全文获取类型
收费全文 | 1140篇 |
免费 | 173篇 |
国内免费 | 85篇 |
专业分类
化学 | 1218篇 |
晶体学 | 12篇 |
力学 | 1篇 |
综合类 | 2篇 |
数学 | 5篇 |
物理学 | 160篇 |
出版年
2024年 | 4篇 |
2023年 | 19篇 |
2022年 | 38篇 |
2021年 | 50篇 |
2020年 | 63篇 |
2019年 | 45篇 |
2018年 | 42篇 |
2017年 | 30篇 |
2016年 | 64篇 |
2015年 | 51篇 |
2014年 | 70篇 |
2013年 | 227篇 |
2012年 | 55篇 |
2011年 | 48篇 |
2010年 | 62篇 |
2009年 | 50篇 |
2008年 | 52篇 |
2007年 | 41篇 |
2006年 | 58篇 |
2005年 | 51篇 |
2004年 | 42篇 |
2003年 | 34篇 |
2002年 | 19篇 |
2001年 | 17篇 |
2000年 | 25篇 |
1999年 | 19篇 |
1998年 | 13篇 |
1997年 | 27篇 |
1996年 | 20篇 |
1995年 | 10篇 |
1994年 | 7篇 |
1993年 | 8篇 |
1992年 | 9篇 |
1991年 | 4篇 |
1990年 | 1篇 |
1989年 | 4篇 |
1988年 | 2篇 |
1987年 | 4篇 |
1985年 | 2篇 |
1982年 | 1篇 |
1980年 | 2篇 |
1979年 | 1篇 |
1976年 | 1篇 |
1975年 | 2篇 |
1974年 | 2篇 |
1972年 | 2篇 |
排序方式: 共有1398条查询结果,搜索用时 31 毫秒
71.
A general and efficient synthetic method of 1,3-bis(phenylseleno)-2-propanol by reducing diphenyl diselenides with sodium borohydride in basic environment and then reacting with epichlorohydrin are described. 相似文献
72.
A convenient one-pot synthesis of benzo[f]pyrimido[4,5-b]quinoline derivatives is described via three-component reaction of benzaldehydes, naphthalen-2-amine, and barbituric acid at room temperature in aqueous media catalyzed by iodine. Compared with other methods, this three-component reaction used a green solvent, gave good yields, and was operationally simple. 相似文献
73.
Shahnaz Rostamizadeh Ali Mohammad Amani Reza Aryan Hamid Reza Ghaieni Nasrin Shadjou 《合成通讯》2013,43(20):3567-3576
A simple, inexpensive, and efficient one-pot synthesis of 2,3-dihydroquinazoline-4(1H)-one derivatives under solvent-free conditions using a catalytic amount of iodine with excellent product yields is reported. This methodology provides easy, quantitative access to various 2,3-dihydroquinazoline-4(1H)-one derivatives, using commercially available iodine as a catalyst. 相似文献
74.
A clean, mild, and efficient catalytic deoximation procedure compatible with several common functional groups has been developed using 30% hydrogen peroxide activated by iodine catalyst in aqueous acetonitrile under essentially neutral conditions. The mechanistic features of an iodonium ion–driven nucleophilic cleavage of oximic C[dbnd]N have been revealed. 相似文献
75.
An efficient one-pot condensation of 4-hydroxylcoumarin, aromatic aldehydes, and 5,5-dimethylcyclohexane-1,3-dione has been achieved with molecular iodine as a catalyst via conventional heating and microwave irradiation techniques, and thus a variety of new tetrahydrobenzo[c]xanthene-1,11-dione derivatives were prepared in good yields. 相似文献
76.
Iodine is an efficient catalyst for the synthesis of symmetrically N,N′‐disubstituted ureas/thioureas by heating respective amines or phenyl hydrazine and urea/thiourea on a preheated hot plate at 90–95°C, under solvent‐free conditions. The yields are excellent, and the reactions go to complete within 5–10 min. 相似文献
77.
Yiming Ren 《合成通讯》2013,43(11):1670-1676
Esterification of carboxylic acids and transesterification of β-ketoesters with alcohols have been developed using a catalytic amount of iodine in polyethylene glycol (PEG) ionic liquid (IL 1000) to afford the corresponding esters in good yields. By simple separation of the ionic-liquid phase containing the iodine, the system of I2/IL 1000 can be reused several times. 相似文献
78.
α‐Tosyloxyketones (2), readily accessible through hypervalent iodine oxidation of enolizable ketones (1) using [hydroxy(tosyloxy)iodo]benzene (HTIB) in acetonitrile, exclusively generates the 6‐arylimidazo[2,1‐b]thiazoles (4) on treatment with commercially available 2‐aminothiazole (3). 相似文献
79.
An efficient and facile route for the synthesis of coumarins via the Pechmann reaction catalyzed by molecular iodine or AgOTf was described. 相似文献
80.
Mekhman S. Yusubov Elena N. Tveryakova Elena A. Krasnokutskaya Irina A. Perederyna Viktor V. Zhdankin 《合成通讯》2013,43(8):1259-1265
A simple and environmentally safe general method of iodination of aromatic substrates under sovent‐free conditions using the I2/AgNO3 combination in a solid state is reported. Both activated and deactivated aromatic compounds afford the respective aryl iodides in generally high yields (80–90%). 相似文献