Dynamic processes in polymeric networks as studied by NMR relaxation methods

By means of NMR pulse methods molecular motions of polymer subchains in crosslinked polystyrene gels are studied. The temperature dependence of the effective transverse relaxation timeT _{2 eff} is explained by a local reorientation process. The local configuration of the elastic chains of the network is shown to be mainly determined by polymer-solvent interaction. The results are compared with those of concentrated solutions. The influence of static-like contributions to the 2nd moments is discussed.     

Local times of continuous N-parameter strong martingales

Let M be a 4N-integrable, real-valued continuous N-parameter strong martingale. By extending Itô-type formulas for M to a function whose 2Nth derivative is Dirac's δ-distribution, Tanaka-type formulas for M are obtained. They represent local time of M with respect to occupation time scaled by the N-fold product of the Stieltjes measure defined by the quadratic variation of M and its kth derivatives in space, where k ≤ N − 1. Applications of Doob's and Burkholder's inequalities give continuity properties: space time continuity for local time, space continuity for the derivatives. In case N is even, for the continuity of the (N − 1)st derivative an additional condition on M is needed which may have a relation to the existence of local times of M w.r.t. different occupation time scales.     

Some of my favorite results with Endre Csáki and Pál Révész - A survey

Summary Some topics of our twenty some years of joint work is discussed. Just to name a few; joint behavior of the maximum of the Wiener process and its location, global and local almost sure limit theorems, strong approximation of the planar local time difference, a general Strassen type theorem, maximal local time on subsets.     

Complexity of local search for the p-median problem

We study the complexity of finding local minima for the p-median problem. The relationship between Swap local optima, 0–1 local saddle points, and classical Karush–Kuhn–Tucker conditions is presented. It is shown that the local search problems with some neighborhoods are tight PLS-complete. Moreover, the standard local descent algorithm takes exponential number of iterations in the worst case regardless of the tie-breaking and pivoting rules used. To illustrate this property, we present a family of instances where some local minima may be hard to find. Computational results with different pivoting rules for random and Euclidean test instances are discussed. These empirical results show that the standard local descent algorithm is polynomial in average for some pivoting rules.     

Complete rank theorem of advanced calculus and singularities of bounded linear operators

Let E and F be Banach spaces, f: U ⊂ E → F be a map of C ^r (r ⩾ 1), x ₀ ∈ U, and ft (x ₀) denote the FréLechet differential of f at x ₀. Suppose that f′(x ₀) is double split, Rank(f′(x ₀)) = ∞, dimN(f′(_{x 0})) > 0 and codimR(f′(x ₀)) s> 0. The rank theorem in advanced calculus asks to answer what properties of f ensure that f(x) is conjugate to f′(x ₀) near x ₀. We have proved that the conclusion of the theorem is equivalent to one kind of singularities for bounded linear operators, i.e., x ₀ is a locally fine point for f′(x) or generalized regular point of f(x); so, a complete rank theorem in advanced calculus is established, i.e., a sufficient and necessary condition such that the conclusion of the theorem to be held is given.      

The effect of structure on the thermoresponsive nature of well‐defined poly(oligo(ethylene oxide) methacrylates) synthesized by ATRP

Statistical copolymers of di(ethylene glycol) methyl ether methacrylate (MEO₂MA) and tri(ethylene glycol) methyl ether methacrylate (MEO₃MA) were synthesized by atom transfer radical polymerization (ATRP) providing copolymers with controlled composition and molecular weights ranging from M_n = 8,300–56,500 with polydispersity indexes (M_w/M_n) between 1.19 and 1.28. The lower critical solution temperature (LCST) of the copolymers increased with the mole fraction of MEO₃MA in the copolymer over the range from 26 to 52 °C. The average hydrodynamic diameter, measured by dynamic light scattering, varied with temperature above the LCST. These two monomers were also block copolymerized by ATRP to form polymers with molecular weight of M_n = 30,000 and M_w/M_n from 1.12 to 1.21. The LCST of the block copolymers shifted toward the LCST of the major segment, as compared to the value measured for the statistical copolymers at the same composition. As temperature increased, micelles, consisting of aggregated PMEO₂MA cores and PMEO₃MA shell, were formed. The micelles aggregated upon further heating to precipitate as larger particles. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 194–202, 2008     

A multiblock/multilevel mesh refinement procedure for CFD computations

A multiblock/multilevel algorithm with local refinement for general two‐ and three‐dimensional fluid flow is presented. The patched‐based local refinement procedure is presented in detail and algorithmic implementations are also presented. The multiblock implementation is essentially block‐unstructured, i.e. each block having its own local curvilinear co‐ordinate system. Refined grid patches can be put anywhere in the computational domain and can extend across block boundaries. To simplify the implementation, while still maintaining sufficient generality, the refinement is restricted to a refinement of the grid successively halving the grid size within a selected patch. The multiblock approach is implemented within the framework of the well‐known SIMPLE solution strategy. Computational experiments showing the effect of using the multilevel solution procedure are presented for a sample elliptic problem and a few benchmark problems of computational fluid dynamics (CFD). Copyright © 2001 John Wiley & Sons, Ltd.     

地方建筑的保护与开发

地方建筑作为一种文化遗产,具有较高的精神和经济价值以及深远的历史意义.当前,由于人们忽视地方建筑的价值,造成地方建筑资源的衰败.对如何正确保护地方建筑这一个重要课题进行了系统的总结和论述.     

带有缺失数据的广义半参数模型的均值借补估计

本文在响应变量随机缺失时, 给出了广义半参数模型中响应变量的2个均值拟似然借补估计.证明了它们具有渐近正态性, 给出了估计的渐近偏差与渐近方差, 并进行模拟比较.     

The synthesis and self‐assembly of ABA amphiphilic block copolymers containing styrene and oligo(ethylene glycol) methyl ether methacrylate in dilute aqueous solutions: Elevated cloud point temperatures for thermoresponsive micelles

A series of ABA amphiphilic triblock copolymers possessing polystyrene (PS) central hydrophobic blocks, one group with “short” PS blocks (DP = 54–86) and one with “long” PS blocks (DP = 183–204) were synthesized by atom transfer radical polymerization. The outer hydrophilic blocks were various lengths of poly(oligoethylene glycol methyl ether) methacrylate, a comb‐like polymer. The critical aggregation concentrations were recorded for certain block copolymer samples and were found to be in the range circa 10⁻⁹ mol L⁻¹ for short PS blocks and circa 10⁻¹² mol L⁻¹ for long PS blocks. Dilute aqueous solutions were analyzed by transmission electron microscopy (TEM) and demonstrated that the short PS block copolymers formed spherical micelles and the long PS block copolymers formed predominantly spherical micelles with smaller proportions of cylindrical and Y‐branched cylindrical micelles. Dynamic light scattering analysis results agreed with the TEM observations demonstrating variations in micelle size with PS and POEGMA chain length: the hydrodynamic diameters (D_H) of the shorter PS block copolymer micelles increased with increasing POEGMA block lengths while maintaining similar PS micellar core diameters (D_C); in contrast the values of D_H and D_C for the longer PS block copolymer micelles decreased. Surface‐pressure isotherms were recorded for two of the samples and these indicated close packing of a short PS block copolymer at the air–water interface. The aggregate solutions were demonstrated to be stable over a 38‐day period with no change in aggregate size or noticeable precipitation. The cloud point temperatures of certain block copolymer aggregate solutions were measured and found to be in the range 76–93 °C; significantly these were ∼11 °C higher in temperature than those of POEGMA homopolymer samples with similar chain lengths. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 7739–7756, 2008