首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   57621篇
  免费   6662篇
  国内免费   3890篇
化学   21596篇
晶体学   559篇
力学   4107篇
综合类   542篇
数学   10518篇
物理学   30851篇
  2024年   67篇
  2023年   446篇
  2022年   949篇
  2021年   1185篇
  2020年   1224篇
  2019年   1229篇
  2018年   1128篇
  2017年   1414篇
  2016年   1599篇
  2015年   1268篇
  2014年   2139篇
  2013年   3565篇
  2012年   2547篇
  2011年   2955篇
  2010年   2247篇
  2009年   3404篇
  2008年   3789篇
  2007年   4234篇
  2006年   3585篇
  2005年   2835篇
  2004年   2481篇
  2003年   2671篇
  2002年   3079篇
  2001年   2344篇
  2000年   2294篇
  1999年   1961篇
  1998年   1833篇
  1997年   1152篇
  1996年   1094篇
  1995年   944篇
  1994年   960篇
  1993年   726篇
  1992年   800篇
  1991年   547篇
  1990年   504篇
  1989年   386篇
  1988年   326篇
  1987年   329篇
  1986年   271篇
  1985年   243篇
  1984年   250篇
  1983年   146篇
  1982年   197篇
  1981年   198篇
  1980年   114篇
  1979年   135篇
  1978年   100篇
  1977年   85篇
  1976年   41篇
  1973年   44篇
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
31.
    
The reaction of [{(η5-C5Me5)M(μ-Cl)Cl}2] {where M = Rh (1), Ir (2)} with functionalized phosphine viz., diphenyl-2-pyridylphosphine (PPh2Py) in dichloromethane solvent yield neutral ϰ1-P-coordinated rhodium and iridium complexes [(η5-C5Me5)RhCl21-P-PPh2Py)]3 and [(η5-C5Me5) IrCl21-P-PPh2Py)]4. Reaction of complexes 1 and 2 with the ligand PPh2Py in methanol under reflux give bis-substituted complexes such as [(η5-C5Me5)RhCl(ϰ1-P-PPh2Py)2]+ 5 and [(η5-C5Me5)IrCl(ϰ1-P-PPh2Py)2]+ 6, whereas stirring in methanol at room temperature gives P-, N-chelating complexes of the type [(η5-C5Me5)RhCl(ϰ2-P-N-PPh2Py)]+ 7 and [(η5-C5Me5)IrCl(ϰ2-P-N-PPh2Py)]+ 8. Neutral ϰ1-P-coordinated complexes [(η5-C5Me5)RhCl21-P-PPh2Py)]3 and [(η5-C5Me5)IrCl21-P-PPh2Py)]4 easily undergo conversion to the cationic P-, N-chelating complexes [(η5-C5Me5)RhCl(ϰ2-P-N-PPh2Py)]+ 7 and [(η5-C5Me5) IrCl(ϰ2-P, N-PPh2Py)]+ 8 on stirring in methanol at room temperature. These complexes are characterized by FT-IR and FT-NMR spectroscopy as well as analytical methods. The molecular structures of the representative complexes [(η5-C5Me5)RhCl21-P-PPh2Py)]3, [(η5-C5Me5)IrCl21-P-PPh2Py)]4 and hexafluorophosphate salt of complex [(η5-C5Me5)IrCl(ϰ2-P-PPh2Py)2]+ 6 are established by single-crystal X-ray diffraction methods  相似文献   
32.
In this paper, integration of interference phenomenon into femtosecond laser micromachining was reported as the femtosecond laser pulses were reshaped spatially to perform ablation. The generation of circular interference pattern was demonstrated by overlapping infrared femtosecond laser pulses. The interference pattern was subsequently focused on a copper substrate to ablate microstructures of concentric circular rings. The present technique is expected to open up new applications in the areas of rapid fabrication of micro-Fresnel lenses, hybrid microlenses and lens arrays.  相似文献   
33.
