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141.
Zhitian Liu Lei Wang Junwu Chen Feng Wang Xiaoying Ouyang Yong Cao 《Journal of polymer science. Part A, Polymer chemistry》2007,45(5):756-767
2,5‐Bis(2‐bromofluorene‐7‐yl)silole was prepared by a modified one‐pot synthesis with a reverse addition procedure, from which novel silole‐containing polyfluorenes with binary random and alternating structures (silole contents between 4.5 and 25% and high Mw up to 509 kDa were successfully synthesized. The well‐defined repeating unit of the alternating copolymer comprises a terfluorene and a silole ring. Optoelectronic properties including UV absorption, electrochemistry, photoluminescence (PL), and electroluminescence (EL) of the copolymers were examined. The different excitation energy transfers from fluorene to silole of the copolymers in solution and in the solid state were compared. The films of the copolymers showed silole‐dominant green emissions with high absolute PL quantum yields up to 83%. EL devices of the copolymers with a configuration of ITO/PEDOT/copolymer/Ba/Al displayed exclusive silole emissions peaked at around 543 nm and the highest EL efficiency was achieved with the alternating copolymer. Using the alternating copolymer and poly(9,9‐dioctylfluorene) as the blend‐type emissive layer, a maximum external quantum efficiency of 1.99% (four times to that of the neat film) was realized, which was a high efficiency so far reported for silole‐containing polymers. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 756–767, 2007 相似文献
142.
Brillouin spectroscopy was used to study elastic properties of the Si (1 1 1) decorated with Ni nanostructures deposited by nanospherical lithography. The height of the nickel nanostructure deposited was about 25 nm, while the area taken by the structure differed depending on the type of matrix used. It was found that the Ni nanostructures change the velocity of both bulk and surface phonons in the systems studied. This finding is in contradiction to the results concerning the surface phonons velocities in different media covered with a homogenous thin metal film, in which the effect was observed for films thicker than 70 nm. 相似文献
143.
本文采用解析的方法计算了应变Si1-xGex层中p型杂质电离度与Ge组分x、温度T以及掺杂浓度N的关系.发现常温时,在同一Ge组分下,随着掺杂浓度的升高,杂质的电离度的先变小,而后又迅速上升到1.在同一掺杂浓度下,轻掺杂时,杂质的电离度随Ge组分的增加先变大,而后几乎不变;重掺杂时,杂质电离能变为0后,杂质电离度为1.低温下,轻掺杂时,载流子低温冻析效应较为明显,杂质的电离度普遍较小,当掺杂浓度大于Mott转换点时,载流子冻析效应不再明显,电离率迅速上升到1.在同一Ge组分下,随着掺杂浓度的升高,杂质的电离度先变小,后变大,而后又迅速上升到1.在同一掺杂浓度下,轻掺杂时,杂质的电离度随Ge组分的增加变大;重掺杂时,杂质电离能变为0后,杂质电离度为1. 相似文献
144.
145.
氩气介质阻挡放电的发光特性 总被引:1,自引:0,他引:1
本文使用水电极介质阻挡放电装置,采用光学方法测量了氩气介质阻挡放电的发光特性。发现在驱动电压处于一定的范围内时,放电处于丝极模式,在驱动电压的每半周期内,无论是放电的总光还是单个微通道的放电发光均只有一次脉冲,单个微放电的时间为2μs,而总放电时间为2.4μs,这表明在氩气的丝极模式中,各单丝产生与熄灭的时间极其接近,各个放电丝之间有着很好的时间相关性。最后将本文的结果与空气中介质阻挡放电丝极模式的发光特性相比较,空气放电在每半周内的总光信号由多个脉冲组成,而每一个脉冲对应多个放电丝,因而氩气中各个放电微通道之间的时间相关性远强于空气的情况。 相似文献
146.
Small‐Angle Neutron Scattering has been performed from poly(ethylene oxide) in deuterated water at temperature ranging from 10 to 80 °C. A simple fitting model was used to obtain a correlation length and a Porod exponent. The correlation length L characterizes the average distance between entanglements in the semidilute region and is proportional to the individual coil sizes in the dilute region. L was found to increase with temperature in the semidilute region but it decreases with temperature in the dilute region. This decrease is the precursor to the single‐chain collapse which applies to very dilute polymer solutions. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 2196–2200, 2007 相似文献
147.
Considering a plane hyperbolic system with time-periodic coefficients, we construct a version of the direct Lyapunov method with the condition on the derivative of the Lyapunov functional along the trajectories of the system which is weakened by use of periodicity of the coefficients. We exhibit an illustrative example. 相似文献
148.
Arman Melkumyan 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》2007,58(2):330-349
The problem of electric and acoustic waves diffraction by a half-plane crack in a transversal isotropic piezoelectric medium
is investigated. The crack is assumed to be electric permeable and free of tractions. The so-called “quasi-hyperbolic approximation”
[15] is adopted. Applying Laplace transformations and Wiener–Hopf technique a closed form solution is obtained. By the means
of Cagniard–de Hoop method a detailed dynamic full electroacoustic wavefield’s investigation is conducted. Mode conversion
between electric and acoustic waves, effect of electroacoustic head wave, Bleustein–Gulyaev surface wave and the wavefield
structure depending on the type of the incident wave (acoustic or electric) and its angle of incidence are analyzed in details.
The dynamic field intensity factors at the crack tip depending on the angle of incidence and on time are derived explicitly.
Numerical analysis is presented. 相似文献
149.
成功制备了结构为ITO/PDDOPV/PPQ/Al的异质结聚合物发光二极管。该器件在正反向偏压下均可发光。在正向偏压下的光发射主要来自PDDOPV,但在反向偏压下的光发射则包括来自PPQ的蓝光发射和PDDOPV的黄光发射。蓝光强度与黄光强度的比值随着反向偏压的增加而增加,当反向直流电压分别为22V、24V、26V、28V时,其电致发光光谱中PPQ与PDDOPV的峰高比IPPQ/IPDDOPV分别为1.092、1.329、1.605、2.046。换句话说,该器件的发光颜色是压控可调的,这对实现彩色显示是极为有利的。分析了在反向偏压下的发光机理以及IPPQ/IPDDOPV受电压控制的原因。 相似文献
150.