ 4 dimensions. When the acceleration is zero, our solution reduces to the Levi-Civita-Bertotti-Robinson metric. We show
that the charge loses its energy, for all dimensions, due to the acceleration. 相似文献