全文获取类型
收费全文 | 2809篇 |
免费 | 611篇 |
国内免费 | 183篇 |
专业分类
化学 | 541篇 |
晶体学 | 9篇 |
力学 | 300篇 |
综合类 | 62篇 |
数学 | 918篇 |
物理学 | 1773篇 |
出版年
2024年 | 4篇 |
2023年 | 21篇 |
2022年 | 58篇 |
2021年 | 50篇 |
2020年 | 51篇 |
2019年 | 54篇 |
2018年 | 72篇 |
2017年 | 112篇 |
2016年 | 120篇 |
2015年 | 87篇 |
2014年 | 179篇 |
2013年 | 197篇 |
2012年 | 183篇 |
2011年 | 204篇 |
2010年 | 167篇 |
2009年 | 199篇 |
2008年 | 202篇 |
2007年 | 183篇 |
2006年 | 164篇 |
2005年 | 146篇 |
2004年 | 150篇 |
2003年 | 121篇 |
2002年 | 120篇 |
2001年 | 109篇 |
2000年 | 99篇 |
1999年 | 81篇 |
1998年 | 94篇 |
1997年 | 63篇 |
1996年 | 63篇 |
1995年 | 47篇 |
1994年 | 22篇 |
1993年 | 30篇 |
1992年 | 23篇 |
1991年 | 21篇 |
1990年 | 14篇 |
1989年 | 15篇 |
1988年 | 13篇 |
1987年 | 9篇 |
1986年 | 9篇 |
1985年 | 6篇 |
1984年 | 7篇 |
1983年 | 4篇 |
1982年 | 6篇 |
1981年 | 6篇 |
1980年 | 5篇 |
1979年 | 4篇 |
1978年 | 2篇 |
1977年 | 3篇 |
1973年 | 1篇 |
1971年 | 2篇 |
排序方式: 共有3603条查询结果,搜索用时 15 毫秒
81.
Emerging fields of biochemical research, such as metabolomics, present challenges to current separation technologies because of the large number of metabolites present in a cell and their often low (submicromolar) concentration. Although capillary electrophoresis (CE) holds great promise as the method of choice for high-resolution separations of biological samples, it suffers from poor concentration sensitivity, especially with the use of UV detection. In CE, sweeping and dynamic pH junction represent two complementary on-line focusing techniques that have been used for sensitivity enhancement of hydrophobic and weakly acidic analytes, respectively. However, the application of either the sweeping or dynamic pH junction technique alone might, in some cases, be less effective for the analysis of certain sample mixtures. Recent work in the development of a hyphenated dynamic pH junction-sweeping technique is presented as an effective on-line method of preconcentration suitable for both hydrophilic (anionic) and hydrophobic (neutral) analytes. Sensitive analyses of flavin metabolites by CE with laser-induced fluorescence (LIF) detection is demonstrated in various biological matrixes, including cell extracts of Bacillus subtilis, pooled human plasma, as well as heat-deproteinized flavoenzymes. Enhanced analyte band narrowing and improved sensitivity is achieved for flavins using dynamic pH junction-sweeping compared to either sweeping or dynamic pH junction alone. This results in over a 1200-fold improvement in sensitivity relative to conventional injection methods, giving a limit of detection (LOD, defined as S/N = 3) of about 4.0 x 10(-12) M. Strategies for sensitive and more comprehensive analyses of other cell metabolites, including nucleotides, coenzymes, and steroids, are also discussed when using on-line focusing techniques in conjunction with multiplexed CE and UV detection. 相似文献
82.
A high-powered, microwave-induced nitrogen–oxygen plasma (N2–O2–MIP) generated by using an Okamoto cavity at atmospheric pressure was investigated when the observation height, the flow rate of carrier gas, and the oxygen content were varied as the experimental parameters. The emission characteristics of the plasma were evaluated with regard to the excitation temperature and the intensity ratio of atomic line to ionic line. The excitation temperature of the N2–O2–MIP was in the range of 5100–5700 K when the oxygen content was varied from 0 to 30% at the observation height of 7 mm and the carrier gas flow rate of 0.6 l/min. The intensity ratio of atomic line to ionic line was elevated with an increase in the oxygen content. 相似文献
83.
流动注射萃取火焰原子吸收光谱法测定硫酸镍电解液中微量铅 总被引:1,自引:4,他引:1
本文采用流动注射在线萃取火焰原子吸收光谱法测定硫酸电解液中微量铅,考察了水相介质,共存离子,萃取装置,相比等因素的影响。分析含铅1.4mg/L和0.16mg/L的试样,分析值的相对标准偏差(n=10)分别为3.9%和12.3%,方法检出限为0.024mg/L。 相似文献
84.
