全文获取类型
收费全文 | 13150篇 |
免费 | 4313篇 |
国内免费 | 907篇 |
专业分类
化学 | 2648篇 |
晶体学 | 192篇 |
力学 | 525篇 |
综合类 | 53篇 |
数学 | 81篇 |
物理学 | 14871篇 |
出版年
2024年 | 26篇 |
2023年 | 66篇 |
2022年 | 221篇 |
2021年 | 278篇 |
2020年 | 262篇 |
2019年 | 211篇 |
2018年 | 301篇 |
2017年 | 415篇 |
2016年 | 511篇 |
2015年 | 516篇 |
2014年 | 850篇 |
2013年 | 914篇 |
2012年 | 918篇 |
2011年 | 1199篇 |
2010年 | 807篇 |
2009年 | 866篇 |
2008年 | 973篇 |
2007年 | 1093篇 |
2006年 | 982篇 |
2005年 | 793篇 |
2004年 | 774篇 |
2003年 | 636篇 |
2002年 | 648篇 |
2001年 | 522篇 |
2000年 | 573篇 |
1999年 | 515篇 |
1998年 | 401篇 |
1997年 | 374篇 |
1996年 | 338篇 |
1995年 | 248篇 |
1994年 | 210篇 |
1993年 | 169篇 |
1992年 | 171篇 |
1991年 | 137篇 |
1990年 | 103篇 |
1989年 | 81篇 |
1988年 | 54篇 |
1987年 | 61篇 |
1986年 | 32篇 |
1985年 | 21篇 |
1984年 | 26篇 |
1983年 | 9篇 |
1982年 | 13篇 |
1981年 | 17篇 |
1980年 | 9篇 |
1979年 | 4篇 |
1976年 | 2篇 |
1975年 | 2篇 |
1974年 | 3篇 |
1973年 | 11篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
81.
Herlin-Boime N. Vicens J. Dufour C. Ténégal F. Reynaud C. Rizk R. 《Journal of nanoparticle research》2004,6(1):63-70
Small SiC nanoparticles (10 nm diameter) have been grown in a flow reactor by CO2 laser pyrolysis from a C2H2 and SiH4 mixture. The laser radiation is strongly absorbed by SiH4 vibration. The energy is transferred to the reactive medium and leads to the dissociation of molecules and the subsequent growth of the nanoparticles. The reaction happens with a flame. The purpose of the experiments reported in this paper is to limit the size of the growing particles to the nanometric scale for which specific properties are expected to appear. Therefore the effects of experimental parameters on the structure and chemical composition of nanoparticles have been investigated. For a given reactive mixture and gas velocity, the flame temperature is governed by the laser power. In this study, the temperature was varied from 875°C to 1100°C. The chemical analysis of the products indicate that their composition is a function of the temperature. For the same C/Si atomic ratio in the gaseous phase, the C/Si ratio in the powder increases from 0.7 at 875°C up to 1.02 at 1100°C, indicating a growth mechanism limited by C2H2 dissociation. As expected, X-ray diffraction has shown an improved crystallisation with increasing temperature. Transmission electron microscopy observations have revealed the formation of 10 nm grains for all values of laser power (or flame temperature). These grains appear amorphous at low temperature, whereas they contain an increasing number of nanocrystals (2 nm diameter) when the temperature increases. These results pave the way to a better control of the structure and chemical composition of laser synthesised SiC nanoparticles in the 10 nm range. 相似文献
82.
In this paper, we present a theoretical model for the gain competition in dual-wavelength dye lasers. For this purpose the rate equations under the steady-state conditions have been used. The degree of the gain competition is shown to depend on the polarization of the two laser beams. The dependence of the gain competition on various working parameters such as pumping power, dye concentration and the reorientation rate of the molecules or solvent viscosity is studied for two different cases of parallel and orthogonal polarizations. The results of our model show dramatically different behaviors in the two proposed cases. 相似文献
83.
FexNi100−x nanometric films were deposited on SiO2/Si substrates at room temperature using the pulsed laser deposition technique. The targets were Fe-Ni amorphous magnetic foils with composition Fe50Ni50, Fe35Ni65 and Fe22Ni78. Morphological and structural properties of the deposited films were investigated using scanning electron microscopy, Rutherford backscattering spectrometry, grazing incidence X-ray diffraction, and X-ray reflectivity. Electrical and magnetic characteristics of the films were investigated by using the four-point probe and the magneto-optic Kerr effect techniques, respectively. The film properties are strictly dependent on the Fe-Ni compositional ratio. 相似文献
84.
