69,71Ga NMR studies of a superconducting Ga 84 cluster compound

We present ^69,71Ga-NMR experiments on microcrystalline samples of the recently discovered supramolecular compound Ga ₈₄ [ N ( SiMe ₃ ) ₂ ] ₂₀ Li ₆ Br ₂ ( thf ) ₂₀ ^. 2 toluene, which is composed of ligand-coordinated Ga₈₄ metal clusters, packed together in a fully ordered crystalline matrix. The compound is highly conducting and even shows superconductivity below T _c ~ 7.2 K. Our preliminary results between 10-300 K show a metallic-like behavior: the nuclear spin-lattice relaxation rate T ₁ ^-1 follows the Korringa law ⁶⁹ ( T ₁ T ) ^-1 = 0.36 s ^-1 K ^-1 , but with a relaxation rate approximately three times smaller than in bulk -Ga metal. No quantum-size effects are observed, the Korringa law being followed down to 10 K, whereas the quantum-gaps for individual clusters should amount to ~ 10 ³ K. These results therefore suggest a transport process based on intermolecular charge transfer, similar as in alkali-doped fullerenes and silicon-clathrates.     

Non-adiabatic quantum molecular dynamics: General formalism and case study H<Subscript>2</Subscript><Superscript>+</Superscript> in strong laser fields

In Rydberg atoms subject to static and harmonic collinear electric fields, intrashell transition can be induced by the first order perturbation from a small perpendicular electric or magnetic field, or by effects of the second order in the major fields. Both mechanisms lead to resonances that are suppressed under certain conditions, and high-frequency interference oscillations in case of non-adiabatic field switching. Recent measurements of microwave ionization signals show very rich and fascinating structures similar to the ones predicted for intrashell mixing. We show that the observed ionization structures may be explained by diabatic electric-field ionization and the consistent use of perturbation theory for intrashell mixing. In particular, the dominant oscillation frequency is successfully interpreted in terms of interference between first and second order transition amplitudes. New predictions are provided. The present approach gives a comprehensive picture of intrashell transitions, which may be tested in future experiments designed to observe such transitions directly. Received 2 May 2002 / Received in final form 23 September 2002 Published online 21 January 2003 RID="a" ID="a"e-mail: Valentin.Ostrovsky@pobox.spbu.ru RID="b" ID="b"e-mail: horsdal@ifa.au.dk     

Non-contemporaneous variations and Hölder’s principle

In the process of deducing the Hölder principle, a key step is to use the concept of non-contemporaneous variations. In this paper, whether starting from analytic method or from graphic solution method, the authors prove that the expression formula of non-contemporaneous variations is incorrect when the variable functions have zero-order nearness degree, and obtain a new expression. From the view of calculus of variations and differential calculus, the non-contemporaneous variations are studied. The study result shows that the concept of non-contemporaneous variations is a combination of the concept of variations and the concept of differentiation. The authors prove that the new expression is correct and obtain an equivalent expression of it. By means of this equivalent expression, this paper proves that the above expression formula of non-contemporaneous variations is correct when the variable functions have one-order nearness degree. Further study shows that, in the process of deducing Hölder’s principle, there is an implicit expression. Whether starting from analytic method or from graphic solution method, the authors discovered that the implicit expression of non-contemporaneous variations is incorrect when the variable functions have zero-order nearness degree and have one-order nearness degree. This paper proves that the implicit expression of non-contemporaneous variations is correct when the variable functions have two-order nearness degree. Further study shows that Hölder’s principle is tenable when the variable functions have two-order nearness degree.     

Oscillations of nonlinear partial difference systems

This paper studies the following two-dimensional nonlinear partial difference systems

     

Extending hysteresis operators to spaces of piecewise continuous functions

We consider continuous-time hysteresis operators, defined to be causal and rate independent operators mapping input signals to output signals . We show how a hysteresis operator defined on the set of continuous piecewise monotone functions can be naturally extended to piecewise continuous piecewise monotone functions. We prove that the extension is also a hysteresis operator and that a number of important properties of the original operator are inherited by the extension. Moreover, we define the concept of a discrete-time hysteresis operator and we show that discretizing continuous-time hysteresis operators using standard sampling and hold operations leads to discrete-time hysteresis operators. We apply the concepts and results described above in the context of sampled-data feedback control of linear systems with input hysteresis.     

