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91.
根据原子分子反应静力学和群论,确定TiH2,TiD2和TjT2的基电子状态为^3A2.应用基函数6-311G^**和密度泛函理论B3P86方法,全电子计算了氢同位素分子及其钛化物的能量E、定容热容Cv和熵S应用电子振动近似理论,即用单个分子TiH2,TiD2和TjT2中的电子和振动能量和熵近似代表他们处于固态时的能量和熵,计算所得到的金属钛的氢化热力学函数△Hc^0,△S^0,△G^0以及平衡压力与温度的关系,与文献符合很好,这表明电子振动近似理论的可应用性,选用金属钛作为中子靶是很正确的。 相似文献
92.
基于简单碰撞理论煤粉燃烧动力学模型的研究-PART Ⅲ:氧气可达比表面积 总被引:1,自引:1,他引:1
根据不同温度下氧分子平均自由程的大小,比较了小孔、中孔和大孔中三种扩散速率与煤焦表面燃烧速度的大小.研究表明2000 K以内,颗粒表面分子扩散速率比氧化反应速率大1个数量级以上,过度扩散速率不小于氧化速率.温度小于1200K时,燃烧速率比Knudsen扩散速率小1~5个数量级,扩散孔径小于15~28 nm,反应主要在内外表面进行;1200~1600K时,燃烧速率与Knudsen扩散速率相当,扩散临界孔径28~38 nm,反应在外表面及浅层内表面进行;温度1600K以上时,Knudsen扩散速率比燃烧速率小1个数量级,孔径38~50 nm以下内表面上碳的氧化速度受扩散控制.煤焦的氧化主要发生在Knudsen扩散临界孔径10~50 nm以上的氧气可达表面上. 相似文献
93.
D. Valenti L. Schimansky-Geier X. Sailer B. Spagnolo 《The European Physical Journal B - Condensed Matter and Complex Systems》2006,50(1-2):199-203
The dynamics of a spatially extended system of two competing
species in the presence of two noise sources is studied. A
correlated dichotomous noise acts on the interaction parameter and
a multiplicative white noise affects directly the dynamics of the
two species. To describe the spatial distribution of the species
we use a model based on Lotka-Volterra (LV) equations. By writing
them in a mean field form, the corresponding moment equations for
the species concentrations are obtained in Gaussian approximation.
In this formalism the system dynamics is analyzed for different
values of the multiplicative noise intensity. Finally by comparing
these results with those obtained by direct simulations of the
time discrete version of LV equations, that is coupled map lattice
(CML) model, we conclude that the anticorrelated oscillations of
the species densities are strictly related to non-overlapping
spatial patterns. 相似文献
94.
B. Spagnolo A. Dubkov 《The European Physical Journal B - Condensed Matter and Complex Systems》2006,50(1-2):299-303
The one-dimensional overdamped Brownian motion in a symmetric
periodic potential modulated by external time-reversible noise is
analyzed. The calculation of the effective diffusion coefficient
is reduced to the mean first passage time problem. We derive
general equations to calculate the effective diffusion coefficient
of Brownian particles moving in arbitrary supersymmetric potential
modulated by: (i) an external white Gaussian noise and (ii) a
Markovian dichotomous noise. For both cases the exact expressions
for the effective diffusion coefficient are derived. We obtain
acceleration of diffusion in comparison with the free diffusion
case for fast fluctuating potentials with arbitrary profile and
for sawtooth potential in case (ii). In this case the parameter
region where this effect can be observed is given. We obtain also
a finite net diffusion in the absence of thermal noise. For
rectangular potential the diffusion slows down, for all parameters
of noise and of potential, in comparison with the case when
particles diffuse freely. 相似文献
95.
P. H. Chavanis 《The European Physical Journal B - Condensed Matter and Complex Systems》2008,62(2):179-208
We study a general class of nonlinear mean field
Fokker-Planck equations in relation with an effective generalized
thermodynamical (E.G.T.) formalism. We show that these equations describe
several physical systems such as: chemotaxis of bacterial
populations, Bose-Einstein condensation in the canonical ensemble,
porous media, generalized Cahn-Hilliard equations, Kuramoto model,
BMF model, Burgers equation, Smoluchowski-Poisson system for
self-gravitating Brownian particles, Debye-Hückel theory of
electrolytes, two-dimensional turbulence... In particular, we show
that nonlinear mean field Fokker-Planck equations can provide
generalized Keller-Segel models for the chemotaxis of
biological populations. As an example, we introduce a new model of
chemotaxis incorporating both effects of anomalous diffusion and
exclusion principle (volume filling). Therefore, the notion of
generalized thermodynamics can have applications for concrete
physical systems. We also consider nonlinear mean field
Fokker-Planck equations in phase space and show the passage from
the generalized Kramers equation to the generalized Smoluchowski
equation in a strong friction limit. Our formalism is simple and
illustrated by several explicit examples corresponding to Boltzmann,
Tsallis, Fermi-Dirac and Bose-Einstein entropies among others. 相似文献
96.
