Chemical profiling and marker characterization of Huangqin decoction prepared with three types of peony root by liquid chromatography with electrospray ionization mass spectrometry

Clarification of the quality and biological effect equivalence of traditional Chinese medicines containing multi‐origin species is essential to improve their current quality standards, and also is the core problem to clarify the origins of single herbs with multi‐species in Chinese formulas that will guarantee their clinical application. Huangqin decoction is the typical one of multi‐origin formulas frequently used in traditional Chinese medicine and Kampo medicine. An ultra high performance liquid chromatography with electrospray ionization–tandem mass spectrometry was developed for chemical profiling and marker quantification of Huangqin decoction prepared with two different original types of peony root, white and red peony root. Forty‐seven main peaks in chemical profiling of Huangqin decoction prepared with white and red peony root were identified: nine were from peony root, 20 from baical skullcap root, 17 from licorice root, and one from jujubae fruit. The markers characteristics of the respective types of peony root in Huangqin decoction differ from that in single herbs, especially in terms of monoterpenoids and hydrolysable tannins. Subsequently, 17 representative markers in Huangqin decoction prepared with three types of peony root and their chemical characteristics and content distribution were carried out.     

1+1/2对转涡轮低压动叶激波结构的研究

本文对1 1／2对转涡轮低压动叶中激波结构等进行了详细的数值模拟．通过对流道中静压和马赫数等参数的分析发现,当高压动叶外伸波扫过低压动叶流道时,低压动叶前缘吸力面处产生了一道脱体弧形激波,流道中吸力面上产生了一道正激波,在脱体激波和正激波之间,存在着较强的膨胀波,这种分布与跨音压气机叶栅中的波系结构相似．当高压动叶尾迹扫过低压动叶时,低压动叶吸力面的压力会产生明显的波动,出现一个随时间变化的低压区．     

位标器动平衡测试系统中的相位测量方法研究

提出了一种相位测量方法,该方法可以准确检测从位标器陀螺仪输出的钟形光电脉冲信号峰值点的位置并以其为时间基准点进行相位测量,并可判断被测两信号之间的时间间隔以及超前滞后关系.针对在现场中的干扰因素,提出了相应的解决措施.该方法电路简单;测量速度快;精度高;可靠性好.     

The Applications of Order Reduction Methods in Nonlinear Dynamic Systems

Two different order reduction methods of the deterministic and stochastic systems are discussed in this paper. First, the transient proper orthogonal decomposition (T-POD) method is introduced based on the high-dimensional nonlinear dynamic system. The optimal order reduction conditions of the T-POD method are provided by analyzing the rotor-bearing system with pedestal looseness fault at both ends. The efficiency of the T-POD method is verified via comparing with the results of the original system. Second, the polynomial dimensional decomposition (PDD) method is applied to the 2 DOFs spring system considering the uncertain stiffness to study the amplitude-frequency response. The numerical results obtained by the PDD method agree well with the Monte Carlo simulation (MCS) method. The results of the PDD method can approximate to MCS better with the increasing of the polynomial order. Meanwhile, the Uniform-Legendre polynomials can eliminate perturbation of the PDD method to a certain extent via comparing it with the Gaussian-Hermite polynomials.     

Doublet bands at borders of A ≈ 130 island of chiral candidates: Case study of ~(120)I

Positive-parity doublet bands were reported in ~(120)I. Based on these, we discuss the corresponding experimental characteristics, including rotational alignment, and re-examine the corresponding configuration assignment.The self-consistent tilted axis cranking relativistic mean-field calculations indicate that the doublet bands are built on the configuration πh_(11/2)■νh_(11/2)~(-1). By adopting the two quasiparticles coupled with a triaxial rotor model, the excitation energies, energy staggering parameter S(I), B(M1)/B(E2), effective angles, and K plots are discussed and compared with available data. The obtained results support the interpretation of chiral doublet bands for the positive-parity doublet bands in ~(120)I, and hence identify this nucleus as the border of the A ≈ 130 island of chiral candidates.     

