全文获取类型
收费全文 | 1314篇 |
免费 | 315篇 |
国内免费 | 297篇 |
专业分类
化学 | 1335篇 |
晶体学 | 67篇 |
力学 | 149篇 |
综合类 | 10篇 |
数学 | 41篇 |
物理学 | 324篇 |
出版年
2024年 | 13篇 |
2023年 | 32篇 |
2022年 | 72篇 |
2021年 | 80篇 |
2020年 | 179篇 |
2019年 | 74篇 |
2018年 | 78篇 |
2017年 | 61篇 |
2016年 | 93篇 |
2015年 | 105篇 |
2014年 | 81篇 |
2013年 | 118篇 |
2012年 | 61篇 |
2011年 | 71篇 |
2010年 | 63篇 |
2009年 | 61篇 |
2008年 | 80篇 |
2007年 | 79篇 |
2006年 | 63篇 |
2005年 | 65篇 |
2004年 | 62篇 |
2003年 | 82篇 |
2002年 | 59篇 |
2001年 | 32篇 |
2000年 | 24篇 |
1999年 | 20篇 |
1998年 | 22篇 |
1997年 | 29篇 |
1996年 | 15篇 |
1995年 | 10篇 |
1994年 | 9篇 |
1993年 | 5篇 |
1992年 | 6篇 |
1991年 | 2篇 |
1990年 | 3篇 |
1989年 | 4篇 |
1988年 | 2篇 |
1987年 | 2篇 |
1986年 | 3篇 |
1985年 | 2篇 |
1982年 | 1篇 |
1979年 | 1篇 |
1975年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有1926条查询结果,搜索用时 0 毫秒
131.
An inorganic-organic hybrid thioantimonate(Ⅲ) [CH3(CH2)3NH3]2Sb4S7 1 with layered structure was synthesized by solvothermal method.1 crystallizes in the triclinic system, space group P with a = 7.0124(11), b = 11.919(2), c = 14.879(3) (A), α = 108.791(3), β = 102.441(3), γ = 92.846(2)o, V = 1140.1(3) (A)3, Mr = 859.71, Z = 2, Dc = 2.504 g/cm3, μ= 5.324 mm-1, F(000) = 804, S = 1.013, the final R = 0.0297 and wR = 0.0618 for 3534 observed reflections with I>2σ(I). 1 consists of [C4H9NH3] cations and two-dimensional [Sb4S7]n2n-anion which is composed of three SbS3 trigonal pyramids and one SbS4 unit joined by sharing common corners. The anionic layers are stacked perpendicularly to the c axis of the unit cell forming two-dimensional channels between the layers. The [C4H9NH3] cations interdigitate in a bilayer and reside in the 2D channels leading to a sandwich-like arrangement of the anion and cations. 相似文献
132.
Yasuhiro Ono Ryuji IshikawaYuzuru Miyazaki Yoshinobu IshiiYukio Morii Tsuyoshi Kajitani 《Journal of solid state chemistry》2002,166(1):177-181
The layered oxide thermoelectric material β-Na0.67CoO2 has been studied by powder neutron diffraction, electric and magnetic measurements. This compound includes an edge-sharing CoO6 slab and a highly vacant Na+ sheet in a unit cell (space group symmetry C2/m, a=4.9023(4) Å, b=2.8280(2) Å, c=5.7198(6) Å and β=105.964(6)° at 300 K). The evaluated formal valence of cobalt ion, +3.33(1), is ascribed to the coexistence of Co3+ and Co4+ in the ratio 2:1. Polycrystalline β-Na0.67CoO2, a p-type thermoelectric material, exhibits metallic behavior of the electric resistivity below 300 K. The Curie-Weiss-type magnetic susceptibility indicates antiferromagnetic interactions between magnetic cobalt ions in the edge-sharing CoO6 slab. 相似文献
133.
Dr. Robert J. Messinger Dr. Kyungsu Na Dr. Yongbeom Seo Prof. Dr. Ryong Ryoo Prof. Dr. Bradley F. Chmelka 《Angewandte Chemie (International ed. in English)》2015,54(3):927-931
Mesoporous zeolites are a new and technologically important class of materials that exhibit improved diffusion and catalytic reaction properties compared to conventional zeolites with sub‐nanometer pore dimensions. During their syntheses, the transient developments of crystalline and mesoscopic order are closely coupled and challenging to control. Correlated solid‐state NMR, X‐ray, and electron microscopy analyses yield new molecular‐level insights on the interactions and distributions of complicated organic structure‐directing agents with respect to crystallizing zeolite frameworks. The analyses reveal the formation of an intermediate layered silicate phase, which subsequently transforms into zeolite nanosheets with uniform nano‐ and mesoscale porosities. Such materials result from coupled surfactant self‐assembly and inorganic crystallization processes, the interplay between which governs the onset and development of framework structural order on different length and time scales. 相似文献
134.
135.
136.
Ugur Gven 《Acta Mechanica Solida Sinica》2011,24(6):506-509
In this work a bi-material beam exhibiting partly bilinear behaviour under a uniform temperature change is analyzed. The essence of solution is based on the approach of Timoshenko’s mechanics of materials. The main aim of the present analysis is to understand the effect of the bilinear behaviour on the peeling moment. This theoretical mechanics model mentioned here can give us useful insights to improve the resistance against the delamination. 相似文献
137.
Ferroelectric SrBi2Ta2O9 film was prepared using the sol-gel technique. The sol-gel precursor resulted in good ferroelectric performance at annealing temperatures as low as 700°C. The baking profiles changed the orientation and the grain size in the film. The finer grain size and the higher switching charge were consistent under the slower baking profile. 相似文献
138.
139.
采用固体烧结法制备了Sr2-xSmxFeMoO6(x=0,0.03,0.05,0.08,0.10,0.13,0.15,0.20)多晶结构样品,用X射线衍射对材料的结构进行了检测。通过光热偏转技术方法对该材料的热扩散率进行了研究,给出了掺杂比例与材料热扩散率的关系曲线,结果发现Sr2FeMoO6样品随着参杂Sm浓度的增加,结构发生变化的同时,样品的热扩散率也随着波动变化。这与文献[1]中给出的结论有明显不同,从声子、电子、自旋及其相互作用角度揭示了与文献[1]不同的根本原因;并且从x射线和热扩散率两个角度给出了样品Sr2-xSmxFeMoO6结构转变的参杂比例在10—13%的范围,说明光热偏转技术方法是研究参杂镧系元素的双钙钛矿结构和电子参杂效应的可行有效方法。 相似文献
140.
实验研究了La2/3CamMnO3样品零磁场下的电阻率和低磁场下的磁化强度随温度的变化行为.结果表明,除了居里温度(Tc)外还存在另一特征温度Tonset,高于Tonset的样品为典型的顺磁绝缘体,而低于Tc的样品为典型的铁磁金属,但在Lonset和Tc之间,样品的磁化率大大偏离居里一外斯定律,同时其导电特性显示出明显的反常.对观察到的不寻常导电特性,根据铁磁金属集团在顺磁绝缘体背景上随机分布的假设,进行了分析与探讨。 相似文献