首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   10290篇
  免费   2410篇
  国内免费   1178篇
化学   6352篇
晶体学   188篇
力学   634篇
综合类   73篇
数学   252篇
物理学   6379篇
  2024年   14篇
  2023年   103篇
  2022年   306篇
  2021年   350篇
  2020年   491篇
  2019年   441篇
  2018年   431篇
  2017年   458篇
  2016年   535篇
  2015年   450篇
  2014年   548篇
  2013年   876篇
  2012年   773篇
  2011年   787篇
  2010年   671篇
  2009年   665篇
  2008年   653篇
  2007年   635篇
  2006年   623篇
  2005年   512篇
  2004年   502篇
  2003年   426篇
  2002年   477篇
  2001年   337篇
  2000年   307篇
  1999年   216篇
  1998年   197篇
  1997年   142篇
  1996年   139篇
  1995年   125篇
  1994年   118篇
  1993年   89篇
  1992年   77篇
  1991年   51篇
  1990年   45篇
  1989年   41篇
  1988年   42篇
  1987年   29篇
  1986年   31篇
  1985年   34篇
  1984年   28篇
  1983年   14篇
  1982年   20篇
  1981年   10篇
  1980年   7篇
  1978年   15篇
  1977年   4篇
  1976年   8篇
  1975年   5篇
  1973年   5篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
121.
The stabilization method is applied to the case of interacting resonances in the photo-dissociation of van der Waals clusters composed by a rare gas atom bound to a dihalogen molecule. The study of an illustrative two-dimensional model consisting in a T-shaped NeI2 molecule shows the adequacy of the method whenever the projection of the stabilization wave functions on the assumed prepared initial state is accounted for. The agreement of the fragmentation cross-sections with some previous results using the effective resolvent method and accurate close-coupling calculations is excellent. The method reveals its utility as a complementary tool since allows, through the analysis of the stabilization wave function in terms of zero-order levels, a precise characterization of the resonant states involved. Received 5 April 2002 / Received in final form 24 May 2002 Published online 19 July 2002  相似文献   
122.
This study describes the preparation of polyethersulfone (PES)/layered silicate nanocomposites (PLSNs) by mixing PES polymer chain into organically‐modified layered silicate in 1‐methyl‐2‐pyrrolidinone (NMP) solution. Both X‐ray diffraction data and transmission electron microscopy images of PLSNs indicate that the silicate layers were almost exfoliated and randomly distributed into the PES matrix. The mechanical and barrier properties of PLSNs show remarkable enhancement in the storage modulus and water/oxygen permeability when compared with that of neat PES matrix. Surfaces modification of PES and PLSN films with various treated times, system pressures, and radio frequency (RF) powers were performed using a mixture of oxygen (O2) and nitrogen (N2) plasmas. The topographical and physical properties of plasma‐modified PES and PLSN surfaces were investigated using scanning probe microscopy (SPM), contact‐angle measurements, and X‐ray photoelectron spectroscopy (XPS). These results indicate that the surface roughness of PLSNs with the same condition of plasma modification is lower than that of neat PES matrix and is probably due to the increase of stiffness with the presence of inorganic layered silicates in PES matrix. The surface properties of the PES and PLSNs are also changed from hydrophobic to hydrophilic. The XPS spectra suggest that the exposure of the PES and PLSNs to the plasmas led to the combination of etching reactions of polymer surface initiated by plasma and the following addition reactions of new oxygen‐ and nitrogen‐containing functional groups onto polymer surfaces to change their surface properties. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 3185–3194, 2006  相似文献   
123.
Magnetic multilayers of 57Fe with nominal thickness, T nom, between 0.4 and 1.0 nm separated by 3.0 nm Al spacer layers were prepared by alternate deposition of the constituents in high vacuum. The samples were investigated at 4.2 K in external magnetic field. A fraction of Fe atoms corresponding to about 0.3 nm equivalent Fe-thickness was found to mix into the Al spacer. The extremely strong magnetic anisotropy observed for T nom < 0.8 nm is attributed to Fe layers of approximately two atomic planes thick. The anisotropy decreases considerably after the building up of the third Fe atomic layer starts at T nom = 0.8 nm, but full saturation was not achieved even for T nom = 1 nm and 3 T magnetic field applied perpendicularly to the sample plane.  相似文献   
124.
