Improvement of an Automated Sample Injection System for Pillar Array Columns to Increase Analytical Reproducibility

In our previous study, we developed an automatic sample injection system for pillar array columns for quantitative analysis. An autosampler was used to maintain a constant sample injection volume. However, the sample was diluted during injection using the autosampler, thus deteriorating the analytical reproducibility. In this study, we have substituted the autosampler with a syringe pump to overcome the abovementioned problem and improve the system. Sample dilution was avoided by filling the entire capillary with the sample at a constant rate. This improved system also increased the analytical reproducibility. In the previous system, the relative standard deviation (RSD) exceeded 17% of the peak height for coumarin dyes. In contrast, the improved system decreased the RSD to the range 1.2–1.8%. The analytical reproducibility was evaluated by using five types of amino acids. The RSD of each peak height was within 3.0%, confirming good reproducibility. These results indicate that the sample injection method developed in this study can be applied to biological sample analyses as a simple quantitative analysis method for pillar array columns.     

绿色简易法制备纯二氧化氮气体

设计了一种在密闭容器中制备纯二氧化氮气体的绿色简易方法。该方法实现了气体制备、收集、尾气处理的一体化,不仅可用于课堂演示实验,也为深入研究二氧化氮溶于水的定量实验奠定物质基础。另外,此方法也可用于无氧环境下其他物质的制备。     

An Ozone Generator of Miniaturization and Modularization with the Narrow Discharge Gap

The method of ionization discharge has a key action on the process of the ionization and decomposition of O₂ molecule as well as the re-decomposition of O₃ molecule. In this paper, an ozone generation of miniaturization which was fabricated by stacking discharge modules with rectangle is introduced, only volume of 23.0×53.0×42.0 cm³ for ozone production capacity of 1 kg/hr. In addition, the ozone concentration and its production efficiency are significantly improved in comparison with a conventional ozone generator, which have the highest ozone concentration of 308 g/Nm³ and the production efficiency of 118 g/kWh at ozone concentration of 200 g/Nm³.     

微电子封装结构设计与仿真分析

近年来半导体相关科技产品快速的朝高密度、高效能、多重物理特性与微小化发展,除上述趋势外,微电子产品尚需保有高可靠度、低制造成本与缩短上市时程等必要特性才可应付国际上激烈的竞争. 面对此一制程技术的快速变迁与高难度及高整合性制程革命性时代的到来,下世代封装技术的研究发展已面临了极大的挑战. 随着产品的高复杂度与微小化的发展趋势,若以传统实验及试误法(Try andError)的设计方式来进行产品的研发,其所耗费的金额与时间将过于庞大与漫长,因此以模拟分析法取代耗时耗钱的实验来进行产品研发的重要性与必然性已逐步提升,并受到国际各半导体相关大厂的重视与采用.     

Blue‐green light generation using high brilliance edge emitting diode lasers

A review about second harmonic generation using edge emitting diode lasers and nonlinear crystals to obtain laser radiation in the blue‐green spectral range is presented. Therefore, pump laser radiation with high brightness and narrow bandwidth is necessary. Thus, this review gives an overview of the advances made with distributed feedback and Bragg reflector lasers, tapered lasers and amplifiers as well as external cavity diode lasers and master oscillator power amplifier schemes to achieve high brilliance emission. Since periodically poled materials have enabled high second harmonic conversion efficiencies with low and moderate pump powers, the review is focused on frequency doubling using those materials. The most commonly used materials, their properties and limitations are discussed briefly. Single pass and resonant SHG setups with waveguide and bulk nonlinear crystals are discussed and an emphasis on building compact and integrated devices is made.     

小孔径微通道板

从空间分辨能力、时间分辨能力和动态范围方面介绍了通道小型化发展的趋势,根据微通道板性能和结构的关系分析了这种小型化带来的微通道板变形、破裂、结构错位等生产难题和解决方法.分析表明:美国MCP的孔径发展依次是12 μm,10 μm,9 μm,8 μm,6 μm和5 μm,先进国家微通道板孔径已经能够做到4 μm～5 μm,夜视仪的分辨能力已超过100 lp/mm;通道直径降至5 μm、4 μm甚至更低,通过改进材料成分和拉丝、排丝、压屏、酸溶工艺及设备可以实现5 μm以下小通道微通道板的制造.     

极限尺寸平板式微热光电系统的构建及性能评估

针对平板式微热光电系统,通过合理的分析和计算,给出了系统的一个极限尺寸以及相应的工作性能。研究过程中,系统完整的能量转换单元包括一个燃烧室、两个过滤层、两片光电池以及一个冷却通道,采用实验和计算分析相结合的方法,确定了各个部件的极限尺寸和相互位置,单元三个方向的总体尺寸分别为10 mm×8 mm×2.5 mm。随后通过建立的能量转换计算模型,对该尺寸下单元的各个性能参数进行计算,当氢氧混合气流量为1500 mL/min时,具体性能数据为:单元电能输出为3.51 W、总效率为1.74%、功率密度达到了17.55 W/cm~3,这充分论证了平板式微热光电系统充当微机械装置电源的可能性。     

稀土镧对薄膜中银纳米粒子的细化作用

通过更换基底材料,证实了稀土镧对AgBaO薄膜中银纳米粒子的细化作用.用LewisCampbell的薄膜理论分析表明,稀土镧对银纳米粒子的细化作用机理是,基底吸附稀土镧增强了基底对银原子的等效吸附能和基底表面徙动激活能,使镧和银结合形成的复合小银粒子在基底表面的徙动扩散运动受到削弱,进而减少了相互团聚所致.基底表面徙动激活能增量在0.04—0.07eV之间,相应的基底对银原子的等效吸附能增量在0.08—0.42eV之间 关键词： 细化 稀土 纳米粒子 粒度     

新型小型化的平面左手介质微带线及其后向波特性验证

基于裂缝谐振环结构的降频技术,首先设计了一种电尺寸较小的左手介质微带线单元,并根据电磁波在微带线上的传输和反射数据,分别计算了左手介质的有效介电常数和有效磁导率.之后针对左手介质八元阵列进行三维电磁仿真实验,结果表明该八元阵列在左手介质频段上具有独特的后向波效应,从而证实了该左手介质频段的存在.与传统的左手介质微带单元相比,阐述的左手介质单元的电尺寸减小了60%,而且结构简单,便于加工,适用于平面电路器件的小型化等应用研究工作. 关键词： 左手介质 小型化 双负特性 后向波特性     

一款小型化可见光两档7.5×变焦系统的设计

许多应用都期望以大视场搜索定位目标,以小视场瞄准跟踪目标.提出并设计一款小型化两档7.5×变焦距成像系统,其工作于486 nm～656 nm的可见光波段,短焦视场为±15°,长焦视场为±2°,两视场下F数均为2.8,系统总长仅为60 mm.系统由玻璃镜片及注塑镜片混合组成,包含一个前固定组和一个可动组,通过可动组在2个...