Development of a stabilized low temperature infrared absorption cell for use in low temperature and collisional cooling experiments 总被引:1,自引:0,他引:1
Valentin A Henry A Claveau C Camy-Peyret C Hurtmans D Mantz AW 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2004,60(14):227-3482
We have constructed a stabilized low temperature infrared absorption cell cooled by an open cycle refrigerator, which can run with liquid nitrogen from 250 to 80K or with liquid helium from 80K to a few kelvin. Several CO infrared spectra were recorded at low temperature using a tunable diode laser spectrometer. These spectra were analyzed taking into account the detailed effects of collisions on the line profile when the pressure increases. We also recorded spectra at very low pressure to accurately model the diode laser emission. Spectra of the R(2) line in the fundamental band of 13CO cooled by collisions with helium buffer gas at 10.5K and at pressures near 1 Torr have been recorded. The He-pressure broadening parameter (gamma(0) = 0.3 cm(-1) atm(-1)) has been derived from the simultaneous analysis of four spectra at different pressures. 相似文献
85.
86.
文中通过对变频控制直接膨胀式太阳能热泵的数值模拟,指出PV/T- SAHP系统实现变频控制从而解决太阳能热泵集热器面积与压缩机的容量不匹配的关键问题是找到系统集热/蒸发器的MSS线.为变工况下太阳能热泵系统的研究提供参考. 相似文献
87.
Stefan Langer 《International Journal of Computational Fluid Dynamics》2013,27(3):131-150
For unstructured finite volume methods, we present a line implicit Runge–Kutta method applied as smoother in an agglomerated multigrid algorithm to significantly improve the reliability and convergence rate to approximate steady-state solutions of the Reynolds-averaged Navier–Stokes equations. To describe turbulence, we consider a one-equation Spalart–Allmaras turbulence model. The line implicit Runge–Kutta method extends a basic explicit Runge–Kutta method by a preconditioner given by an approximate derivative of the residual function. The approximate derivative is only constructed along predetermined lines which resolve anisotropies in the given grid. Therefore, the method is a canonical generalisation of point implicit methods. Numerical examples demonstrate the improvements of the line implicit Runge–Kutta when compared with explicit Runge–Kutta methods accelerated with local time stepping. 相似文献
88.
针对目前各行业数字化、智能化产品应用日趋广泛,数据的获取、传输、分析、应用尤为重要,如何避免采集设备接口单一、功能固定、实用性差等缺点,提出采用ARM嵌入式工控模块M9080-N20为基础,采用VK3266串口芯片扩展UART串行接口,提出基于73K222AU调制解调器、HR219307变压器实现采集器二线模拟通信,并支持以太网、CAN总线和UART串行通信,可以有效解决数据远程采集、传输和控制,适用于特殊环境设备故障检测、诊断和抢修。实验结果证明,智能数据采集器不仅具有多种型号设备故障诊断功能;还能实现野外快速通信组网,不同类型设备数据远程采集、传输、分析和控制功能,在军民融合产品上具有广阔的应用前景和实用价值。 相似文献
89.
Mohamed Charif Soufiane El Adraoui Mounirh Khalid Asmaa Zugari Mohamed I. Yaich Mohsine Khalladi 《Optik》2014
The current density (JE), the piecewise linear recursive convolution (PLRC) and the constant convolution recursive (CRC) techniques are developed and integrated into the transmission line matrix (TLM) algorithm. A comparison of these three schemes according to the criteria of accuracy and CPU time is presented. Numerical experiments show that JE provides the most accurate solution and requires the least CPU time; PLRC is nearly as accurate but consumes more CPU time than CRC. 相似文献
90.
Oliver Salazar Celis Annie Cuyt Dirk Deschrijver Dries Vande Ginste Tom Dhaene Luc Knockaert 《Applied Mathematical Modelling》2013
In this paper a novel macromodeling scheme is presented to model the per unit of length (p.u.l.) parameters of uniform transmission lines. In particular, it is focused on single on-chip interconnects, because their p.u.l. parameters are influenced by the presence of semiconductor (s) and as such exhibit a strong frequency-dependency, making the modeling process harder. Starting from a set of very accurate tabulated data samples, obtained by two-dimensional electromagnetic modeling, rational models for the four p.u.l. parameters are constructed. The novelty of the approach lies in the fact that the rational models are positive by construction and that a controllable accuracy is obtained. These models can then further be used to construct multivariate models, e.g., for variability analysis. Here, the novel scheme is applied to an on-chip inverted embedded microstrip line, of which the signal integrity behavior is assessed in both the frequency and the time domain, demonstrating the applicability of the macromodels. 相似文献