This paper discusses the influence of chemical composition on the final electromagnetic properties in higher permeability material. Furthermore, the effect of the hot rolling practice and the end of austenite transformation temperature range on the hot band microstructure is described. The magnetic polarization J5000 better than 1.7 T, using hot rolling conditions 40 mm transfer bar thickness, finish mill entry temperature 1000 °C, and finishing temperature 800–840 °C and after decarburization heat treatment and grain growth treatment, was obtained.  相似文献   
125.
A new Co–Fe-based ferromagnetic bulk metallic glass (BMG) was synthesized by copper mould casting method. The thermal stability and crystallization processes were investigated by differential scanning calorimetry (DSC) and X-ray diffraction (XRD). The soft magnetic behavior was studied by DC magnetic measurements. The high glass formation ability was interpreted in terms of the effective suppression of nucleation and growth of the intermetallic compounds which appear in the multicomponent system during solidification. The high thermal stability indicates that the new Co–Fe-based BMG could be used as high-temperature magnetic material. The low coercivity which was as low as 8 A/m for the as-cast sample was found in the Co–Fe-based metallic glass cylinder with a diameter of 1.5 mm.  相似文献   
126.
纤维素基磁性聚偕胺肟树脂吸附锂   总被引:3,自引:0,他引:3  
研究了氯化锂浓度、树脂含量和溶液的PH对碱式纤维素基磁性聚偕胺肟树脂吸附Li^+离子能力的影响。在适当条件下,每个偕胺肟基可吸附两个Li^+离子。  相似文献   
127.
Both homogeneous and asymmetric polyethersulfone (PES) membranes were prepared by solvent casting. The sorption and permeation behavior of CO2, O2, and N2 using these two kinds of cast PES membranes and commercially available homogeneous PES film was investigated to extract the pressure dependence of gas permeability and the permselectivity for CO2 relative to N2, and to confirm the validity of the working assumption that a skin layer in an asymmetric membrane can be essentially replaced by a thick homogeneous dense membrane. The pressure dependence of the mean permeability coefficient to CO2 in homogeneous membranes obeys the dual-mode mobility model. The ideal separation factor for CO2 relative to N2 at an upstream pressure of 0.5 MPa attains ca. 40, while the permeability to CO2 is about 2.7 Barrer at the same upstream pressure. The same separation factor in asymmetric membranes amounts to 35. The diffusion behavior for the skin layer in an asymmetric membrane with a thin skin layer can be simulated approximately by that in a homogeneous dense membrane. © 1993 John Wiley & Sons, Inc.  相似文献   
128.
129.
Issues raised by W. A. Rodrigues, Jr. are discussed.1. This is not a new result; see,e.g., Rohrlich.(3) 2. A typographical error in Eq. (77) is corrected here: The productj A in the right-hand parentheses was erroneously transcribed in Ref. (2) as A.3. I define electromagnetic fieldF = A to be that generated by electric charges and the magnetoelectric fieldG = M to be that generated by magnetic monopoles:F F +5 G. 4. Rodrigues, on the other hand, takes the position that the importance of the Lagrangian formulation should be downgraded if not discarded altogether: ... it is redundant to look for Lagrangians.(1) 5. In fact, he reformulates it using the language of differential forms.6. It is interesting to observe that this bilinear form has the additional virtue of being appropriate for dealing with the monopolecharge parity question, which was pointed out long ago.(14) 7. In fact, even mathematics looks to Nature for its authority.(16) There is evidence that Rodrigues does not understand this concept.(17)  相似文献   
130.
研究了采用低场脉冲核磁共振(NMR)测定二醋酸纤维素丝束油剂的新方法,给出NMR法测定二醋酸纤维素丝束油荆含量的标准曲线。同时对NMR法测量二醋酸纤维素丝束油荆不确定度进行了评估。结果表明,NMR法具有分析速度快、无污染、无损伤和准确度高的优点,适合于二醋酸纤维素丝束油荆的分析。  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号