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Abstract The i.r. spectra of N-phenylphthalimide and 15N-phenylphthalimide have been measured in 4000–100 cm?1 frequency range as KBr and polyethylene pellets and as chloroform solutions. The Raman spectra (4000–50) cm?1 of microcrystalline powder of the of the same compounds have also been investigated. A detailed assignment of most of the observed frequencies has been proposed on the basis of the group vibrational concept, isotopic shift data and analogies with the spectra of related molecules. Some literature data have been discussed and some frequencies are reassigned. 相似文献
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The 60 MHz 1H NMR spectra of racemic 5-[[3,5-bis(1,1-dimethylethyl)-4-hydroxyphenyl]methyl]-4-thiazolidinone, 1, have been studied in CDCl3 solution at 28° with the achiral lanthanide shift reagent (LSR), tris (6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)europium (III), 2, and the chiral LSRs, tris[3-(heptafluoropropylhydroxymethylene)- (+)-camphoratojeuropium(III), 3, and tris[3-(trifluoromethylhydroxymethylene-(+) -camphorato]europium (III), 4, Significant enantiomeric shift differences were observed in the presence of added 3, for the aryl protons of 1 that should permit direct determination of enantiomeric excess. Relative magnitudes of lanthanide-induced shift for the different nuclei of 1 with the three LSRs are compared and discussed in terms of preferred LSR binding sites. A favored conformation of 1 with respect to rotation about the C(5)-CH2 bond is suggested. 相似文献
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Shigehiro Morikawa Toshiro Inubushi Kan Takahashi Hisanari Ishii Shino Shigemori 《Magnetic resonance imaging》1996,14(10):1197-1204
The relationships among tissue edema, lactate accumulation, and intracellular pH in middle cerebral artery (MCA)-occluded rats were investigated with multiecho 1H magnetic resonance imaging and spatially resolved metabolic images constructed by 1H and 31P nuclear magnetic resonance (NMR) chemical shift imaging (CSI). For the effective and sensitive detection of NMR signals from the brain, outer volume suppression (OVS), reduced k-space sampling and proton irradiation were incorporated into the CSI sequences. The consecutive three measurements of calculated T2 image, lactate image, and pH image which were required for 3.75 h were repeated for four cycles of 1–16 h after MCA occlusion. Tissue edema and lactate accumulation in the infarcted region were gradually and consistently increased during the 15-h observation period. In contrast, severe acidosis was already detected on the first pH image (2–4.7 h after MCA occlusion); thereafter, the degree of acidosis became milder and showed no further progression. The dissociation between the time courses of the lactate accumulation and pH decrease was clearly demonstrated by the NMR metabolic images. Acid-base balance in cerebral infarction might be affected not only by lactate production but also by complicated interactions with tissue edema and some other factors. 相似文献
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用立体李萨如图形测频率 总被引:2,自引:0,他引:2
在用李萨如图形测频率时,若待测频率与参考频率相差太大,则示波器上的李氏图形尤其是边缘区太拥挤,不易观测切点数目。本提出采用具有立体感的李萨如图形,就可以解决上述问题。 相似文献