Viscoelastic properties of semidilute poly(methyl methacrylate) solutions

Viscoelastic properties were examined for semidilute solutions of poly(methyl methacrylate) (PMMA) and polystyrene (PS) in chlorinated biphenyl. The number of entanglement per molecule, N, was evaluated from the plateau modulus, G _N . Two time constants, _s and ₁, respectively, characterizing the glass-to-rubber transition and terminal flow regions, were evaluated from the complex modulus and the relaxation modulus. A time constant _k supposedly characterizing the shrink of an extended chain, was evaluated from the relaxation modulus at finite strains. The ratios ₁/ _s and _k / _s were determined solely by N for each polymer species. The ratio ₁/ _s was proportional to N ^4.5 and N ^3.5 for PMMA and PS solutions, respectively. The ratio _k / _s was approximately proportional to N ^2.0 in accord with the prediction of the tube model theory, for either of the polymers. However, the values for PMMA were about four times as large as those for PS. The result is contrary to the expectation from the tube model theory that the viscoelasticity of a polymeric system, with given molecular weight and concentration, is determined if two material constants _s and G _N are known.     

Entanglement Dynamics of Two V-type Atoms with Dipole–Dipole Interaction in Dissipative Cavity

In this work, a coupled system of two V-type atoms with dipole–dipole interaction in a dissipative single-mode cavity, which couples with an external environment, is studied. The analytical solution of this model is obtained by solving the time dependent Schrodinger equation after Hamiltonian of dissipative cavity is diagonalized by introducing a set of new creation and annihilation operators according to Fano theorem. It is also discussed in detail how the entanglement dynamics of different initial states are influenced by the cavity-environment coupling, the spontaneously generated interference (SGI) parameter, and the dipole–dipole interaction between two atoms . The results show that the SGI parameter has different effects on entanglement dynamics under different initial states. Namely, the SGI parameter will increase the decay rate of the initially maximal entangled state and reduce that of the initially partial entangled state. For the initially product state, the larger SGI parameter corresponds to the more entanglement generated. The entanglement monotonically decreases under the weak cavity-environment coupling, while the oscillation of entanglement will occur under the strong cavity-environment coupling. The larger the dipole–dipole interaction is, the slower the entanglement decays and the more the entanglement will be generated. So the dipole–dipole interaction can not only protect and generate entanglement very effectively, but also enhance the regulation effect of the SGI parameter on entanglement.     

Quantum‐matter photonic framework perspective of chemical processes: Entanglement shifts in HCN/CNH isomerization

A complete electro‐nuclear (EN) basis set and quantum electrodynamics bases in photon number scheme combines to form photonic bases sets. The EN q‐states can hence be modulated by appropriate external electromagnetic sources. Quantum determinants for HCN/CNH isomerization within photonic bases are elaborated that rationalize quantum state changes as if it were an apparent unimolecular process. Topologic label of base states permit linking with those obtained with semiclassic schemes. A comparison of results leads to conclude that both schemes can turn out to be complementary. The q‐scheme yielding more detailed information that the semiclassic one as expected. © 2015 Wiley Periodicals, Inc.     

Double‐trace deformations and entanglement entropy in AdS

We compute the bulk entanglement entropy of a massive scalar field in a Poincare AdS with the Dirichlet and Neumann boundary condition when we trace out a half space. Moreover, by taking into account the quantum back reaction to the minimal surface area, we calculate how much the entanglement entropy changes under a double‐trace deformation of a holographic CFT. In the AdS3/CFT2 setup, our result agrees with the known result in 2d CFTs. In higher dimensions, our results offer holographic predictions.     

Detection of Tripartite Genuine Entanglement by Two Bipartite Entangled States

There are practical motivations to construct genuine tripartite entangled states based on the collective use of two bipartite entangled states. Here, the case that the states are two‐qubit Werner states is considered. The intervals of parameters of two‐qubit Werner states are revealed such that the tripartite state is genuinely entangled. Furthermore, we also investigate the lower bound of genuine multipartite entanglement concurrence for tripartite qudit states. Several examples are given to show the effectiveness of the lower bound.     