本文对反应堆压力容器紧急安注时的流动与传热特性在1/10的模型上进行了流动可视化、局部传热系数以及混合函数的试验研究。针对三个热冲击敏感区域的部分测点,比较了环腔流速为0.5m/s、安注流速为1~30 m/s时不同含气率对下降环腔内流动与传热特性的影响,得出并分析了不同测点传热系数、混合函数的变化规律。研究结果表明:随着含气率增大,安注流体与环腔流体的混合增强;下降环腔内的含气率对小安注流速时的流动与传热影响显著,而对大安注流速时影响较小。  相似文献   
34.
双掺(Tm3+,Tb3+)LiYF4激光器1.5 μm波长激光阈值分析   总被引:1,自引:0,他引:1  
胡晓  方达伟  洪治  洪方煜  邬良能 《光学学报》2002,22(12):426-1432
由速率方程推出了双掺(Tm^3 ,Tb^3 )离子准四能级系统的激光阈值解析式,讨论了Tm^3 和Tb^3 离子之间的相互作用。分析了1.5μm波长附近的激光阈值和Tm^3 、Tb^3 离子的掺杂原子数分数及晶体长度的关系。结果表明,对于对应Tm^3 离子^3H4→^3F4跃迁的约1.5μm波长的激光,激活离子Tm^3 的掺杂原子数分数过大时,交叉弛豫作用将使系统阈值迅速增加。Tb^3 离子的加入,一方面能抽空激光下能级,起到降低阈值的作用;另一方面亦减少了激光上能级的寿命,使阈值升高。故Tb^3 离子有最佳掺杂原子数分数。对于Tm原子数分数为y=0.01的Tm:LiYF4晶体,Tb^3 离子的最佳掺杂原子数分数为0.002左右,同时表明,激光阈值与晶体长度有关。最佳晶体长度与Tm^3 、Tb^3 离子的掺杂原子数分数以及晶体的衍射损耗和吸收损耗有关。  相似文献   
35.
The polycrystalline perovskitelike manganese oxides La1-xAxMnO (A = Na, and K, ) have been fabricated by sol-gel technique. For all the compositions explored in this work, the average manganese oxidation state is practically constant, at for A = Na, and for A = K, respectively. A close relationship is confirmed to hold between the Curie temperature (Tc) and the bond distance of Mn-O. Results of magnetic measurements show that these materials can be utilized as suitable candidates for magnetic refrigerants with wide applied temperature span, for their significant entropy change and the easily tuned Curie temperature. Received: 12 September 1997 / Revised: 18 December 1997 / Accepted: 21 January 1998  相似文献   
36.
37.
The strength of basic sites has been measured by pyrrole-IR on alkali metal cation exchanged β and X zeolites, as well as NaOH loaded Naβ. The influence of cation type and the structure of zeolites on their basicity has been studied. The acidic and basic properties of the samples were investigated by NH3-TPD and isopropanol reaction. It was shown that the strength of basic sites on samples could be characterized by the shift of vNH band in the pyrrole-IR spectra. The framework oxygen charges were calculated from the Sanderson electronegativity. The changes in basic properties with various alkali metal cation are consistent with the changes of local oxygen charges of the zeolite framework.  相似文献   
38.
环状连续强激光下光学薄膜的瞬温和热畸变   总被引:1,自引:0,他引:1       下载免费PDF全文
详细研究了非冷却光学薄膜元件在环形激光光束辐照下的瞬态温度分布和随后的热畸变,并且用泰曼干涉仪实际测量了连续波氧碘激光辐照各种非冷却光学元件的热畸变量并与理论计算相比较,分析结果表明理论和实验相一致。  相似文献   
39.
The dependence of the beam propagation factor (M 2 parameter) with the absorbed pump power in the case of monolithic microchip laser under face-cooled configuration is extensively studied. Our investigations show that the M 2 parameter is related to the absorbed pump power through two parameters (α and β) whose values depend on the laser material properties and laser configuration. We have shown that one parameter arises due to the oscillation of higher order modes in the microchip cavity and the other parameter accounts for the spherical aberration associated with the thermal lens induced by the pump beam. Such dependency of M 2 parameter with the absorbed pump power is experimentally verified for a face-cooled monolithic microchip laser based on Nd3+ -doped GdVO4 crystal and the values of α and β parameters were estimated from the experimentally measured data points.  相似文献   
40.
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号