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931.
V. S. Bondarenko E. D. Korniets B. A. Sokolenko N. B. Kovrova 《Russian Chemical Bulletin》1993,42(2):388-389
The temperature dependence of the1H NMR spectra ofcis-[Pt(II)R2Cl2] complexes was studied in DMSO at 18–100°C (R is 2-methyl and 2,5-dimethylpyridine). The broadening of the signals from the methyl groups or hydrogen atoms in theortho-positions of heteroaromatic ligands is due to the coexistence of two forms of thecis-complexes in solution. These forms arise from the hindered rotation of asymmetrical ligands around the Pt-N bond.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 424–425, February, 1993. 相似文献
932.
A technique is suggested for evaluating the properties of alkane conformers using the parameters of internal rotation of interdependent C-C bonds. To determine the mean conformational composition of a rotational equilibrium mixture of alkane conformers, one need not exhaust the latter because the contribution of the conformation energy to alkane enthalpy can be expressed in terms of the product of tensors with further convolution over indices. 相似文献
933.
Electron diffraction (ED) data for B2F4 recorded by Hedberg et al. over the temperature range –80 to +150°C have been used to obtain equilibrium geometry of this molecule in the framework of a large-amplitude motion model. The torsional coordinate has been adiabatically separated from the rest of vibrations. Two types of constraints applied to obtain ab initio torsional potential energy function (PEF) and the parameters of the geometry relaxation are discussed. The relations between anharmonic interaction force constants and the parameters of the geometry relaxation are briefly considered. Ab initio force constant matrices for rigid vibrational coordinates as well as large-amplitude torsional PEF have been scaled in the procedure of simultaneous fitting to the ED data and experimental vibrational frequencies. The resulting equilibrium geometry and potential function provided good fit to both ED and spectroscopic data. As expected, the results for the equilibrium geometry obtained from separate ED patterns recorded at different temperatures did not show noticeable temperature trend. The determined equilibrium structural parameters for B2F4 are: r
e
(B–B) = 1.719(4) Å, r
e
(B–F) = 1.309(2) Å, BBF = 121.1(1)°. Uncertainties given in parentheses include three times standard deviation and a systematic error. The rotational barrier height was evaluated as 160(50) cm–1. 相似文献
934.
The molecular structures of 2-nitro, 3-nitro, and 4-nitroaniline and their internal rotational isomers were calculated by
anab-initio method using HF/6-31G* basis set. The geometries were influenced by the nitro group's position. The perturbation of the amino
group on the nitro group was observed in a 2-nitroaniline isomer having a molecular structure distinct from that of the other
two isomers. Among them, 4-nitroaniline is the most stable one. Internal rotation tests of either the nitro or amino group
of 3-nitro and 4-nitroaniline indicate that no significant deformations of the phenyl ring occurred after internal rotation;
however, the internal rotational isomers of 2-nitroaniline differed from its original structure. Relatively easier internal
rotation of the nitro group than the amino group and different C-NO2 and C-NH2 bonds indicate the bond-breaking message of nitroanilines. As products of explosives induced by thermal or shock are of interest,
five products of 2-nitroaniline were selected to assess their geometries and energies. The above calculations revealed that
these products are thermodynamically unfavorable. 相似文献
935.
The potential response of a symmetrical configuration in which the LaF3-membrance is placed between two solutions is discussed. The electrode body provides contact with the inner surface of the fluoride membrane, with a solution containing Fe(CN)
6
3–
-Fe(CN)
6
4–
redox couple and a Pt wire as internal reference electrode. The electrode was examined in terms of potentialconcentration curves and potential-time response and shown to behave similarly to the commencal Orion fluoride electrode. The advantage of the proposed redox reference system is that the electrode has minimal drift immediately after assembly. 相似文献
936.
Freddy RommOleg Figovsky 《Journal of solid state chemistry》2002,164(2):237-245
A theoretical (thermodynamic) method for the estimation of mechanical characteristics of polymeric systems is proposed. This method uses the statistical polymer method for modeling of branched/cross-linked structures. The weak interaction between macromolecules is modeled in the approach of their mutual interpenetration. The proposed method is used for the estimation of mechanical resistance and stability of microporous polymeric materials. An engineer method for the evaluation of mechanical stability and resistance of polymeric materials is derived. 相似文献
937.
