全文获取类型
收费全文 | 10290篇 |
免费 | 2410篇 |
国内免费 | 1178篇 |
专业分类
化学 | 6352篇 |
晶体学 | 188篇 |
力学 | 634篇 |
综合类 | 73篇 |
数学 | 252篇 |
物理学 | 6379篇 |
出版年
2024年 | 14篇 |
2023年 | 103篇 |
2022年 | 306篇 |
2021年 | 350篇 |
2020年 | 491篇 |
2019年 | 441篇 |
2018年 | 431篇 |
2017年 | 458篇 |
2016年 | 535篇 |
2015年 | 450篇 |
2014年 | 548篇 |
2013年 | 876篇 |
2012年 | 773篇 |
2011年 | 787篇 |
2010年 | 671篇 |
2009年 | 665篇 |
2008年 | 653篇 |
2007年 | 635篇 |
2006年 | 623篇 |
2005年 | 512篇 |
2004年 | 502篇 |
2003年 | 426篇 |
2002年 | 477篇 |
2001年 | 337篇 |
2000年 | 307篇 |
1999年 | 216篇 |
1998年 | 197篇 |
1997年 | 142篇 |
1996年 | 139篇 |
1995年 | 125篇 |
1994年 | 118篇 |
1993年 | 89篇 |
1992年 | 77篇 |
1991年 | 51篇 |
1990年 | 45篇 |
1989年 | 41篇 |
1988年 | 42篇 |
1987年 | 29篇 |
1986年 | 31篇 |
1985年 | 34篇 |
1984年 | 28篇 |
1983年 | 14篇 |
1982年 | 20篇 |
1981年 | 10篇 |
1980年 | 7篇 |
1978年 | 15篇 |
1977年 | 4篇 |
1976年 | 8篇 |
1975年 | 5篇 |
1973年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 781 毫秒
101.
The reactions of bis(trimethylstannyl)ethyne, Me3Sn–C?C–SnMe3 ( 4 ), with trimethylsilyl‐ or dimethylsilyl‐dialkylboryl‐substituted alkenes 1 – 3 afford organometallic‐substituted allenes 5 , 6 and 8 , 9 in high yield. In the case of (E)‐2‐trimethylsilyl‐3‐diethylboryl‐2‐pentene ( 1) , a butadiene derivative 7 could be detected as an intermediate prior to rearrangement into the allene. All reactions were monitored by 29Si and 119Sn NMR, and the products were characterized by an extensive NMR data set (1H, 11B, 13C, 29Si, 119Sn NMR). Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
102.
Thi Thi Nge Naruhito Hori Akio Takemura Hirokuni Ono Tsunehisa Kimura 《Journal of Polymer Science.Polymer Physics》2003,41(7):711-714
A high magnetic field of 5 T was used to fabricate a magnetically aligned, optically anisotropic, liquid‐crystalline chitin/poly(acrylic acid) composite. The aligned mesophase was fixed by photoinitiated free‐radical polymerization. From an examination of polarized optical micrographs and an X‐ray diffraction study, a high degree of orientation of 0.70 was observed for the composite with a higher liquid‐crystalline chitin concentration (10.70 wt %); the orientation was reduced with a decreased chitin concentration at a given acrylic acid concentration. The X‐ray data for the developed composite showed a uniplanar orientation for the chitin crystallites, with its molecular long axes perpendicular to the direction of the magnetic field. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 711–714, 2003 相似文献
103.
Possible triggering of solar activity to big earthquakes (Ms ≥ 8) in faults with near west-east strike in China 总被引:1,自引:0,他引:1
HAN Yanben GUO Zengjian WU Jinbing & MA Lihua . National Astronomical Observatories Chinese Academy of Sciences Beijing China . Earthquake Research Institute of Lanzhou CSB Lanzhou China Correspondence should be addressed to Han Yanben 《中国科学G辑(英文版)》2004,(2)
A big earthquake (Ms = 8.1) occurred at western Kunlun Mts gap on November 14, 2001. It is the biggest earthquake in China in the past 50 years and the only one with a magnitude bigger than 8 in China after Dangxiong Earthquake (M = 8) in Tibet in 1951. The big earthquake has drawn wide attention of scientists in seismological, geophysical, geological and astro-geodynamic circles. Scientists are interested in the occurrence regularity of the very big earthquakes and try to find out the fac… 相似文献
104.
