氢氧化铝/环氧树脂复合材料的电荷衰减特性

环氧树脂电气绝缘性能优良, 但是其在脉冲功率设备中充当绝缘子时, 表面容易带电且不易衰减, 当表面电荷集聚到一定的程度会造成局部放电甚至发展为沿面闪络。为了提高环氧树脂的沿面闪络性能, 用中心粒径为1 m的氢氧化铝(ATH)无机填料来改善环氧树脂复合材料的表面性能。分别制备了ATH填料质量分数为0%(纯环氧) , 20%, 40%, 60%, 80%和100%的ATH/环氧树脂复合材料试样。用电声脉冲法研究了ATH填料对环氧树脂复合材料电荷衰减性能的影响, 对比了试样直流极化场强为10 kV/mm和30 kV/mm的试验结果。结果表明：ATH/环氧树脂复合材料电荷的衰减常数不仅与填料的质量分数有关, 而且与试样的带电量有关。     

Preparation of Zn(Cd)O:Ga–SiO2 composite scintillating materials

Composite material consisting of highly luminescent Zn(Cd)O:Ga powder embedded in the silica matrix was prepared. It was found out that ZnO:Ga with less developed crystals (i.e. annealed at lower temperatures) is more prone to interact with the SiO₂ matrix and form zinc silicates, which in turn resulted in the decrease in the excitonic emission. Pre-annealing of the powders at temperatures above 600 °C prevented the interaction with the SiO₂ matrix. ZnO:Ga with well-developed crystals at such a high temperatures was not affected by the matrix and retained its properties, i.e. high radioluminescence intensity and ultrafast sub nanosecond photoluminescence decay. Introducing Cd into the ZnO lattice caused observable red shift in the excitonic luminescence, without negatively affecting the total intensity or the decay.     

Pure annihilation type B→K0*±(1430)K(*)干 decays in the family non-universal Z0 model

By assuming that the scalar meson KK₀^*(1430) belongs to the rst excited states or the lowest lying ground states of qq', we study the pure annihilation-type decays B→K₀^*±(1430)K^(*)+ in the QCD factorization approach. Within the Standard Model, the branching fractions are of the order of 10^-8-10^-7, which is possible to measure in the ongoing LHCb experiment or forthcoming Belle-II experiment. We also study these decays in the family non-universal Z' model. The results show that if m_Z' 600 GeV (ξ =0.02), both the branching fractions and CP asymmetries of q⁰ →K₀^*+(1430)K^- could be changed remarkably, which provides us with a place for probing the e ect of new physics. These results could be used to constrain the parameters of the Z' model.     

Fluorescence decay and quenching of pyrene labeled on sulfonate polyelectrolytes in salt-free aqueous solutions

Fluorescence decay and quenching of pyrene labels on copolymers of 2-acrylamido-2-methylpropanesulphonic acid (AMPS) and N,N-dimethylacrylamide were observed in dilute salt-free aqueous solutions as a function of the mole fraction F_AMPS of AMPS from 0 to 0.896. Monoexponential decay was found for the samples of F_AMPS<0.35 and biexponential decay for the samples of F_AMPS>0.35. The fast decay component is 80%, and the averaged lifetime 〈τ〉 and lifetime τ₁ of the fast decay is decreased with increasing F_AMPS. Quenching efficiency of Cu²⁺, I⁻, CH₃NO₂, and dinitrobenzene to the pyrene label was investigated in the framework of Stern-Volmer plot. With increasing F_AMPS the quenching efficiency of Cu²⁺ is increased while that of I⁻ decreased. For the neutral quenchers, the quenching rate constant k_q increases when F_AMPS<0.449 then decreases, showing a decline of accessibility to the pyrene label. These results were interpreted consistently with the counterion condensation concept, where condensed counterions caused the polyelectrolyte chains to aggregate. The existence of less-polar “temporal aggregated domain” in highly charged polyelectrolytes appears to lead to the slower decay and lower accessibility of the pyrene labels.