Resource reduction for simultaneous generation of two types of continuous variable nonclassical states

We demonstrate experimentally the simultaneous generation and detection of two types of continuous variable nonclassical states from one type-0 phase-matching optical parametric amplification (OPA) and subsequent two ring filter cavities (RFCs). The output field of the OPA includes the baseband ω₀ and sideband modes ω₀±nω_fsubjects to the cavity resonance condition, which are separated by two cascaded RFCs. The first RFC resonates with half the pump wavelength ω₀ and the transmitted baseband component is a squeezed state. The reflected fields of the first RFC, including the sideband modes ω₀±ω_f, are separated by the second RFC, construct Einstein–Podolsky–Rosen entangled state. All freedoms, including the filter cavities for sideband separation and relative phases for the measurements of these sidebands, are actively stabilized. The noise variance of squeezed states is 10.2 dB below the shot noise limit (SNL), the correlation variances of both quadrature amplitude-sum and quadrature phase-difference for the entanglement state are 10.0 dB below the corresponding SNL.     

Can Quantum Correlations Lead to Violation of the Second Law of Thermodynamics?

Quantum entanglement can cause the efficiency of a heat engine to be greater than the efficiency of the Carnot cycle. However, this does not mean a violation of the second law of thermodynamics, since there is no local equilibrium for pure quantum states, and, in the absence of local equilibrium, thermodynamics cannot be formulated correctly. Von Neumann entropy is not a thermodynamic quantity, although it can characterize the ordering of a system. In the case of the entanglement of the particles of the system with the environment, the concept of an isolated system should be refined. In any case, quantum correlations cannot lead to a violation of the second law of thermodynamics in any of its formulations. This article is devoted to a technical discussion of the expected results on the role of quantum entanglement in thermodynamics.     

Local Information as an Essential Factor for Quantum Entanglement

Quantum entanglement is not only a fundamental concept in quantum mechanics but also a special resource for many important quantum information processing tasks. An intuitive way to understand quantum entanglement is to analyze its geometric parameters which include local parameters and correlation parameters. The correlation parameters have been extensively studied while the role of local parameters have not been drawn attention. In this paper, we investigate the question how local parameters of a two-qubit system affect quantum entanglement in both quantitative and qualitative perspective. Firstly, we find that the concurrence, a measure of quantum entanglement, of a general two-qubit state is bounded by the norms of local vectors and correlations matrix. Then, we derive a sufficient condition for a two-qubit being separable in perspective of local parameters. Finally, we find that different local parameters could make a state with fixed correlation matrix separable, entangled or even more qualitatively entangled than the one with vanished local parameters.     

Effects of classical random external field on the dynamics of entanglement in a four-qubit system

We investigate the dynamics of entanglement through negativity and witness operators in a system of four non-interacting qubits driven by a classical phase noisy laser characterized by a classical random external field (CREF). The qubits are initially prepared in the GHZ-type and W-type states and interact with the CREF in two different qubit-field configurations, namely, common environment and independent environments in which the cases of equal and different field phase probabilities are distinguished. We find that entanglement exhibits different decaying behavior, depending on the input states of the qubits, the qubit-field coupling configuration, and field phase probabilities. On the one hand, we demonstrate that the coupling of the qubits in a common environment is an alternative and more efficient strategy to completely shield the system from the detrimental impacts of the decoherence process induced by a CREF, independent of the input state and the field phase probabilities considered. Also, we show that GHZ-type states have strong dynamics under CREF as compared to W-type states. On the other hand, we demonstrate that in the model investigated the system robustness's can be greatly improved by increasing the number of qubits constituting the system.     

Stress overshoot of polymer solutions at high rates of shear; Polystyrene with bimodal molecular weight distribution

Overshoot of shear stress, σ, and the first normal stress difference, N₁, in shear flow was investigated for dilute solutions of polystyrene with very high molecular weight in concentrated solution of low M PS. In the case that the matrix was a nonentangled system, behavior of overshoot was similar to that of dilute solution of high M PS in pure solvent. The magnitudes of shear, γ_σm and γ_Nm, corresponding to the peaks of σ and N₁ lay on the universal functions of γ˙τ_R, respectively, proposed for dilute solutions in pure solvent. Here τ_R is the Rouse relaxation time for high M PS in the blend evaluated from dynamic modulus at high frequencies. In the case that the matrix was an entangled system, an additional σ peak was observed at high rates of shear at times corresponding to γ_σm = 2–3. This peak can be assigned to the motion of low M chains in entanglement network. When the matrix was entangled, stress overshoot was observed even at relatively low rates of shear, say γ˙τ_R < 10⁻². This is probably due to the motion of high M chains in entanglement of all the chains. In this case the γ_σm and γ_Nm values were higher than those expected for entangled chains of monodisperse polymer in pure solvent. © 2000 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 38: 2043–2050, 2000