White electroluminescence from a single polyfluorene containing bis‐DCM units

A series of fluorene‐based copolymers composed of blue‐ and orange‐light‐emitting comonomers were synthesized through palladium‐catalyzed Suzuki coupling reactions. 9,9‐Dihexylfluorene and 2‐(2,6‐bis‐{2‐[1‐(9,9‐dihexyl‐9H‐fluoren‐2‐yl)‐1,2,3,4‐tetrahydroquinolin‐6‐yl]‐vinyl}‐pyran‐4‐ylidene)‐malononitrile (DCMF) were used as the blue‐ and orange‐light‐emitting chromophores, respectively. The resulting single polymers exhibited simultaneous blue (423/450 nm) and orange (580–600 nm) emissions from these two chromophores. By adjusting the fluorene and DCMF contents, white light emission could be obtained from a single polymer; a device with an ITO/PEDOT:PSS/polymer/Ca/Al configuration was found to exhibit pure white electroluminescence with Commission Internationale de L'Eclairage (CIE) coordinates of (0.33, 0.31), a maximum brightness of 1180 cd/m², and a current efficiency of 0.60 cd/A. Furthermore, the white light emission of this device was found to be very stable with respect to variation of the driving voltage. The CIE coordinates of the device were (0.32, 0.29), (0.32, 0.29), and (0.33, 0.31) for driving voltages of 7, 8, and 10 V, respectively. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3380–3390, 2007     

大粒子对高斯波束散射的数值模拟

基于广义米氏理论，精确的求解了球形粒子对高斯波束和平面波的散射，采用Matlab编程， 改进了计算方法，所能够计算的粒子的尺寸参数已突破80000. 给出了平面波与高斯波入射 时，均匀粒子以及镀层粒子的散射分布，比较了吸收粒子和非吸收粒子散射分布. 关键词： 广义米氏理论 高斯波束 光散射 波束因子     

Synthesis,photophysics, structure‐tunable photoluminescence,and electrochemical properties of soluble poly(p‐phenylenevinylene)‐based polymers with adjacent 1,3,4‐oxadiazoles in the backbone

Three new poly(p‐phenylenevinylene)‐based polymers containing two 1,3,4‐oxadiazole moieties in the main chain per repeat unit were synthesized by Heck coupling. A single, double, or triple bond was introduced between the oxadiazoles to provide a means for modifying the polymer properties. The polymers were readily soluble in common organic solvents and showed T_g values lower than 50 °C. The color of the emissive light in both the solid state and the solution could be tuned by a change in the nature of the bond between the oxadiazole rings. The polymers emitted ultraviolet‐green light in solution with a photoluminescence (PL) emission maximum at 345–483 nm and blue‐green light at 458–542 nm in thin films. The PL quantum yields in solution were 0.36–0.43. The electrochemical properties are affected by the nature of the bond between the oxadiazoles as well. In polymers with a single bond between the oxadiazoles, a lower ionization potential was observed than in polymers with a double or triple bond. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 3079–3090, 2005     

Synthesis and self‐assembly of highly incompatible polybutadiene–poly(hexafluoropropylene oxide) diblock copolymers

A versatile coupling reaction for the preparation of polybutadiene–poly‐(hexafluoropropylene oxide) (BF) diblock copolymers is described. Six diblock copolymers with different block lengths were characterized by nuclear magnetic resonance spectroscopy and size exclusion chromatography; all six had total molecular weights below 15,000. Microphase separation of the block copolymers in the bulk state was established by small‐angle X‐ray scattering (SAXS) and differential scanning calorimetry. SAXS data suggest that the diblocks are characterized by an unusually large Flory‐Huggins interaction parameter, χ, on the order of 10. However, extraction of χ from the order–disorder transition gave large (order 1) but significantly different values, thereby suggesting that these copolymers are too small and too strongly interacting to be described by block copolymer mean‐field theory. Dynamic light scattering was used to analyze dilute solutions of the title block copolymers in four selective organic solvents; the sizes of the micelles formed were solvent dependent. The micellar aggregates were large and nonspherical, and this is also attributed to the high degree of incompatibility between the two immiscible blocks. © 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 43: 3685–3694, 2005     

Investigation of the Effective Space–Time of the Vacuum Nonlinear Electrodynamics in a Magnetic Dipole Field

The metric tensor of the effective pseudo-Riemannian space–time for an electromagnetic wave propagating in the magnetic dipole field and the gravitational field of a neutron star is obtained within a parameterized post-Maxwellian vacuum electrodynamics. The angles of the nonlinear electrodynamic and gravitational ray bending for electromagnetic waves propagating in the magnetic equatorial plane of the star are calculated based on an analysis of isotropic geodesics of this space. We show that for all nonlinear theories whose post-Maxwellian parameters do not coincide, the velocity of the electromagnetic signal propagation in external fields and the rays along which these signals propagate depend on the polarization of the electromagnetic waves. The difference of the source-to-detector propagation time of these signals for two principal polarization states is calculated.     

用于激光吸收和散射光能量测量的4π盒式卡计

报道了国内第一台用于ＩＣＦ实验散射光和激光吸收能量精密测量的４π盒式卡计。性能测试表明，该盒式卡计的性能优于国外用热电堆作传感元件的盒式卡计的性能。     

CCD自动调光设计

介绍一种在89C51单片机的智能控制系统中,用A/D536等器件组成的真有效值电路作为CCD视频信号的检测电路,采取程序控制方式对天空背景下的目标进行自动调光控制.     

季氨盐对KDP晶体的光学特性影响

 生长了不同季氨盐掺杂浓度的KDP晶体，其锥光干涉实验显示了晶体的内应力引起的双折射和双轴晶特性较明显。透过率特性的实验结果表明，不同浓度的季氨盐对KDP晶体的光学均匀性有较大影响。报道了掺季氨盐0.001%的KDP晶体的异常光学透过率特性以及晶体具有三维变化的波片效应和旋光特性。     

Nucleon Spin Structure Functions in the Resonance Region and the Duality

We discuss the nucleon spin structure function gl and the difference between the proton and neutrontargets gp1 - gn1 , based on quark model calculation. Quark-hadron duality for the nucleon spin structure function is alsoanalyzed. Effects of the △(1232) and Roper P11(1440) resonances on the spin structure function and on the differencegn1 - gn1 are mentioned. The results of different models for the Roper resonance are also addressed.     

具有光照强度不变性的显微细胞图像处理算法

显微图像受光源光照强度的影响很大,研究了不受光照强度影响的显微细胞图像的增强技术。对显微灰度图像,用Top Hat算法对细胞进行了突出;对于显微彩色图像,先由图像的RGB空间变换到IHS(Intensity,HueandSaturation)空间,然后,通过对分量提取细胞的颜色信息。实验表明,以上两种方法消除了光照强度变化对图像的影响。