Synthesis and magnetic properties of organic multilayer films based on the layer‐by‐layer assembly

Two polymers containing pyridine rings were prepared by free‐radical polymerization and confirmed by Fourier transform infrared and ¹H NMR spectra. The preparation of four multilayer films that were obtained by self‐assembly of the polymer and the transition metal neutralized polyelectrolyte on PE substrate was described. UV–vis spectra and atomic force microscopy images were applied to characterize these films and indicate the uniform assembling process. The driving force for building up the multilayer films was identified by infrared spectroscopy to be the coordination interaction. The magnetic behavior was examined as a function of magnetic field strength at 30 kOe and as a function of temperature (5–300 K). All films display strong soft ferromagnetic properties and higher than those of the bulk materials. The magnetic results show that the layer‐by‐layer self‐assembling approach is beneficial to the ordered alignment of adjacent paramagnetic spins and induces better magnetic phenomena. Copyright © 2015 John Wiley & Sons, Ltd.     

数字图像法测定养殖水中的孔雀石绿

建立一种简单、可靠的养殖水中孔雀石绿的数字图像检测方法。以1-己基-3-甲基咪唑四氟硼酸盐离子液体富集水样品,再用手机拍照获取样品信息,最后用数字图像结合多层感知器神经网络定量分析孔雀石绿的含量。该法测定结果的相对标准偏差不大于6%(n=5),加标回收率为97.8%~103.0%。该方法可用于养殖水中孔雀石绿的含量测定。     

Boundary conditions for contacts lines in coextrusion flows

A bicomponent coextrusion process is modelled using a 3-D finite element formulation. The layer uniformity problem in coextrusion is addressed by examining the effects of the polymer melt/polymer melt/die wall contact line boundary condition. It has been observed that the less viscous polymer layer will tend to displace the more viscous polymer layer near the die wall. The behaviour of the contact lisle is considered to be either a stick or slip boundary condition. In the stick boundary condition, the contact line does not move from its original position after the two polymer layers meet, A slip boundary condition allows the contact line to move along the die wall. The calculated interfaces which result from different contact line assumptions are determined. Results show that if a stick boundary condition is appropriate for a given fluid/fluid/solid contact line, then a very thin entrained layer of the more viscous polymer melt will be trapped between the less viscous polymer melt and the die wall. Slip boundary conditions would allow complete displacement of the contact line along the die wall. Both slip and stick boundary conditions produce similar interface profiles far away from the die wall for small viscosity ratios. In certain eases, the displacement of the more viscous material by the less viscous material will cease and a static interface structure is produced regardless of die length. Experimental work with polycarbonate melts is compared with the numerical simulations.A. Torres on leave from Investigación y Desarrollo,, C.A. (INDESCA), P.O. Box 10319, Complejo Petroquímico El Tablazo, Maracaibo, 4001, Venezuela.     

用积分变换及边界积分方法求解多层地基的静力问题

本文利用积分变换及矩阵递推方法得到了任意n层弹性体平面应变及轴对称问题的Mindlin解。再把此解作为基本解,利用Somigliana关系式,得到计算多层弹性体内部任意点位移的简便方法。利用此法很容易编制程序,且具有较高的计算精度与速度。     

层合球面各向同性热释电空心球的瞬态响应

运用叠加原理，将层合球面各向同性热释电空心球的球对称动力学问题的解分成准静态和动 态两部分，准静态部分首先运用状态空间法给出了显式表达式，然后运用分离变量法、初参 数法和特征函数展开技术，给出了动态部分的表示式，再结合内外表面上的电学边界条件和 界面上的电学连续条件，导出一个关于时间函数的第二类Volterra积分方程，运用插值法 可成功地给出此积分方程的高精度数值解，最终可求得原问题的位移、应力、电位移以及电 势的响应. 此方法适用任意层数且各层是任意厚度的层合热释电空心球作用随时间以任意形 式变化的球对称温度场. 文中还给出了数值结果.     

