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981.
982.
H.-J. Buschmann A. Wego K. Jansen E. Schollmeyer D. Döpp 《Journal of inclusion phenomena and macrocyclic chemistry》2005,53(3):183-189
α-Cyclodextrin and cucurbit[6]uril are macrocyclic ligands with nearly identical molecular properties. Both ligands possess nonpolar cavities with similar dimensions. They are able to include nonpolar molecules within their cavities. The main difference between both ligands is their solubility in water. An acceptable solubility for cucurbit[6]uril is only given in the presence of acids or salts. Due to the similarity of both ligands, the formation of mixed polyrotaxanes seems to be possible. The synthesis of statistically threaded α-cyclodextrin and cucurbit[6]uril on polyethylene glycol 2000 is verified using elemental analysis, 1H-NMR spectroscopy and differential scanning calorimetry. Under the experimental conditions used the number of threaded α-cyclodextrin molecules is higher compared with cucurbit[6]uril. However it is shown that the formation of mixed complexes is possible. 相似文献
983.
Evolutionary stability, the central solution concept in evolutionary game theory, is closely related to local asymptotic stability in a certain nonlinear dynamical system operating on the state space, the so-called "replicator dynamics". However, a purely dynamical characterization of evolutionary stability is not available in an elementary manner. This characterization can be achieved by investigating so-called "derived games" which consist of mixed strategies corresponding to successful states in the original game. Using well-known facts, several characterization results are obtained within this context. These also may shed light on the extremality properties of evolutionary stability. 相似文献
984.
985.
《先进技术聚合物》2018,29(4):1334-1343
The aminated graphene oxide (GO) was prepared by the functionalization of pristine GO with ethylenediamine and then dispersed into the poly(amic acid) (the precursor of polyimide [PI]) solution followed by the chemical imidization to successfully fabricate the PI/amine‐functionalized GO mixed matrix membranes (MMMs) using in‐situ polymerization method. Chemical structure and morphology of the GO before and after amine modification were characterized by scanning electron microscopy, Raman spectrum, Fourier transform infrared, and X‐ray photoelectron spectroscopy. Scanning electron microscopy indicated that fine dispersion of GO throughout PI matrix was achieved, which indicates that the in‐situ polymerization approach can enhance the interfacial interaction between the GO and the PI matrix, and then improve the dispersion of carbon material in the polymer matrix. Compared with the conventional solution mixture method, the MMMs prepared with in‐situ polymerization method showed excellent CO2 permeability and CO2/N2 selectivity. The MMMs doped with 3 wt.% aminated GO exhibited maximum gas separation performance with a CO2 permeability of 12.34 Barrer and a CO2/N2 selectivity of 38.56. These results suggest that the amino groups on GO have strong interaction with the CO2 molecules, which can significantly increase the solubility of polar gas. Our results provide an easy and efficient way to prepare MMMs with good mechanical behavior and excellent gas separation performance. 相似文献
986.
《先进技术聚合物》2018,29(2):874-883
The concept of mixed matrix membrane comprising dispersed inorganic fillers into a polymer media has revealed appealing to tune the gas separation performance. In this work, the membranes were prepared by incorporation of mesoporous silica into polyurethane (PU). Mesoporous silica particles with different pore size and structures, MCM‐41, cubic MCM‐48 and SBA‐16, were synthesized by templating method and functionalized with 3‐aminopropyltriethoxysilane (APTES). High porosity and aminated surface of the mesoporous silica enhance the adhesion of the particles to the PU matrix. The SEM and FTIR results showed strong interactions between the particles and the PU chains. Moreover, the thermal stability of the hybrid PUs improved compared to the pure polymer. Gas transport properties of the membranes were measured for pure CO2, CH4, O2, and N2 gases at 10 bar and 25°C. The results showed that the gas permeabilities enhanced with increasing in the loading of modified mesoporous silica particles. High porosity and amine‐functionalized particles render opportunities to enhance the gas diffusivity and solubility through the membranes. The enhanced gas transport properties of the mixed matrix membranes reveal the advantages of mesoporous silica to improve the gas permeability (CO2 permeability up to ~70) without scarifying the gas selectivity (α(CO2/N2)~ 30 for 5 wt% SBA‐16 content). 相似文献
987.
In this paper, we present a two-grid discretization scheme for semilinear parabolic integro-differential equations by $H^{1}$-Galerkin mixed finite element methods. We use the lowest order Raviart-Thomas mixed finite elements and continuous linear finite element for spatial discretization, and backward Euler scheme for temporal discretization. Firstly, a priori error estimates and some superclose properties are derived. Secondly, a two-grid scheme is presented and its convergence is discussed. In the proposed two-grid scheme, the solution of the nonlinear system on a fine grid is reduced to the solution of the nonlinear system on a much coarser grid and the solution of two symmetric and positive definite linear algebraic equations on the fine grid and the resulting solution still maintains optimal accuracy. Finally, a numerical experiment is implemented to verify theoretical results of the proposed scheme. The theoretical and numerical results show that the two-grid method achieves the same convergence property as the one-grid method with the choice $h=H^2$. 相似文献
988.
989.
设$\mathcal{A}$, $\mathcal{B}$是两个因子且$\dim\mathcal{A}>4$.本文证明了双射$\phi:\mathcal{A}\rightarrow\mathcal{B}$ 满足对所有的$A,B,C\in\mathcal A$有$\phi([A,B]\bullet C)=[\phi(A),\phi(B)]\bullet\phi(C)$当且仅当$\phi$是线性*-同构, 共轭线性*- 同构,负的线性*-同构, 负的共轭线性*-同构. 相似文献
990.
R. Kh. Sadikova 《Mathematical Notes》1997,61(6):724-730
Suppose (T, Σ, μ) is a space with positive measure,f: ? → ? is a strictly monotone continuous function, and &;(T) is the set of real μ-measurable functions onT. Letx(·) ∈ &;(T) andf ○x)(·) ∈L 1(T,μ). Comparison theorems are proved for the means $\mathfrak{M}_{(T,{\mathbf{ }}\mu ,{\mathbf{ }}f)} (x( \cdot ))$ and the mixed means $\mathfrak{M}_{(T_1 ,{\mathbf{ }}\mu _1 ,{\mathbf{ }}f_1 )} (\mathfrak{M}_{(T_2 ,{\mathbf{ }}\mu _2 ,{\mathbf{ }}f_2 )} (x( \cdot )))$ these inequalities imply analogs and generalizations of some classical inequalities, namely those of Hölder, Minkowski, Bellman, Pearson, Godunova and Levin, Steffensen, Marshall and Olkin, and others. These results are a continuation of the author's studies. 相似文献