Alex M. Green David G. Gevaux Christine Roberts Chris C. Phillips 《Physica E: Low-dimensional Systems and Nanostructures》2004,20(3-4):531
In this paper we outline the use of resonant-cavity enhancement for increasing the exterior coupling efficiency of photodetectors and light-emitting diodes (LEDs) in the mid-infrared (MIR) spectral region. This method is potentially very important in the MIR because encapsulation is not presently feasible due to the lack of suitable materials. Among other potential applications, resonant-cavity-enhanced (RCE) photodetectors and LEDs could be particularly suitable for greenhouse gas detection because of their ‘pre-tunable’ spectrally narrowed resonantly enhanced peaks. We also present the optical characterization of an InAs RCE photodetector aimed at the detection of methane gas (λ≈3.3 μm), and an InAs/InAs0.91Sb0.09 resonant-cavity LED (RCLED) aimed at carbon dioxide gas (λ≈4.2 μm). The high peak responsivity of the RCE photodetector was 34.7 A/W at λ=3.14 μm, and the RCLED peaked at λ=3.96 μm. These are among the longest operating wavelengths for III–V RCE photodetectors and RCLEDs reported in the literature. 相似文献
85.
The patterns of absorption and reflection of an ultrashort laser pulse by a plasma with a solid-state density, which are realized in the mode of the normal skin effect, are studied. It is shown that a decrease in low-power pulse duration shorter than the period corresponding to the fundamental frequency of radiation leads to an increase in the absorption coefficient. If the pulse power is so high as to provide electron heating during a time shorter than the reciprocal fundamental frequency, nonlinear suppression of absorption takes place and the spectrum of the reflected radiation contains odd harmonics of the fundamental frequency. 相似文献
86.
Starting from the total Hamiltonian of an excited exciton–biexciton system, nonresonant renormalizations in the electronic spectrum of a coherently driven direct semiconductor are considered. Stringent group-theoretical inclusion of the particle spin in the Hamiltonian allows one to account for the dependence of different renormalization effects on polarizations of the incident laser fields. On the example of circularly polarized driving and probing pulses it is shown that the kind of observed renormalization is defined by the pump-and-probe polarization geometry. Thus, the exciton optical Stark effect must appear in the case of co-circular pump-and-probe, whereas a mixing of the polariton and biexciton spectra is possible only in the case of counter-circular pump-and-probe. The polariton--biexciton dispersion renormalization may manifest itself as synchronous splittings of the exciton--polariton and biexciton spectra under resonant pumping at a frequency of the polariton--biexciton transition, or in their shifts in opposite directions under near-resonant pumping. The mechanisms of both kinds of renormalization effects are analyzed, and the dependence of their characteristics on the pump parameters and microscopic parameters of the exciton–biexciton–photon system is established. An evaluation of the characteristics shows that the effect of polariton–biexciton dispersion renormalization dominates in the spectra of semiconductors with stable biexciton formation. Results of the theoretical study provide an adequate explanation of available experimental data. 相似文献
87.
High power industrial multibeam CO2 lasers consist of a large number of closely packed parallel glass discharge tubes sharing a common plane parallel resonator.
Every discharge tube forms an independent resonator. When discharge tubes of smaller diameter are used and the Fresnel numberN ≪ 1 for all resonators, they operate in waveguide mode. Waveguide modes have excellent discrimination of higher order modes.
A DC excited waveguide multibeam CO2 laser is reported having six glass discharge tubes. Simultaneous excitation of DC discharge in all sections is achieved by
producing pre-ionization using an auxiliary high frequency pulsed discharge along with its other advantages. Maximum 170 W
output power is obtained with all beams operating in EH11 waveguide mode. The specific power of 28 W/m is much higher as compared to similar AC excited waveguide multibeam CO2 lasers. Theoretical analysis shows that all resonators of this laser will support only EH11 mode. This laser is successfully used for woodcutting 相似文献
88.
Zhang Xun Zhang Hongjie Zhang Ping Chen Weibin Luo Xizhang 《International Journal of Infrared and Millimeter Waves》2003,24(11):1967-1976
Based on the basic theory of molecular vibration relaxation and semi-classical density matrix theory, operating parameters optimization of buffer gas in the process of miniature pulsed optically pumped submillimeter wave laser was systemically studied and the theoretical calculated result was tested by experiments. The result would do favor to develop and study high-power and wide-range tunable miniature and high-efficient pulsed optically pumped submillimeter wave laser and also had some instruction to its application. 相似文献
89.
90.
M. Brunken L. Casper H. Genz C. Hessler S. Khodyachykh A. Richter 《Optics & Laser Technology》2003,35(5):349-353
A compact autocorrelator suitable for the measurement of the optical pulse length of the infrared free electron laser (IR-FEL) at the S-DALINAC is described. It allows to investigate the energy transfer process from the electrons into the laser light within the undulator of the FEL. The autocorrelator utilizes the second harmonic generation (SHG) and it provides the possibility of a background-free measurement at wavelengths between 4 and 10 μm. Simulations for three different crystals used for SHG show that the largest efficiency for SHG and the best temporal resolution is achieved with a ZnGeP2 crystal at a length of 2 mm. A test experiment at the free electron laser for infrared experiments confirmed the expected high efficiency of about 7.5% of SHG for the ZnGeP2 crystal as well as the easy handling and fast adjustment of the system. 相似文献