105.
H. Ohta M. Kimata K. Koyama Y. Oshima M. Motokawa H. Nishikawa K. Kikuchi I. Ikemoto 《International Journal of Infrared and Millimeter Waves》2005,26(11):1525-1530
We have developed a new magneto-optical measurement system using a rotational cavity system equipped with a millimeter vector
network analyzer and a 14 T solenoid type super conducting magnet. The measurement can be performed in the transmission configuration
down to 1.6 K. The results of the precise angular dependence measurement of quasi-one-dimensional organic conductor (DMET)2I3 using the new system are shown, and its Fermi surface will be discussed in connection with the previous reports. 相似文献
106.
M.A. Grado-Caffaro 《Optik》2003,114(5):237-238
Sensitivity of the velocity of a single electron, in the relativistic case, to a perpendicular magnetic field is evaluated by defining a parameter which becomes useful in a number of cases related to dynamical systems. In particular, the ultrarelativistic case is examined. 相似文献
107.
The polycrystalline sample of layered compound FePS_3 has been investigated by using M?ssbauer spectroscopy (12K to 300K), magnetic susceptibility measurements, x-ray diffraction and FTIR spectroscopy. The antiferromagnetic order exists below T_N=120.5±1K. The M?ssbauer spectra below T_N indicate that the magnetization axis is perpendicular to the layer of FePS_3, and the divalent iron cations are in their high spin configurations. By fitting the hyperfine field parameters near the Néel temperature, we obtain information on the nature of magnetic interactions in the material. The results show that the magnetic coupling can be treated by the two-dimensional Ising model, and it can be interpreted on the basis of a crystal-field effect. 相似文献
108.
对轴线起爆式螺线管型爆磁压缩发生器进行了理论模型研究,建立了爆炸管的一维爆轰驱动模型、螺线管内空间磁场强度分布模型、爆炸管外表面磁压力模型和发生器系统的等效电路模型等,对此类发生器的物理过程进行系统描述。在此基础上,编制了相应的零维数值模拟程序CEMG 1.0,利用该程序分别对四种不同模型参数的发生器进行了理论计算和参数优化,并对其中一模型发生器爆炸管外表面的磁压力及其引起的剩余电感进行了计算,给出了剩余电感与初始输入条件及负载电感的关系,从而得到该模型的输出性能极限。对理论模型的正确性进行了实例验算证明。 相似文献
109.
Akira Shimazu Tukasa Miyazaki Shigeru Katayama Yasuo Ito 《Journal of Polymer Science.Polymer Physics》2003,41(3):308-318
The ortho‐positronium (o‐Ps) lifetime τ3 and its intensity I3 in various fluorinated polyimides were determined by the positron annihilation technique and were studied with the spin–lattice relaxation time T1 and the propylene permeability, solubility, diffusivity, and permselectivity for propylene/propane in them. τ3, I3, and the distribution of τ3 changed when the bulky moieties in the polyimides were changed. The polyimides, having both large τ3 and I3 values, exhibited a short T1 and a high permeability with a low permselectivity. The propylene permeability and diffusivity were exponentially correlated with the product of I3 and the average free‐volume hole size estimated from τ3. In highly plasticized states induced by the sorption of propylene, the permeability increased with the propylene pressure in excellent agreement with the change in the free‐volume hole properties probed by o‐Ps. The large and broad distribution of the free‐volume holes and increased local chain mobility for the 2,2‐bis(3,4‐decarboxyphenyl) hexafluoropropane dianhydride‐based polyimides are thought to be important physical properties for promoting penetrant‐induced plasticization. These results suggest that o‐Ps is a powerful probe of not only the free‐volume holes but also the corresponding permeation mechanism and penetrant‐induced plasticization phenomenon. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 308–318, 2003 相似文献
110.