首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   2806篇
  免费   613篇
  国内免费   183篇
化学   540篇
晶体学   9篇
力学   300篇
综合类   62篇
数学   918篇
物理学   1773篇
  2024年   4篇
  2023年   21篇
  2022年   57篇
  2021年   50篇
  2020年   51篇
  2019年   54篇
  2018年   72篇
  2017年   112篇
  2016年   120篇
  2015年   87篇
  2014年   179篇
  2013年   197篇
  2012年   183篇
  2011年   204篇
  2010年   167篇
  2009年   199篇
  2008年   202篇
  2007年   183篇
  2006年   164篇
  2005年   146篇
  2004年   150篇
  2003年   121篇
  2002年   120篇
  2001年   109篇
  2000年   99篇
  1999年   81篇
  1998年   94篇
  1997年   63篇
  1996年   63篇
  1995年   47篇
  1994年   22篇
  1993年   30篇
  1992年   23篇
  1991年   21篇
  1990年   14篇
  1989年   15篇
  1988年   13篇
  1987年   9篇
  1986年   9篇
  1985年   6篇
  1984年   7篇
  1983年   4篇
  1982年   6篇
  1981年   6篇
  1980年   5篇
  1979年   4篇
  1978年   2篇
  1977年   3篇
  1973年   1篇
  1971年   2篇
排序方式: 共有3602条查询结果,搜索用时 484 毫秒
151.
李志平  方捻  陈克亚  王陆唐  黄肇明 《光子学报》2007,36(10):1858-1861
提出了两种适用于光突发交换网的可编程光缓存器结构:交叉型和多端口开关型.两种结构都能满足突发包缓存的超长性和可变性的要求,且结构简单紧凑,成本低,可扩展.交叉型缓存器通过指定信号在每个子缓存模块的光纤环中的循环次数即能实现可变时间的延迟.多端口开关型缓存器通过指定信号在两个多端口开关相应端口与所接光纤延迟线组成的光纤环中的循环次数实现可变时间的延迟.仿真结果表明,两种可编程光缓存器都能对光突发包实现ns级指定时间延迟,可用于解决光突发交换网突发包的冲突问题.  相似文献   
152.
高温氧化-化学发光检测法测定水中总氮   总被引:2,自引:0,他引:2  
采用高温氧化-化学发光检测法(high temperature oxidation & chemiluminescence, HTO-CL)进行水质总氮(TN)的在线测定。总氮浓度(CN)与化学发光的强度(IN)呈良好的线性关系,线性区间为0.05~100mg/L。对真实水样采用本方法进行测定,其结果与国标方法相符,回收率在90%~110%之间。以本方法为工作原理的TN-2000型总氮测定仪可用于地表水质及污水的在线监测。  相似文献   
153.
《光谱学快报》2013,46(3):303-318
Abstract

Open‐path Fourier transform infrared (FTIR) spectrometry was used to continuously monitor 11 chlorinated hydrocarbon species in the region connecting two different industrial complexes for 24 hr. The single‐beam spectra obtained from open‐path FTIR were analyzed by newly developed software named COL1SB, which generates site‐specific background spectra as well as path‐averaged water vapor concentrations in addition to performing regression analyses. The path‐averaged water vapor concentrations calculated by the COL1SB agreed very well with those measured by a thermo‐hygrometer. In addition, site‐specific background spectra were generated by accounting for chemical absorption of 50 chemical species. The accurate estimation of path‐averaged water vapor concentrations, as well as the usage of site‐specific background spectra, enables chlorinated hydrocarbons to be measured by open‐path FTIR spectrometry at the ppb level. Among 11 chlorinated hydrocarbons considered here, trichlorofluoromethane, carbon tetrachloride, trichloroethylene, and tetrachloroethylene were identified as major chlorinated hydrocarbons having concentrations above 1 ppb. Wind affected the temporal variations of these chlorinated hydrocarbons, indicating the importance of local transport. However, the effect of wind differed from one species to another because of different source characteristics.  相似文献   
154.
The inverse problem of the scattering theory for Sturm–Liouville operator on the half line with boundary condition depending quadratic on the spectral parameter is considered. Scattering data are defined, some properties of the scattering data are examined, the main equation is obtained, solvability of the integral equation is proved and uniqueness of algorithm to the potential with given scattering data is studied. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   
155.
矩形毛细微槽中三角形区域接触线特性的研究   总被引:1,自引:0,他引:1  
利用CCD和宽视场体视显微镜相结合的技术,拍摄了矩形毛细微槽内液体工质在三角形区域的润湿图像,并进行了图像处理,研究结果表明:随着热流密度的增加,三角形区域内的三相接触线向微槽底角收缩,导致三相接触线的长度减小,液膜厚度减小;随着微槽深度的增加,三角形区域的接触线长度减小;随着微槽宽度和倾斜角度的增加,三角形区域内的接触线长度增加,液膜厚度增加.  相似文献   
156.
157.
158.
Benchtop NMR emerges as an appealing alternative to widely extend the scope of NMR spectroscopy in harsh environments and for on‐line monitoring. Obviously, the use of low‐field magnets induces a dramatic reduction of the spectral resolution leading to frequent peak overlaps. This issue is even more serious because applications such as chemical process monitoring involve the use of non‐deuterated solvents, leading to intense and broad peaks overlapping with the signals of interest. In this article, we highlight the need for efficient suppression methods compatible with flowing samples, which is not the case of the common pre‐saturation approaches. Thanks to a gradient coil included in our benchtop spectrometer, we were able to implement modern and efficient solvent suppression blocks such as WET or excitation sculpting to deliver quantitative spectra in the conditions of the on‐line monitoring. While these methods are commonly used at high field, this is the first time that they are investigated on a benchtop setting. Their analytical performance is evaluated and compared under static and on‐flow conditions. The results demonstrate the superiority of gradient‐based methods, thus highlighting the relevance of implementing this device on benchtop spectrometers. The comparison of major solvent suppression methods reveals an optimum performance for the WET‐180‐NOESY experiment, both under static and on‐flow conditions. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   
159.
Continuous and pulsed 12 keV electron beams were used to excite nitrogen within a gas cell at pressures ranging from 10 to 1400 hPa. The pressure dependence of the ratio of photon fluxes for emission from vibrational levels v'=0 and 1 of the C 3Π u state has been studied. The results confirm the presence of a collisional excitation mechanism populating v'=0, 1 in addition to electron impact excitation. Rate constants of (1.27 ±0.04)×10-11 cm3s-1 [ v'=0] and (2.68 ±0.08)×10-11 cm3s-1 [ v'=1] were measured for C 3Π u quenching by ground state nitrogen. For electron beam conditions relative excitation efficiencies of 1:0.59:0.22 for vibrational levels 0, 1 and 2 were calculated. The recorded flux ratios are compared with the predictions given by a vibrational relaxation model.  相似文献   
160.
The design of the China Spallation Neutron Source (CSNS) low-energy beam transport (LEBT) line, which locates between the ion source and the radio-frequency quadrupole (RFQ), has been completed with the TRACE3D code. The design aims at perfect matching, primary chopping, a small emittance growth and sufficient space for beam diagnostics. The line consists of three solenoids, three vacuum chambers, two steering magnets and a pre-chopper. The total length of LEBT is about 1.74 m. This LEBT is designed to transfer 20 mA of H-pulsed beam from the ion source to the RFQ. An induction cavity is adopted as the pre-chopper.The electrostatic octupole steerer is discussed as a candidate. A four-quadrant aperture for beam scraping and beam position monitoring is designed.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号