利用广义不确定关系计算Reissner-Nordstrm-de Sitter黑洞的统计力学熵

利用广义不确定关系修正的态密度方程并采用Wentzel-Kramers-Brillouin(WKB)近似方法,计算了Reissner-Nordstrm-de Sitter(RNdS)黑洞时空中标量场的统计力学熵.结果表明,由这种方法得到的黑洞熵与它的内、外视界面积和宇宙视界面积之和成正比,这与采用其他方法所得的结果一致,从而揭示了黑洞熵与视界面积之间的内在联系,也进一步表明了黑洞熵是视界面上量子态的熵,是一种量子效应.     

Scattering and absorption of particles by a black hole involving a global monopole

Under the conditions that the wavelength of a particle is much larger than its radius of central mass, and the Schwarzschild field is weak, the scattering of a particle has been studied by many researchers. They obtained that scalar and vector particles abide by Rutherford’s angle distribution by using the low level perturbation method and the scattered field’s approximation in a weak field. The scattering cross section of a photon coincides with the section in Newton’s field of point mass. We can obtain the photon’s polarization effect by calculating the second-order perturbation in the linear Schwarzschild field. This article discusses the scattering and absorption of a particle by a black hole involving a global monopole by using the aforesaid method.     

A theoretical study of the oxygen K-edge near-edge X-ray absorption ne structure of N2O/Ir(110)

A multiple-scattering cluster method is employed to calculate the oxygen K-edge near-edge X-ray absorption fine structure of N₂O/Ir(110) and its monolayer. Two peaks and one weak resonance appear in both cases. The selfconsistent field DV-X calculations of the peaks and resonance show that the physical origin of the pre-edge peak x is different from those of the main peak 1 and the other weak resonance σ₁. This setup is intrinsic to the N₂O monolayer, owing to the interaction between the neighbouring molecular chains in the monolayer and partly to the adsorbed atomic oxygen, according to both the theoretical and experimental data.     

椭圆柱形光学黑洞红外辐射特性分析

本文主要采用时域有限差分(FDTD)方法计算了二维椭圆柱形光学黑洞的红外辐射特性。并且采用几何光学近似(GOA)对椭圆柱形的光学黑洞的光线入射轨迹进行分析和比较。研究结果表明,FDTD计算的光学黑洞内的能流分布结果与GOA计算的光学黑洞内的光线入射轨迹结果相吻合,椭圆柱形光学黑洞的红外辐射特性主要受折射率梯度和入射波长的影响。     

Enantiomerically Pure Phosphaalkene–Oxazolines (PhAk‐Ox): Synthesis,Scope and Copolymerization with Styrene

The design of a synthetic route to a class of enantiomerically pure phosphaalkene–oxazolines (PhAk‐Ox) is presented. The condensation of a lithium silylphosphide and a ketone (the phospha‐Peterson reaction) was used as the P?C bond‐forming step. Attempted condensation of PhC(?O)Ox (Ox=CNOCH(iPr)C H₂) and MesP(SiMe₃)Li gave the unusual heterocycle (MesP)₂C(Ph)?CN‐(S)‐CH(iPr)CH₂O ( 3 ). However, PhAk‐Ox (S,E)‐MesP?C(Ph)CMe₂Ox ( 1 a ) was successfully prepared by treating MesP(SiMe₃)Li with PhC(?O)CMe₂Ox (52 %). To demonstrate the modularity and tunability of the phospha‐Peterson synthesis several other phosphaalkene–oxazolines were prepared in an analogous manner to 1 a : TripP?C(Ph)CMe₂Ox ( 1 b ; Trip=2,4,6‐triisopropylphenyl), 2‐iPrC₆H₄P?C(Ph)CMe₂Ox ( 1 c ), 2‐tBuC₆H₄P?C(Ph)CMe₂Ox ( 1 d ), MesP?C(4‐MeOC₆H₄)CMe₂Ox ( 1 e ), MesP?C(Ph)C(CH₂)₄Ox ( 1 f ), and MesP?C(3,5‐(CF₃)₂C₆H₃)C(CH₂)₄Ox ( 1 g ). To evaluate the PhAk‐Ox compounds as prospective precursors to chiral phosphine polymers, monomer 1 a and styrene were subjected to radical‐initiated copolymerization conditions to afford [{MesPC(Ph)(CMe₂Ox)}_x{CH₂CHPh}_y]_n ( 9 a : x=0.13n, y=0.87n; GPC: M_w=7400 g mol^?1, PDI=1.15).     

