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991.
对新型钝感高能炸药组分1,1-二氨基-2,2-二硝基乙烯(FOX-7),考察并选择了适用的分子力场和超晶胞初始构型,通过303K-378K温度范围在NPT系综下的分子动力学模拟(MD),得到常压下各温度的FOX-7晶体平衡构型,发现随温度升高晶体内分子的取向和堆积方式不变;通过线性拟合求算出线膨胀系数,发现αb明显较大而αc与αa接近但不相等;接着采用密度泛函理论(DFT)方法随各向棱长膨胀的能量变化进行了模拟计算,发现得到的能量变化成各向异性并与各向热膨胀系数相关,从而建立FOX-7晶体特定分子堆积模式与热膨胀各向异性的关联。 相似文献
992.
采用密度泛函(DFT)中的B3LYP方法,选择CEP-31g基组,优化并得到了MgnLa(n=2- 6)小团簇的基态平衡结构,计算出了掺杂团簇的基态结构的平均键长、对称性、费米能级、能级间隙、束缚能、总能的二阶差分.结果表明,随着团簇原子数的增加,La原子更容易趋于团簇表面位置. 与未掺杂Mg团簇相比,La原子多采用取代其稳定基态结构的一个Mg原子形成掺杂团簇的稳定结构. 从有限的结果看,其中 Mg3La和 Mg6La的结构更为稳定. 相似文献
993.
Concepts of programmability and compact programmability are defined relative to a class of modified Poisson series. Lie-series-based canonical perturbation methods from astrodynamics are applied to the Hamiltonian system boundary-value problem, and more usual methods are applied to the perturbed Hamilton-Jacobi-Bellman partial differential equation, in order to obtain a complete set of equations for the perturbed optimal feedback control law for both infinite-time and finite-time regulator problems. The relative advantages of each approach are evaluated. A major aim of the paper is to determine the largest class of perturbations, within the set of Poisson series, for which the equations can be derived on a computer by symbolic manipulation. The more general the class, the more accurate the perturbation solution can be, for a given order. The solutions developed are complete; all that remains is to program them in order to have computerized derivations of the optimal nonlinear feedback control laws.This research was supported by NSF Grant No. ENG-78-10232. This paper was presented at the 1982 Conference on Information Sciences and Systems, Princeton, New Jersey, and appears in the Proceedings. 相似文献
994.
C. -H. L. Ong 《Annals of Pure and Applied Logic》2004,130(1-3):125-171
We prove that the observational equivalence of third-order finitary (i.e. recursion-free) Idealized Algol (IA) is decidable using Game Semantics. By modelling the state explicitly in our games, we show that the denotation of a term M of this fragment of IA is a compactly innocent strategy-with-state, i.e. the strategy is generated by a finite view function fM. Given any such fM, we construct a real-time deterministic pushdown automaton (DPDA) that recognizes the complete plays of the knowing-strategy denotation of M. Since such plays characterize observational equivalence, and there is an algorithm for deciding whether any two DPDAs recognize the same language, we obtain a procedure for deciding the observational equivalence of third-order finitary IA. Restricted to second-order terms, the DPDA representation cuts down to a deterministic finite automaton; thus our approach gives a new proof of Ghica and McCusker’s regular-expression characterization for this fragment. Our algorithmic representation of program meanings, which is compositional, provides a foundation for model-checking a wide range of behavioural properties of IA and other cognate programming languages. Another result concerns second-order IA with full recursion: we show that observational equivalence for this fragment is undecidable. 相似文献
995.
激励销售与准确预测的薪酬机制设计 总被引:1,自引:2,他引:1
由于销售人员具有比厂商更多的销售信息,厂商在制定生产计划时需要参考来自销售人员的市场预测。传统的薪酬机制在引导销售人员如实上报预测量方面存在严重不足。Gonik机制虽然可以部分地弥补这一不足,但仍然要由厂商先提供参考定额和相应奖金数值。本发展了一种不需要厂商提供参考定额值而直接由销售人员自己参与提出定额确定奖金并努力销售的薪酬机制。章论证了它的有效性,并导出了在设计合同参数时,需要注意的一些规则和约束,对实际操作有一定的指导意义。 相似文献
996.
According to an induced-matter approach, Liu and Wesson obtained the rest mass of a typical particle from the reduction of a 5D Klein–Gordon equation to a 4D one. Introducing an extra-dimension momentum operator identified with the rest mass eigenvalue operator, we consider a way to generalize the 4D Dirac equation to 5D. An analogous normal Dirac equation is gained when the generalization reduces to 4D. We find the rest mass of a particle in curved space varies with spacetime coordinates and check this for the case of exact solitonic and cosmological solution of the 5D vacuum gravitational field equations. 相似文献
997.
Bertrand Chauvineau 《General Relativity and Gravitation》2002,34(11):1855-1864
We show that the general relativity theory equation, in presence of pressureless matter (dust) in irrotational motion, can be recovered from a scalar-tensor like variational approach. In this approach, the kinetic energy, , of a dynamical scalar field , couples directly to gravity. The lagrangian, exempt of explicit matter term, is varied in the framework of the first order formalism, and a conformal transformation, restoring riemannian geometry, is made. In this approach, it turns out that a non-empty spacetime is necessarily four-dimensional. 相似文献
998.
根据半波带法的思路,介绍了利用计算机课件演示对单缝夫琅和费衍射的条纹光强与衍射角之间的关系,以便有效地化解教学难点,帮助学生对该知识点形成清晰的认识和深化理解,同时对课件制作要点作了简要说明。 相似文献
999.
The universality principle of the free energy density functional and the ‘test particle' trick by Percus are combined to construct the approximate free energy density functional or its functional derivative. Information about the bulk fluid radial distribution function is integrated into the density functional approximation directly for the first time in the present methodology. The physical foundation of the present methodology also applies to the quantum density functional theory. 相似文献
1000.