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11.
An implicit quasi-monotone second-order accurate method is proposed for analyzing the spiral Couette flow of a rarefied gas between coaxial cylinders. The basic advantages of the method over the conventional method of stationry iterations are that the former is conservative with respect to the collision integral, has a simple software implementation for any types of boundary conditions, and applies to a wide range of Knudsen numbers.  相似文献   
12.
A localH-theorem is derived for a recently proposed extension of Enskog kinetic theory to a dense model fluid composed of particles with interactions extending beyond a hard core.On leave from: Katedra Fizyki, Uniwersytetu Szczecinskiego, 70-451 Szczecin, Poland.  相似文献   
13.
This is the first part of a series devoted to the study of thermodynamic behavior of large dynamical systems with the use of a family of fully-discrete and conservative models named elementary reversible cellular automata (ERCAs). In this paper, basic properties such as conservation laws and phase space structure are investigated in preparation for the later studies. ERCAs are a family of one-dimensional reversible cellular automata having two Boolean variables on each site. Reflection and Boolean conjugation symmetries divide them into 88 equivalence classes. For each rule, additive conserved quantities written in a certain form are regarded as a kind of energy, if they exist. By the aid of the discreteness of the variables, every ERCA satisfies the Liouville theorem or the preservation of phase space volume. Thus, if an energy exists in the above sense, statistical mechanics of the model can formally be constructed. If a locally defined quantity is conserved, however, it prevents the realization of statistical mechanics. The existence of such a quantity is examined for each class and a number of rules which have at least one energy but no local conservation laws are selected as hopeful candidates for the realization of thermodynamic behavior. In addition, the phase space structure of ERCAs is analyzed by enumerating cycles exactly in the phase space for systems of comparatively small sizes. As a result, it is revealed that a finite ERCA is not ergodic, that is, a large number of orbits coexist on an energy surface. It is argued that this fact does not necessarily mean the failure of thermodynamic behavior on the basis of an analogy with the ergodic nature of infinite systems.  相似文献   
14.
从正交各向异性三维弹性动力学的控制方程出发,在求得四边简支矩形板自由振动频率和位移振型的基础上,构造了受迫振动的位移函数;利用自由振动位移振型的正交性,将控制方程的空间变量和时间变量分离,得到了广义质量、广义力和频率表示的关于时间的2阶常微分方程,从而得到了正交各向异性弹性矩形板在受迫振动下的位移场和应力场.给出了本文方法与薄板理论的算例.  相似文献   
15.
研究了Fe(acac)3-Al(i-Bu)3-8-羟基喹啉(acac=乙酰丙酮)催化体系催化丙烯酸丁酯(BA)聚合,考察了聚合规律,用凝胶渗透色谱研究了聚合物分子量和分子量分布.动力学研究表明聚合反应对单体浓度呈一级关系,表观活化能为13.9kJ/mol.  相似文献   
16.
甲基对硫磷的快速测定及电化学性质   总被引:3,自引:2,他引:1  
研究了杀虫剂甲基对硫磷的电化学性质。在pH10.38的Bdtton—Robinson缓冲溶液中,采用微分脉冲溶出伏安法在悬汞电极上得到一个还原峰,峰电位为-0.5V(vs.Ag/AgCl),本工作对实验条件进行了深入的研究,结合线性扫描伏安法等手段。研究了体系的电化学行为。实验表明,甲基对硫磷在汞电极上具有吸附性,电极反应具有不可逆性。该法用于水果及水样中甲基对硫磷残余量的测定,结果满意。  相似文献   
17.
基于稠密气体分子运动论和颗粒动理学,建立可压稠密气固两相流动模型。采用梯度模拟来考虑气相可压缩性对气相湍流的影响。模拟计算表明气固两相射流速度沿轴向和径向减小,颗粒浓度下降。气固两相射流具有高的颗粒温度,呈现强烈的气固两相湍流流动特性。  相似文献   
18.
In this paper, Maxwell's equations involving generally nonlinear polarization and field-dependent currents are studied. The main objective is the asymptotic behavior of the solution for t→∞ if no damping term occurs in the equation governing the polarization field.  相似文献   
19.
给出引理解决了方程非振动解与其各阶导数的符号关系,并由此得到了若干判别准则,用于判别三阶线性脉冲微分方程解的振动性与渐近性,举例说明了准则的有效性。本文推广了相关文献的结果。  相似文献   
20.
Rhythmic growth of ring‐banded spherulites in blends of liquid crystalline methoxy‐poly(aryl ether ketone) (M‐PAEK) and poly(aryl ether ether ketone) (PEEK) has been investigated by means of differential scanning calorimetry (DSC), polarized light microscopy (PLM), and scanning electron microscopy (SEM) techniques. The measurements reveal that the formation of the rhythmically grown ring‐banded spherulites in the M‐PAEK/PEEK blends is strongly dependent on the blend composition. In the M‐PAEK‐rich blends, upon cooling, an unusual ring‐banded spherulite is formed, which is ascribed to structural discontinuity caused by a rhythmic radial growth. For the 50:50 M‐PAEK/PEEK blend, ring‐banded spherulites and individual PEEK spherulites coexist in the system. In the blends with PEEK as the predominant component, M‐PAEK is rejected into the boundary of PEEK spherulites. The cooling rate and crystallization temperature have great effect on the phase behavior, especially the ring‐banded spherulite formation in the blends. In addition, the effects of M‐PAEK phase transition rate and phase separation rate on banded spherulite formation is discussed. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 3011–3024, 2007  相似文献   
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