INFLUENCE OF FRICTION ON THE MOTION OF BASE WITH AN ECCENTRIC ROTOR

偏心转子惯性力引起的底座运动受到地面摩擦的影响,与光滑情形的理论结果存在定性差异。转子逆时针匀速旋转的惯性力若小于构件总重,则底座随摩擦因子增加而出现连续、一次停顿和两次停顿的振动及完全静止的4种状态。因惯性力对正压力及摩擦力的影响,底座在连续及一次停顿的振动时右向位移较大;而底座跳起时如``蛤蟆夯'则整体向左移动。     

多相催化反应的在线光谱-质谱探测系统

在研究多相催化反应中,建立和发展了一套在线高灵敏的共振增强多光子电离-飞行时间质谱检测系统。采用光纤作为传输介质,消除了激光在电离池内的吸收;自制了高输入阻抗的电荷灵敏放大器,提高了信号的稳定性;改进了飞行时间质谱仪中脉冲阀的进气方式,减少了死区,实现了质谱的快速采样。实验结果证明与传统的催化检测仪器相比,本系统具有灵敏度和采样率高,在线实时检测等特点。     

Synthesis and Infrared Multi‐band Absorption Properties of Core‐shell NaYF4:Yb3+, Er3+@SiO2 Nanoparticles

Due to the unique size effects, nanomaterials in infrared absorption have attracted much attention for their strong absorption in the infrared region. To achieve the infrared multi‐band absorption, we propose to synthesize a core‐shell structure nanomaterial consisting of NaYF₄:Yb³⁺, Er³⁺ core and a layer of SiO₂ as shell. A series of NaYF₄:Yb³⁺, Er³⁺ nanocrystals were synthesized through hydrothermal method by adjusting the ratio of citric acid(CA)‐to‐NaOH, and the effects of CA concentration, and NaOH concentration were studied in detail. NaYF₄:Yb³⁺, Er³⁺@SiO₂ nanoparticles were synthesized by sol‐gel method using TEOS as silica source. The results show that the core‐shell NaYF₄:Yb³⁺, Er³⁺@SiO₂ nanoparticles were successfully synthesized. Up‐conversion spectra of these nanoparticles were recorded with 980 nm laser excitation under room temperature. There are no changes of the emission centers of nanoparticles before or after silica coating, but the emission intensities of nanoparticles after silica coating are weakened. Furthermore, the property of infrared multi‐band absorption was tested through ultraviolet‐visible‐near infrared spectrophotometer and infrared absorption spectra. The results illustrate that the multi‐band infrared absorption nanomaterial was successfully synthesized.     

Safety margin criterion of nonlinear unbalance elastic axle system

IntroductionAtpresentanewanddevelopingsubject—chaoticdynamicsstartsabroadprospectforanalysisofnonlinearsystem[1～ 5 ].Largerotatingmachineryisatypicalnonlinearnon_autonomoussystem .Thesaferunofrotorsystemisofgreatsignificancetosociallifeandeconomicdevelopment.Thestabilityisthekeytosafeoperation .Thesafestabilityanalysisandcontrolforlargesystemisnotonlyamajorbasicresearchbutalsoisveryimportanttosolvethesafeproblemsinlifeandproduction[6 ,7].Soar,althoughmanymathematicians,mechanistsandengineer…     

具有局部非线性动力系统周期解及稳定性方法

对于具有局部非线性的多自由度动力系统，提出一种分析周期解的稳定性及其分岔的方法该方法基于模态综合技术，将线性自由度转换到模态空间中，并对其进行缩减，而非线性自由度仍保留在物理空间中在分析缩减后系统的动力特性时，基于Ｎｅｗｍａｒｋ法的预估－校正－局部迭代的求解方法，与Ｐｏｉｎｃａｒé映射法相结合，推导出一种确定周期解，并使用Ｆｌｏｑｕｅｔ乘子判定其稳定性及分岔的方法