目前液相色谱串联质谱法测定动物源性食品中瘦肉精普遍采用酶水解提取、固相萃取净化的方式处理样品,该方法耗时长、分析成本高。 本研究采用酸水解和酶水解两种提取方式结合QuEChERS(Quick,Easy,Cheap,Effective,Rugged,Safe)净化和高效液相色谱串联质谱建立了动物性食品中特布他林、沙丁胺醇、莱克多巴胺和克伦特罗4种β2受体激动剂的快速定性确证和定量检测方法。 采用酶水解提取-QuEChERS净化处理样品,在电喷雾离子源正离子扫描(ESI+)和多反应监测(MRM)模式下,4种瘦肉精在1.0~20.0 μg/L浓度之间呈线性,线性相关系数均大于0.999,检出限和定量限分别为0.1和0.3 μg/kg,猪肉和牛肉样品中4种化合物的回收率为78.5%~112%,相对标准偏差RSD为2.8%~8.9%。 采用酸水解法代替酶水解提取时,尽管对于样品中莱克多巴胺测定结果稍偏低,但样品前处理时间大大缩短。 两种提取方法结合使用对于提高瘦肉精引起的食物中毒应急处置效率具有重要意义。 相似文献
938.
《Surface and interface analysis : SIA》2003,35(3):276-281
Selective oxidation in silicon steel shows several interesting phenomena, such as the formation of an internal oxidation zone that depends on the oxidation conditions and the steel composition. In this work, SIMS and XPS were used for characterizing the formation processes of surface layers formed during selective oxidation of a typical silicon steel. The starting material is a secondary‐recrystallized 3 mass% Si‐steel sheet with a surface orientation of (011). Sample sheets were annealed at a temperature of 948–1023 K under an atmosphere with a low partial pressure of oxygen. The SIMS depth profiles show that the internal oxidation zone thickens and an iron‐rich layer that formed on the internal oxidation zone expands as the annealing temperature increases. Manganese and chromium levels increase outside the internal oxidation zone, whereas tin exists in the internal oxidation zone. The XPS results of the sample surface show that silicon and manganese levels increase on the sample surface to form oxides, and the chemical composition and state of these elements depend on the annealing temperature. In addition, tin increases on the surface of a relatively thick iron‐rich layer that formed on the internal oxidation layer. These experimental results are discussed on the basis of the thermodynamic characteristics of the elements. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
939.
Temperature dependence of the EPR spectrum of 2-trifluoromethylnitrobenzene radical anion in anhydrous acetonitrile in the
temperature range 217 K ≤ T ≤ 296 K was studied and simulated. Temperature-dependent dynamic modulation of the fluorine isotropic hyperfine structure
is caused by slow hindered rotation of CF3 group with an activation energy of E
F* = 36.5±0.5 kJ mol−1, which is the highest value for motions in π-type free radicals studied to date.
Dedicated to the memory of Academician V. A. Koptyug on the occasion of the 75th anniversary of his birth.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 926–931, June, 2006. 相似文献
940.
Galeev R. V. Gunderova L. N. Mamleev A. H. Shapkin A. A. Pozdeev N. M. Grikina O. E. Proskurnina M. V. Khaikin L. S. 《Russian Chemical Bulletin》2001,50(9):1605-1611
The microwave spectrum of 2-chloro-4,5-dimethyl-1,3,2-dioxaphospholene (1) was studied in the frequency range from 7 to 53 GHz. Rotational transitions of the parent molecule in the ground and eleven excited vibrational states and those of its mono-substituted 37Cl, 13CMe, and 13CCycle isotopomers in the ground vibrational state were identified. Rotational constants and partial r
s-structure were obtained. The quartic centrifugal distortion constants, dipole moment components a = 3.8D and c = 0.24D (the total dipole moment is 3.81D), and the 35Cl quadrupole coupling constants were determined for the parent molecule. The fine structure of the microwave transitions in the parent molecule was analyzed under the assumption of noninteracting methyl groups. The height of the barrier to internal rotation (V
30 = V
03 = 665 cm–1) and the frequency of torsional vibrations ( = 167 cm–1) were found. The frequencies of two lowest vibrational modes corresponding to deformation vibrations of the five-membered ring were estimated (100 cm–1) from the relative intensities of rotational transitions for different vibrational states. 相似文献