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21.
C. Vaca‐Garcia G. Gozzelino W. G. Glasser M. E. Borredon 《Journal of Polymer Science.Polymer Physics》2003,41(3):281-288
The main transitions of cellulose fatty esters with different degrees of substitution (DSs) were investigated with dynamic mechanical thermal analysis. Two distinct main relaxations were observed in partially substituted cellulose esters (PSCEs). They were attributed to the glass‐transition temperature and to the chain local motion of the aliphatic substituents. The temperatures of both transitions decreased when DS or the number of carbon atoms (n) of the acyl substituent increased. Conversely, all the transitions of fully substituted cellulose esters occurred within a narrow temperature range, and they did not vary significantly with n. This phenomenon was explained by the formation of a crystalline phase of the fatty substituents. The presence of few residual OH groups in PSCEs was responsible for a large increase in the storage bending modulus, and it eliminated the effect of n on damping. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 281–288, 2003 相似文献
22.
Aji P. Mathew Gabriel Groeninckx G. H. Michler H. J. Radusch Sabu Thomas 《Journal of Polymer Science.Polymer Physics》2003,41(14):1680-1696
The effects of the blend ratio and initiating system on the viscoelastic properties of nanostructured natural rubber/polystyrene‐based interpenetrating polymer networks (IPNs) were investigated in the temperature range of ?80 to 150 °C. The studies were carried out at different frequencies (100, 50, 10, 1, and 0.1 Hz), and their effects on the damping and storage and loss moduli were analyzed. In all cases, tan δ and the storage and loss moduli showed two distinct transitions corresponding to natural rubber and polystyrene phases, which indicated that the system was not miscible on the molecular level. However, a slight inward shift was observed in the IPNs, with respect to the glass‐transition temperatures (Tg's) of the virgin polymers, showing a certain degree of miscibility or intermixing between the two phases. When the frequency increased from 0.1 to 100 Hz, the Tg values showed a positive shift in all cases. In a comparison of the three initiating systems (dicumyl peroxide, benzoyl peroxide, and azobisisobutyronitrile), the dicumyl peroxide system showed the highest modulus. The morphology of the IPNs was analyzed with transmission electron microscopy. The micrographs indicated that the system was nanostructured. An attempt was made to relate the viscoelastic behavior to the morphology of the IPNs. Various models, such as the series, parallel, Halpin–Tsai, Kerner, Coran, Takayanagi, and Davies models, were used to model the viscoelastic data. The area under the linear loss modulus curve was larger than that obtained by group contribution analysis; this showed that the damping was influenced by the phase morphology, dual‐phase continuity, and crosslinking of the phases. Finally, the homogeneity of the system was further evaluated with Cole–Cole analysis. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 1680–1696, 2003 相似文献
23.
S.BOUZID Z.AZARI 《宁波大学学报(理工版)》2003,16(4):354-362
冲蚀过程是一个与颗粒反复冲击物体表面而移除物质相关的表面现象.本文研究了玻璃的冲蚀坑的几何尺寸和体积,给出了冲蚀移除物质如何依赖于颗粒流动速度、颗粒尺寸和冲击角的理论关系.通过理论与实验结果相比较,定义了一定冲蚀坑尺度的有效域. 相似文献
24.
25.
含铒碲酸盐玻璃的上转换荧光性质研究 总被引:1,自引:0,他引:1
在室温下,用804nm波长的半导体激光器作激发源,在TeO_2-PbO基掺铒碲酸盐玻璃中实现了中心波长分别为525nm,550nm和660nm的上转换发射.荧光强度与激发功率呈非线性关系.估测了PbO含量对上转换荧光相对强度的影响. 相似文献
26.
Thermal, spectroscopic and electrical properties of lead pyrophosphate glass prepared by melt quenching have been examined.
A model based on the structural disproportionation of the P2O
7
4−
ions has been proposed and is shown to consistently explain all the observations. The equilibrium of various anionic species
has been discussed on the basis of their electronegativities which are in turn related to their basicities.
Communication No. 129 from the Materials Research Centre 相似文献
27.
激光标线的原理和实验 总被引:1,自引:1,他引:0
根据几何光学知识分析了激光标线原理.理论和实验表明:激光标线长度与激光光束形状、光学元件形状及材料折射率有关.并讨论了激光标线向两侧扩展的原因. 相似文献
28.
29.
Novel oxyfluoride glasses are developed with the composition of 30SiO2-15Al2O3-28PbF2-22CdF2-0.1TmF3 - xYbF3 - (4.9 - x) AlF3(x=0, 0.5, 1.0, 1.5, 2.0) in tool fraction, Furthermore, the upconversion luminescence characteristics under a 970nm excitation are investigated. Intense blue, red and near infrared luminescences peaked at 453nm, 476nm, 647nm and 789nm, which correspond to the transitions of Tm^3+: ^1D2 →^3F4, ^1G4 →^3H6, ^1G4 →^3F4, and ^3H4 →^3H6, respectively, are observed. Due to the sensitization of Yb^3+ ions, all the upconversion luminescence intensities are enhanced considerably with Yb^3+ concentration increasing. The upconversion mechanisms are discussed based on the energy matching rule and quadratic dependence on excitation power. The results indicate that the dominant mechanism is the excited state absorption for those upconversion emissions. 相似文献
30.