Tuning properties of silver particle monolayers via controlled adsorption-desorption processes

Nanoparticle self-assembly at fluid-fluid interfaces has been traditionally exploited in emulsification, encapsulation and oil recovery, and more recently in emerging applications including functional nanomaterials and biphasic catalysis. We provide a review of the literature focusing on the open challenges that still hamper the broader applicability of this potentially transformative technology, and we outline strategies to achieve improved control over interfacial self-assembly of nanoparticles. First, we discuss means to promote spontaneous adsorption by tuning the interfacial energies of the nanoparticles with the fluids using capping ligands, and the occurrence of energy barriers. We then examine the interactions between interfacial nanoparticles and how they affect the formation of equilibrium interfacial suspensions versus non-equilibrium two-dimensional phases, such as weakly attractive glasses and gels. Important differences with colloidal interactions in a bulk suspension arise due to the discontinuity in solvent properties at the interface. For instance, ligand brushes rearrange in asymmetric configurations, and thus play a significant role in determining interparticle interactions. Finally, we briefly discuss the link between interfacial microstructure and the dynamic response of particle-laden interfaces, including interfacial rheology and the fate of nanoparticle monolayers upon out-of-plane deformation.     

Determination of Oxytetracycline in Food Using a Disposable Montmorillonite and Acetylene Black Modified Microelectrode

Oxytetracycline is a broad-spectrum antibiotic used in animal husbandry that may cause the occurrence of antibiotic residues in food-producing animals. A detailed study of the electrochemical properties of oxytetracycline was carried out at montmorillonite and acetylene black modified carbon paste microelectrode. The oxytetracycline underwent an irreversible oxidation at montmorillonite-acetylene black/carbon paste microelectrode, which was an adsorption-controlled process with one proton and one electron. Using differential normal pulse voltammetry with accumulation at a fixed potential of 0.3 V for 120 s, oxytetracycline yielded a well-defined voltammetric response at 0.6 V in pH 7.4 citric acid–Na₂HPO₄ buffer. Furthermore, the oxidation peak current of oxytetracycline at the montmorillonite–acetylene black/carbon paste microelectrode linearly increased with concentration in the range of 0.5–50 µM with a low detection limit of 87 nM (S/N = 3). This methodology was successfully applied to the determination of oxytetracycline from food samples, suggesting that it has practical applications in monitoring oxytetracycline.     

复合型改性木质素基钻井液用降粘剂的性能研究

以马尾松硫酸盐制浆黑液为原料,经化学改性制备复合型改性木质素基钻井液用降粘剂,并对其在钻井液中的降粘性能进行实验室评价。研究结果表明,该降粘剂既能发挥无机降粘剂良好的降粘作用,又具有木质素系降粘剂良好的抗温、抗盐效果,具有较好的协同作用。加入0.5%降粘剂的淡水基浆,降粘率可达96.7%。     

Thermal properties and flame retardancy of novel epoxy based on phosphorus‐modified Schiff‐base

Through addition reaction of Schiff‐base terephthalylidene‐bis‐(p‐aminophenol) ( DP‐1 ) and diethyl phosphite (DEP), a novel phosphorus‐modified epoxy, 4,4'‐diglycidyl‐(terephthalylidene‐bis‐(p‐aminophenol))diphosphonate ether ( EP‐2 ), was obtained. An modification reaction between EP‐2 and DP‐1 resulted in an epoxy compound, EP‐3 , possessing both phosphonate groups and C?N imine groups. The structure of EP‐2 was characterized by Fourier transform infrared (FTIR), elemental analysis (EA), ¹H, ¹³C, and ³¹P NMR analyses. The thermal properties of phosphorus‐modified epoxies cured with 4,4'‐diaminodiphenylmethane (MDA) and 4,4'‐diaminodiphenyl ether (DDE) were studied by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The activation energies of dynamic thermal degradation (E_d) were calculated using Kissinger and Ozawa's methods. The thermal degradation mechanism was characterized using thermogravimetric analysis/infrared spectrometry (TG‐IR). In addition, the flame retardancy of phosphorus‐modified epoxy thermosets was evaluated using limiting oxygen index (LOI) and UL‐94 vertical test methods. Via an ingenious design, phosphonate groups were successfully introduced into the backbone of the epoxies; the flame retardancy of phosphorus‐modified epoxy thermosets was distinctly improved. Due to incorporation of C?N imine group, the phosphorus‐modified epoxy thermosets exhibited high thermal stabilities; the values of glass‐transition temperatures (T_gs) were about 201–210°C, the values of E_d were about 220–490 kJ/mol and char yields at 700°C were 49–53% in nitrogen and 45–50% in air. These results showed an improvement in the thermal properties of phosphorus‐modified epoxy by the incorporation of C?N imine groups. Copyright © 2010 John Wiley & Sons, Ltd.     

Changes in Protein Composition in Erythrocyte Membrane of Ethanol—Poisoned Rats After Administration of Teas

Selective hydrolysis of the protein to peptides, their resolution by chromatography and determination of the amino-acid sequence in individual peptides is one method applied to studies of their modifications and mutations in pathological conditions. The purpose of this work is the determination of the green and black tea effect on peptides and their amino acid contents in integral erythrocyte membrane proteins in ethanol intoxicated rats. It was shown that ethanol intoxication causes a decrease in peptides and their amino acid contents in comparison with the control group. The ingestion of green (black) tea with ethanol partially prevents these ethanol-induced changes.