析氢反应动力学的交流阻抗法研究

利用交流阻抗法测定析氢电化学动力学参数，得到与极化曲线法一致的结果，为确定复杂析氢过程速率的决定步骤提供了判据。     

停流—荧光动力学分析法测定痕量钛的研究

利用自行组装的停流-荧光动力学分析仪,采用停流法汇合流体动力注入技术,研究了钛与3.5-二溴水杨基荧光酮的荧光增强动力学反应性质,讨论了流速、进样时间对方法灵敏度和精密度的影响,提出了一个快速、简便、精确测定钛的分析方法,并用于稀土样品及合成样品中痕量钛的测定.方法检测限为8×10~(-3)ppm,大多数元素的干扰均可用动力学方法消除.     

Distribution Functions in Quantum Mechanics and Wigner Functions

We formulate and solve the problem of finding a distribution function F(r,p,t) such that calculating statistical averages leads to the same local values of the number of particles, the momentum, and the energy as those in quantum mechanics. The method is based on the quantum mechanical definition of the probability density not limited by the number of particles in the system. The obtained distribution function coincides with the Wigner function only for spatially homogeneous systems. We obtain the chain of Bogoliubov equations, the Liouville equation for quantum distribution functions with an arbitrary number of particles in the system, the quantum kinetic equation with a self-consistent electromagnetic field, and the general expression for the dielectric permittivity tensor of the electron component of the plasma. In addition to the known physical effects that determine the dispersion of longitudinal and transverse waves in plasma, the latter tensor contains a contribution from the exchange Coulomb correlations significant for dense systems.     

Transesterification of an RNA model in buffer solutions in H2O and D2O

Transesterification of a phosphodiester bond of RNA models has been studied in various buffer solutions, under neutral and slightly alkaline conditions in H₂O and D₂O. The results show that imidazole is the only buffer system where a clear buffer catalysis on the cleavage of a phosphodiester bond is observed. The rate enhancement in sulphonic acid buffers is smaller, and a sulphonate base, particularly, is inactive as a catalyst. The rate‐enhancing effect of imidazole is, however, catalytic, and the catalytic inactivity of sulphonate buffers can be attributed to their structure and/or charge. The catalysis by imidazole is a complex system which, in addition to first‐order reactions, involves a process that shows a second‐order dependence in imidazole concentration. The latter reaction becomes significant in acidic imidazole buffers (pH < pK_a), as the buffer concentration increases. The kinetic solvent deuterium isotope effect k_H/k_D, referring to first‐order catalysis by imidazole base, is 2.3 ± 0.3. That referring to second‐order catalysis is most probably much larger, but an accurate value could not be obtained. Copyright © 2007 John Wiley & Sons, Ltd.     

Asymptotic behavior of solutions for a class of predator-prey reaction-diffusion systems with time delays

The aim of this paper is to investigate the asymptotic behavior of solutions for a class of three-species predator-prey reaction-diffusion systems with time delays under homogeneous Neumann boundary condition. Some simple and easily verifiable conditions are given to the rate constants of the reaction functions to ensure the convergence of the time-dependent solution to a constant steady-state solution. The conditions for the convergence are independent of diffusion coefficients and time delays, and the conclusions are directly applicable to the corresponding parabolic-ordinary differential system and to the corresponding system without time delays.     

Global smooth solutions to the multi-dimensional hydrodynamic model for two-carrier plasmas

The existence of global smooth solutions to the multi-dimensional hydrodynamic model for plasmas of electrons and positively charged ions is shown under the assumption that the initial densities are close to a constant. The model consists of the conservation laws for the particle densities and the current densities, coupled to the Poisson equation for the electrostatic potential. Furthermore, it is proved that the particle densities converge exponentially fast to the (constant) steady state. The proof uses a higher-order energy method inspired from extended thermodynamics.     

氩气介质阻挡放电的发光特性

本文使用水电极介质阻挡放电装置,采用光学方法测量了氩气介质阻挡放电的发光特性。发现在驱动电压处于一定的范围内时,放电处于丝极模式,在驱动电压的每半周期内,无论是放电的总光还是单个微通道的放电发光均只有一次脉冲,单个微放电的时间为2μs,而总放电时间为2.4μs,这表明在氩气的丝极模式中,各单丝产生与熄灭的时间极其接近,各个放电丝之间有着很好的时间相关性。最后将本文的结果与空气中介质阻挡放电丝极模式的发光特性相比较,空气放电在每半周内的总光信号由多个脉冲组成,而每一个脉冲对应多个放电丝,因而氩气中各个放电微通道之间的时间相关性远强于空气的情况。     

Insight into chain dimensions in PEO/water solutions

Small‐Angle Neutron Scattering has been performed from poly(ethylene oxide) in deuterated water at temperature ranging from 10 to 80 °C. A simple fitting model was used to obtain a correlation length and a Porod exponent. The correlation length L characterizes the average distance between entanglements in the semidilute region and is proportional to the individual coil sizes in the dilute region. L was found to increase with temperature in the semidilute region but it decreases with temperature in the dilute region. This decrease is the precursor to the single‐chain collapse which applies to very dilute polymer solutions. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 2196–2200, 2007     

Recent radiochemical studies of the fission process

This article summarizes the recent radiochemical investigations on mass, charge kinetic energy and fragment angular distributions in low energy fission of actinides.