“三明治式”多层Au/Pt复合薄膜的制备及其对甲醇的电氧化

采用界面组装、欠电位沉积和氧化还原置换反应组合方法制备了单层Pt/Au复合薄膜, 并且不需要任何有机偶联剂; 组装单层Pt/Au复合薄膜为三类多层Pt/Au复合薄膜: (Pt/Au)_n、Pt_m/Au和(Pt₃/Au)_k (n、m和k分别为Pt/Au、Pt和Pt₃/Au的层数). 采用电子显微镜研究了Au纳米粒子单层膜和Pt/Au复合多层膜的形貌. 对于所有的多层膜电极而言, 其电化学活性面积随着层数的增加而增加. 通过研究甲醇在每一类Pt/Au复合薄膜上的氧化电流密度, 考察了其对甲醇的电催化和抗毒化性能. 对于同一类复合薄膜而言, 甲醇分别在(Pt/Au)₃、Pt₃/Au和(Pt₃/Au)₂电极上均具有最大的氧化电流密度, 且优于本体Pt电极. 在这三种电极中, (Pt/Au)₃电极无论从电流密度上还是从抗毒化能力上讲, 其性能是最好的, 而且其抗毒化能力也优于商业Pt/C催化剂. 这种良好的催化性能源于Au和Pt之间最大化的协同效应, 这取决于Pt和Au原子比率以及Pt纳米层和Au纳米层之间的排布方式.     

Layer-by-layer assembled multilayer films of methoxypoly(ethylene glycol)-block-poly(α,l-glutamic acid) and chitosan with reduced cell adhesion

A methoxypoly(ethylene glycol)-block-poly(α,L-glutamic acid) (mPEGGA) diblock copolymer is synthesized. Using QCM measurements, it is shown that (CS/mPEGGA)(n) film construction takes place over two build-up stages (exponential-to-linear). UV-vis spectra reveal the regular increase of the multilayer film growth at different molecular weights of mPEGGA. Contact angle and surface morphology investigation prove that the hydrophilicity of CS/mPEGGA multilayer film-modified substrate becomes better and the surface becomes rough. Significantly reduced cell adhesion is observed on the CS/mPEGGA multilayer film coated surface.     

改进的Whipple防护结构与相关数值模拟方法研究进展

基于弹丸在超高速撞击薄板时破碎形成碎片云的机理,Whipple防护结构能够对航天器所面临的空间碎片及微流星体等威胁形成有效防护。通过回顾Whipple防护结构的研究和发展历程,对多层板结构、填充式防护结构、夹芯板结构等进行对比,分析其力学效应和防护性能;总结可应用于含泡沫、蜂窝、梯度和编织等材料的防护结构超高速撞击的数值模拟方法及其改进方法;结合相关材料的超高速撞击试验及数值模拟结果,为防护结构未来的研究方向提出建议。     

Annealing effects on structure and laser-induced damage threshold of Ta2O5/SiO2 dielectric mirrors

The effects of annealing on structure and laser-induced damage threshold (LIDT) of Ta₂O₅/SiO₂ dielectric mirrors were investigated. Ta₂O₅/SiO₂ multilayer was prepared by ion beam sputtering (IBS), then annealed in air under the temperature from 100 to 400 °C. Microstructure of the samples was characterized by X-ray diffraction (XRD). Absorption of the multilayer was measured by surface thermal lensing (STL) technique. The laser-induced damage threshold was assessed using 1064 nm free pulsed laser at a pulse length of 220 μs.

It was found that the center wavelength shifted to long wavelength gradually as the annealing temperature increased, and kept its non-crystalline structure even after annealing. The absorbance of the reflectors decreased after annealing. A remarkable increase of the laser-induced damage threshold was found when the annealing temperature was above 250 °C.     

Physicochemical Studies of the Sea-Surface Microlayer

In physicochemical studies on the sea-surface microlayer (SML) in seawater, the main researches conducted were as follows: (1) It was found that there is an objective layer of sudden change in physical and chemical properties between the SML and the subsurface layer in seawater. (2) The SML thickness was determined and should be about 50±10 μm. (3) The Gibbs model of the SML was extended, and the multilayer model of the SML was advanced. (4) The original-location method, which corresponds with the traditional removal-location method, was founded and used to determine the SML thickness. The results obtained from the two methods were almost identical. (5) An abnormal phenomenon was found when the Gibbs solution adsorption was applied to the seawater system, the reason for which was discussed preliminarily.