全文获取类型
收费全文 | 4735篇 |
免费 | 446篇 |
国内免费 | 573篇 |
专业分类
化学 | 2662篇 |
晶体学 | 17篇 |
力学 | 1041篇 |
综合类 | 45篇 |
数学 | 481篇 |
物理学 | 1508篇 |
出版年
2024年 | 8篇 |
2023年 | 41篇 |
2022年 | 129篇 |
2021年 | 152篇 |
2020年 | 164篇 |
2019年 | 134篇 |
2018年 | 122篇 |
2017年 | 136篇 |
2016年 | 140篇 |
2015年 | 130篇 |
2014年 | 186篇 |
2013年 | 412篇 |
2012年 | 231篇 |
2011年 | 294篇 |
2010年 | 221篇 |
2009年 | 312篇 |
2008年 | 316篇 |
2007年 | 328篇 |
2006年 | 298篇 |
2005年 | 278篇 |
2004年 | 217篇 |
2003年 | 236篇 |
2002年 | 178篇 |
2001年 | 131篇 |
2000年 | 115篇 |
1999年 | 97篇 |
1998年 | 88篇 |
1997年 | 93篇 |
1996年 | 84篇 |
1995年 | 65篇 |
1994年 | 67篇 |
1993年 | 50篇 |
1992年 | 57篇 |
1991年 | 35篇 |
1990年 | 34篇 |
1989年 | 21篇 |
1988年 | 37篇 |
1987年 | 27篇 |
1986年 | 16篇 |
1985年 | 17篇 |
1984年 | 23篇 |
1983年 | 2篇 |
1982年 | 14篇 |
1981年 | 6篇 |
1980年 | 3篇 |
1979年 | 4篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1974年 | 1篇 |
1969年 | 1篇 |
排序方式: 共有5754条查询结果,搜索用时 453 毫秒
11.
Ibrahim Erol 《Journal of polymer science. Part A, Polymer chemistry》2004,42(13):3157-3169
A new type of methacrylate monomer, [2‐oxo‐2‐(4‐acetyl) phenyl amino] ethylene methacrylate (APEMA), was synthesized. The oxime, 2,4‐dinitrophenylhydrazone, and thiosemicarbazone derivatives of poly{[2‐oxo‐2‐(4‐acetyl) phenyl amino] ethylene methacrylate} [poly(APEMA)] were prepared with hydroxylamine hydrochloride, 2,4‐dinitrophenylhydrazine, and thiosemicarbazone hydrochloride, respectively. The radical homopolymerization of APEMA was performed at 65 °C in a 1,4‐dioxane solution with benzoyl peroxide as an initiator. The monomer and its homopolymer were characterized with Fourier transform infrared and NMR techniques. The thermal stabilities of poly(APEMA) and its derivatives were investigated with thermogravimetric analysis and differential scanning calorimetry. The ultraviolet stability of the polymers were compared. The solubility and inherent viscosity of the polymers were also determined. The number‐average and weight‐average molecular weights and polydispersity index of the polymers were determined with gel permeation chromatography. The antibacterial and antifungal effects of the monomer and the polymer and its derivatives were also investigated on various bacteria and fungi. The activation energies of the thermal degradation of the polymers were calculated with the Ozawa method. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 3157–3169, 2004 相似文献
12.
A. Bourgeat O. Gipouloux E. Marui‐Paloka 《Mathematical Methods in the Applied Sciences》2004,27(4):381-403
In this paper, we study the global behaviour of an underground waste disposal in order to have an accurate upscaled model suitable for the computations involved in safety assessment processes. We start from a detailed model describing the transport of pollutant leaking from a high number of units. Using the method of homogenization, going to the limit, we obtain first a macroscopic model where the sources are now appearing globally. Then we compute a first‐order matched asymptotic expansion and we give the error estimates for this approximation. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
13.
Arup Baksi Bidyut Kumar Roy Rasajit Kumar Bera 《Mathematical and Computer Modelling》2006,44(11-12):1069-1079
The fundamental equations of the problems of generalized thermoelasticity with one relaxation parameter including heat sources in infinite rotating magneto-thermo-viscoelastic media have been derived in the form of a vector matrix differential equation in the Laplace transform domain for a one dimensional problem. These equations have been solved by the eigenvalue approach to determine deformations, stress, and temperature. The results have been compared to those available in the existing literature. The graphs have been drawn to show the effect of rotation in the medium. 相似文献
14.
Christodoulos Athanasiadis Nikolaos Berketis 《Mathematical Methods in the Applied Sciences》2006,29(1):27-48
A spherical electromagnetic wave propagating in a chiral medium is scattered by a bounded chiral obstacle which can have any of the usual properties. Reciprocity and general scattering theorems, relating the scattered fields due to scattering of waves from a point source put in any two different locations are established. Applying the general scattering theorem for appropriate locations and polarizations of the point source we prove an associated forward scattering theorem. Mixed scattering relations, relating the scattered fields due to a plane wave and the far‐field patterns due to a spherical wave, are also established. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
15.
Franck D'Agosto Marie‐Thrse Charreyre Christian Pichot Robert G. Gilbert 《Journal of polymer science. Part A, Polymer chemistry》2003,41(9):1188-1195
A method is described for synthesizing latex particles with anchored hairs by the grafting of hydrophilic chains, synthesized by reversible addition–fragmentation chain transfer, onto functionalized latex particles. These have the potential to bind biologically active species. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1188–1195, 2003 相似文献
16.
The paper deals with the stress, displacement, pore and fissure pressures fields induced by the drilling and/or the pressurization of a vertical borehole in a formation of water-saturated porous media with double porosity. The solution includes the boundary condition of non-hydrostatic in situ state of stress. The solid skeleton is assumed to behave as a linearly poroelastic material with compressible constituents. The analytical solution is derived in Laplace’s space and transformed to the time domain using a numerical inversion technique. The histories of pore and fissure pressures are illustrated to show the influence of permeabilities of the pore and fissure systems. 相似文献
17.
18.
Reaction diffusion systems on cylindrical domains with terms that vary rapidly and periodically in the unbounded direction can be analyzed by averaging techniques. Here, using iterated normal form transformations and Gevrey regularity of bounded solutions, we prove a result on exponential averaging for such systems, i.e., we show that traveling wave solutions can be described by a spatially homogenous equation and exponentially small remainders. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
19.
An optical element constructed by stacking a set of binary-phase grating sheets can simulate the functions of optically recorded volume gratings. Our electromagnetic numerical study also shows that if one of the grating sheets is replaced by another one with different grating period, power spectrum of the diffracted wave changes completely with extra diffraction orders. This property will claim strong advantage in security document applications. Analysis of alignment error reveals interesting phenomena concerning to how misalignment affects diffraction efficiency. 相似文献
20.
Eric Flauraud Frdric Nataf Isabelle Faille Roland Masson 《Comptes Rendus Mecanique》2003,331(12):849-855
We present in this paper a domain decomposition method to treat faults in geological basin modeling. The particularity of this model is that the faults whose widths are very small in comparison with the basin size, are not characterized as subdomains any more but as interfaces between sedimentary blocks. The originality of this work lies in the formulation of this new fault model and in the definition and the computation of the interface conditions between the subdomains. To cite this article: E. Flauraud et al., C. R. Mecanique 331 (2003). 相似文献