姿态倾斜对时-空联合调制型干涉成像光谱仪成像质量的影响 总被引:1,自引:0,他引:1
时空联合调制型干涉成像光谱仪获取的像面干涉图是带有干涉条纹的二维空间图像,具有对姿态变化敏感的特点.根据该类仪器的成像过程,在竖直摄影时,相邻两帧像面干涉图之间的像移量为一列像元;偏离竖直摄影时,由于像面干涉图的几何变形或旋转,会引入非正常像移.利用共线方程导出了这一非正常像移量的表达式.利用仿真计算说明:这一非正常像移会在像面干涉图序列中不断积累,导致提取出的物体干涉信息失真.在竖直摄影而平台指向精度较低、倾斜摄影、探测器阵列的安装方向精度较低或者航空成像且存在偏流角时,必须对像面干涉图进行有效校正,才能保证最终反演出的物体光谱的真实性. 相似文献
97.
基于频谱分析的匀速运动模糊图像模糊方向识别 总被引:5,自引:0,他引:5
点扩展函数的设置是图像复原中的关键问题,对于匀速直线运动模糊图像,运动方向和模糊长度决定了点扩展函数。根据运动模糊图像和原始图像在频谱上存在的对应关系,即运动模糊图像频谱存在着对应于传递函数零点的暗条纹,提出对运动模糊图像,通过二维傅里叶变换、二值化以及Radon变换检测运动模糊图像频谱图上暗条纹的方向和位置,来实现运动方向测量的方法。用该方法对模糊图像进行检测,模糊方向的识别精度小于1°。实验证明该方法可以实现平面内任意方向运动的测量。 相似文献
98.
运用量子信息熵理论,研究了二项式光场与运动二能级原子相互作用过程中运动原子的信息熵压缩。讨论了不同的原子初态和场的有关参数对原子信息熵压缩的影响。结果表明:选择原子初态、场模结构、场调节参数及原子运动速度可以调控原子信息熵的压缩方向、偶极矩分量值和压缩周期;适当的选择参数可得到持续性的原子信息熵压缩。 相似文献
99.
A. Shabunin A. Efimov 《The European Physical Journal B - Condensed Matter and Complex Systems》2008,65(3):387-393
A spatio-temporal process in the Lattice Lotka Volterra (LLV) model, when realized on low dimensional support, is studied.
It is shown that the introduction of a long-range mixing causes a drastic change in the system’s behavior, which transits
from small random-like fluctuations to global oscillations when the mixing rate transcends above a critical point. The amplitude
of the induced oscillations is well defined by the mixing rate and is insensitive to the initial conditions and the lattice
size variations. The observed behavior essentially differs from that predicted by the Mean-Field model which is conservative.
The oscillations are of limit-cycle type and appear as a stochastic analog of a Hopf bifurcation. 相似文献
100.
A. Fiasconaro W. Ebeling E. Gudowska-Nowak 《The European Physical Journal B - Condensed Matter and Complex Systems》2008,65(3):403-414
We give an overview over recent studies on the model of Active Brownian Motion (ABM) coupled to reservoirs providing free
energy which may be converted into kinetic energy of motion. First, we present an introduction to a general concept of active
Brownian particles which are capable to take up energy from the source and transform part of it in order to perform various
activities. In the second part of our presentation we consider applications of ABM to ratchet systems with different forms
of differentiable potentials. Both analytical and numerical evaluations are discussed for three cases of sinusoidal, staircaselike
and Mateos ratchet potentials, also with the additional loads modelled by tilted potential structure. In addition, stochastic
character of the kinetics is investigated by considering perturbation by Gaussian white noise which is shown to be responsible
for driving the directionality of the asymptotic flux in the ratchet. This stochastically driven directionality effect is visualized as a strong nonmonotonic dependence of the statistics of the right versus left trajectories of motion
leading to a net current of particles. Possible applications of the ratchet systems to molecular motors are also briefly discussed. 相似文献