Queueing Dynamics and Maximal Throughput Scheduling in Switched Processing Systems

We study a processing system comprised of parallel queues, whose individual service rates are specified by a global service mode (configuration). The issue is how to switch the system between various possible service modes, so as to maximize its throughput and maintain stability under the most workload-intensive input traffic traces (arrival processes). Stability preserves the job inflow–outflow balance at each queue on the traffic traces. Two key families of service policies are shown to maximize throughput, under the mild condition that traffic traces have long-term average workload rates. In the first family of cone policies, the service mode is chosen based on the system backlog state belonging to a corresponding cone. Two distinct policy classes of that nature are investigated, MaxProduct and FastEmpty. In the second family of batch policies (BatchAdapt), jobs are collectively scheduled over adaptively chosen horizons, according to an asymptotically optimal, robust schedule. The issues of nonpreemptive job processing and non-negligible switching times between service modes are addressed. The analysis is extended to cover feed-forward networks of such processing systems/nodes. The approach taken unifies and generalizes prior studies, by developing a general trace-based modeling framework (sample-path approach) for addressing the queueing stability problem. It treats the queueing structure as a deterministic dynamical system and analyzes directly its evolution trajectories. It does not require any probabilistic superstructure, which is typically used in previous approaches. Probability can be superposed later to address finer performance questions (e.g., delay). The throughput maximization problem is seen to be primarily of structural nature. The developed methodology appears to have broader applicability to other queueing systems.     

General Solution for Hamiltonians with Extended Cubic and Quartic Potentials

In terms of hyperelliptic functions, we integrate a two-particle Hamiltonian with quartic potential and additional linear and nonpolynomial terms in the Liouville integrable cases 1:6:1 and 1:6:8.     

Higher-Order Convex Approximations of Young Measures in Optimal Control

The general theory of approximation of (possibly generalized) Young measures is presented, and concrete cases are investigated. An adjoint-operator approach, combined with quasi-interpolation of test integrands, is systematically used. Applicability is demonstrated on an optimal control problem for an elliptic system, together with one-dimensional illustrative calculations of various options.     

BV estimates of Lax-Friedrichs' scheme for a class of nonlinear hyperbolic conservation laws

We give uniform BV estimates and -stability of Lax-Friedrichs' scheme for a class of systems of strictly hyperbolic conservation laws whose integral curves of the eigenvector fields are straight lines, i.e., Temple class, under the assumption of small total variation. This implies that the approximate solutions generated via the Lax-Friedrichs' scheme converge to the solution given by the method of vanishing viscosity or the Godunov scheme, and then the Glimm scheme or the wave front tracking method.

     

<Emphasis Type="Italic">X</Emphasis>-Trees and Weighted Quartet Systems

In this note, we consider a finite set X and maps W from the set $ \mathcal{S}_{2|2} (X) $ of all 2, 2- splits of X into $ \mathbb{R}_{\geq 0} $. We show that such a map W is induced, in a canonical way, by a binary X-tree for which a positive length $ \mathcal{l} (e) $ is associated to every inner edge e if and only if (i) exactly two of the three numbers W(ab|cd),W(ac|bd), and W(ad|cb) vanish, for any four distinct elements a, b, c, d in X, (ii) $ a \neq d \quad\mathrm{and}\quad W (ab|xc) + W(ax|cd) = W(ab|cd) $ holds for all a, b, c, d, x in X with #{a, b, c, x} = #{b, c, d, x} = 4 and $ W(ab|cx),W(ax|cd) $ > 0, and (iii) $ W (ab|uv) \geq \quad \mathrm{min} (W(ab|uw), W(ab|vw)) $ holds for any five distinct elements a, b, u, v, w in X. Possible generalizations regarding arbitrary $ \mathbb{R} $-trees and applications regarding tree-reconstruction algorithms are indicated.AMS Subject Classification: 05C05, 92D15, 92B05.