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101.
Two new Zn2Dy2 complexes were constructed from Zn (II) salen‐type Schiff base complex fragment and 2,6‐pyridinedimethanol (H2pdm) or its Br‐substituted analogue (4‐bromopyridine‐2,6‐diyl)dimethanol (H2Brpdm); their molecular formulas are [Zn2Dy2(L)2(pdm)2(MeOH)2](ClO4)2 [ 1 , H2L = N, N′‐ bis(3‐methoxysalicylidene)‐1,3‐diaminopropane] and [Zn2Dy2(L)2(Brpdm)2(MeOH)2](ClO4)2 [ 2 ], the Dy (III) ions of which have a NO7 triangular dodecahedral coordination sphere. The two complexes show not only ferromagnetic interaction but also field‐induced single‐molecule magnet (SMM) behavior, which are rare Dy (III)‐containing cluster complexes with the NO7 triangular dodecahedral coordination sphere that can show good magnetic relaxation. The energy barrier value of complex 2 is higher than those of complex 1 and the Dy (III) complexes with the DyNO7 triangular dodecahedral coordination configuration reported in the literature. 相似文献
102.
Timothy F. L. McKenna 《大分子反应工程》2019,13(2)
This review gives an overview of the evolution of the technology of condensed mode cooling, primarily for the case of ethylene polymerization on supported catalysts in fluidized bed reactors. It is well known that this mode of heat removal is quite effective in allowing polyolefin manufacturers to increase significantly production rates. What is perhaps less well understood are all of the issues that, in addition to the effect of the latent heat of vaporization of injected liquid components, also have an impact on the rate of production and behavior of the reactor. However, the liquid components injected into the reactor can vaporize rapidly under full‐scale conditions, leaving behind several heavy components (with respect to ethylene) that have numerous effects on how the particles behave, on the reaction rate, and on fluidization, fouling, and other parameters related to reactor and process performance. 相似文献
103.
基于应用型本科院校创新型人才的培养目标,对本科生开展科研训练,将科研训练纳入教学过程,从课程体系、教学环节、教学手段、考核评价等方面进行了探索,构建了以科研训练为主线的研究型教学模式。 相似文献
104.
Theoretical analysis of the radiation effect on transient behavior of an optoelectronic integrated device composed of a heterojunction phototransistor and a light emitting diode is studied theoretically. First, the transient behavior and the rise time of this device before radiation are investigated based on the frequency response of the constituent devices and the optical feedback inside the device. Second, the effect of neutron irradiation flux on the transient behavior of this device is theoretically studied. The results show that, by increasing the optical feedback inside the device, the rise time in the amplification mode is increased along with an increasing output, while that in the switching mode can be reduced effectively, and the neutron irradiation reduces the transient response and the rise time in both the amplification and switching modes. This type of model can be exploited as optical amplifier, optical switching device, and other applications. 相似文献
105.
出行者的选择行为分析是交通系统中的一项重要内容,随着城市的发展,交通出行方式大体分为三大类:公共交通出行、辅助公共交通出行和私人交通出行。本文在以往的研究基础上,采用演化博弈的方法研究公共交通、共享汽车以及私家车三者之间的博弈关系,模拟出行者的选择行为,分析博弈均衡点稳定性及参数条件。通过模型仿真实验,演化结果中各项比例大小取决于各项收益、补贴、损失以及额外收益,要增加公共交通的配套设施,增收拥堵费以及增加对共享汽车的补贴及配套服务。 相似文献
106.
107.
An improved algorithm for the shallow water equations model reduction: Dynamic Mode Decomposition vs POD
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We propose an improved framework for dynamic mode decomposition (DMD) of 2‐D flows for problems originating from meteorology when a large time step acts like a filter in obtaining the significant Koopman modes, therefore, the classic DMD method is not effective. This study is motivated by the need to further clarify the connection between Koopman modes and proper orthogonal decomposition (POD) dynamic modes. We apply DMD and POD to derive reduced order models (ROM) of the shallow water equations. Key innovations for the DMD‐based ROM introduced in this paper are the use of the Moore–Penrose pseudoinverse in the DMD computation that produced an accurate result and a novel selection method for the DMD modes and associated amplitudes and Ritz values. A quantitative comparison of the spatial modes computed from the two decompositions is performed, and a rigorous error analysis for the ROM models obtained is presented. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
108.
In this paper an inclined edge cracked short beam specimen subjected to symmetric three-point bend loading was designed and examined for conducting mixed-mode I/II fracture toughness experiments. The aspect ratio (i.e. length to width ratio) and the loading span distance are considered much lower than the other conventional cracked bend beam samples. Crack tip parameters such as stress intensity factors and T-stress were computed numerically for this specimen by several finite element analyses and it was demonstrated that the specimen is able to produce full combinations of mode I and II including pure mode II. The practical capability of the short bend beam specimen was studied experimentally by conducting a set of mixed-mode fracture tests on PolymethylMethacrylate (PMMA) as a well-known model brittle material. The critical stress intensity factors, the direction of fracture kinking and the path of fracture trajectory were investigated both experimentally and theoretically using two stress and strain-based fracture criteria. The fracture toughness of tested PMMA was decreased by moving towards mode II case due to the effect of T-stress on the fracture mechanism of the short bend beam specimen. 相似文献
109.
Mohammad Pourmahmood Aghababa 《Communications in Nonlinear Science & Numerical Simulation》2012,17(3):1489-1492
The aim of this note is to point out some comments to the article [Delavari H, Ghaderi R, Ranjbar A, Momani S. Fuzzy fractional order sliding mode controller for nonlinear systems, Commun Nonlinear Sci Numer Simulat 15 (2010) 963-978]. 相似文献
110.
The quantum dynamics of carriers bound to helical tube surfaces is investigated in a thin-layer quantization scheme. By numerically solving the open-boundary Schrödinger equation in curvilinear coordinates, geometric effect on the coherent transmission spectra is analysed in the case of single propagating mode as well as multimode. It is shown that, the coiling endows the helical nanotube with different transport properties from a bent cylindrical surface. Fano resonance appears as a purely geometric effect in the conductance, the corresponding energy of quasibound state is obviously influenced by the torsion and length of the nanotube. We also find new plateaus in the conductance. The transport of double-degenerate mode in this geometry is reminiscent of the Zeeman coupling between the magnetic field and spin angular momentum in quasi-one-dimensional structure. 相似文献