全文获取类型
收费全文 | 3037篇 |
免费 | 453篇 |
国内免费 | 206篇 |
专业分类
化学 | 1063篇 |
晶体学 | 30篇 |
力学 | 684篇 |
综合类 | 42篇 |
数学 | 360篇 |
物理学 | 1517篇 |
出版年
2023年 | 23篇 |
2022年 | 52篇 |
2021年 | 62篇 |
2020年 | 67篇 |
2019年 | 57篇 |
2018年 | 66篇 |
2017年 | 112篇 |
2016年 | 95篇 |
2015年 | 91篇 |
2014年 | 134篇 |
2013年 | 221篇 |
2012年 | 146篇 |
2011年 | 188篇 |
2010年 | 156篇 |
2009年 | 170篇 |
2008年 | 162篇 |
2007年 | 195篇 |
2006年 | 210篇 |
2005年 | 149篇 |
2004年 | 158篇 |
2003年 | 160篇 |
2002年 | 133篇 |
2001年 | 86篇 |
2000年 | 102篇 |
1999年 | 123篇 |
1998年 | 91篇 |
1997年 | 82篇 |
1996年 | 62篇 |
1995年 | 50篇 |
1994年 | 42篇 |
1993年 | 43篇 |
1992年 | 35篇 |
1991年 | 18篇 |
1990年 | 16篇 |
1989年 | 18篇 |
1988年 | 7篇 |
1987年 | 13篇 |
1986年 | 13篇 |
1985年 | 11篇 |
1984年 | 16篇 |
1983年 | 4篇 |
1982年 | 11篇 |
1981年 | 11篇 |
1980年 | 7篇 |
1979年 | 5篇 |
1978年 | 7篇 |
1976年 | 8篇 |
1971年 | 1篇 |
1959年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有3696条查询结果,搜索用时 93 毫秒
161.
全内反射荧光显微镜技术是当今最灵敏的生物成像和检测方法之一,可以直接探测单个荧光分子。这种方法已成功地用于生命科学、化学、物理学等研究领域,获得了常规方法无法得到的重要信息。本文介绍了全内反射荧光显微镜的工作原理和实验技术,总结了近年来这种单分子检测方法在生命科学、化学等领域的重要应用,并对其发展前景进行了展望。 相似文献
162.
163.
Using the new two-dimensional cranking relativistic mean field (RMF) approach, the shears mechanism of magnetic rotation based on configuration πh121/2νh-211/2 in 142Gd is microscopically and self-consistently examined by investigating the aligning angular momenta of the valence nucleons. 相似文献
164.
Vadim V. Ilyushin Zbigniew Kisiel Heinrich Mäder 《Journal of Molecular Spectroscopy》2010,259(1):26-12194
A new program is described for fitting rotation-torsion energy levels in molecules like toluene, in which the frame (C6H5) has C2v symmetry and the methyl top has C3v symmetry, i.e., for molecules where the internal rotation barrier is expanded in cos6nα, where α is the internal rotation angle and n = 1,2,…. The program is based on the theoretical framework developed by Sørensen and Pedersen in their application of the Longuet-Higgins permutation-inversion group G12 to the microwave spectrum of CH3NO2. It is specifically designed for sixfold barrier molecules, and allows the user to select almost any symmetry-allowed torsion-rotation term for inclusion in the fitting Hamiltonian. This program leads to a very successful fit of transitions in the microwave spectrum of toluene characterized by J ? 30, Ka ? 12, and by the free-rotor quantum number ∣m∣ ? 3. In these fits we included both published and rather extensive unpublished new measurements, for which fits using other torsion-rotation programs have not been very successful. The fit presented here uses 28 parameters to give an overall standard deviation of 7.4 kHz for 372 line frequencies, and results in a much improved value for the sixfold barrier for toluene, V6 = 13.832068(3) cal mol−1. 相似文献
165.
166.
R.Y. Hong Y.J. Wu G.Q. Di B. Xu D.G. Wei 《Journal of magnetism and magnetic materials》2009,321(8):1106-1110
Bi-substituted yttrium iron garnet (Bi-YIG, Bi1.8Y1.2Fe5O12) nanoparticles were prepared by microwave-assisted co-precipitation as well as conventional co-precipitation using ammonia aqueous solution as precipitant. The nanoparticles were characterized by thermal gravity-differential thermal analysis, X-ray powder diffraction, transmission electron microscopy, dynamic light scattering and vibrating sample magnetometer, respectively. The Faraday rotation of Bi-YIG modified PMMA slices was also investigated. Results demonstrate that the Bi-YIG nanoparticles prepared by microwave-assisted co-precipitation show smaller particle size and higher Faraday rotation than those prepared by conventional co-precipitation. 相似文献
167.
G. Brunner 《Isotopes in environmental and health studies》2013,49(12):420-424
Modern radiometric analytics demands a complex consideration of nuclear and electron shell processes, if more pretentious aims are envisaged. As an example the small variation of decay rates of radionuclides presents possibilities for information on chemical situations of decaying atoms. In principle this phenomenon is well known since many years, but now the situation is such that, e.g. in 99mTc internal conversion, a full agreement of the difficult experiments and the respective theory was established. The secondary emission of X-rays as a consequence of high excitation of electron shells in combination with nuclear transitions supplies another example for a methodical progress of radiometry. Investigations on 51Cr as an electron capture nuclide have shown that chemically induced variations of the Kα to Kβ X-ray intensity ratio is at least qualitatively understood. 相似文献
168.
Sergey P. Gavrish 《Journal of computational chemistry》2012,33(27):2173-2179
Fairly accurate approximate expressions for commonly used characteristics of non‐planarity of trigonal sp2‐hybridized centers are reported. It is shown that the behavior of all these parameters as a function of bond angles (α, β, γ) is determined primarily by the square‐root of the difference [360° ? (α + β + γ)]. This quantity is proposed as a new versatile measure of pyramidalization. © 2012 Wiley Periodicals, Inc. 相似文献
169.
High-spin states in nucleus 139Pm have been studied using the reaction 116Cd(27Al,4n)139Pm.Two dipole cascades have been found.Spin and parity assignments were based on the Directional Correlation of Oriented Nuclei(DCO) ratios and systematic behavior in neighboring odd-proton nuclei.The level structures of 139Pm are compared with those of the N =78 isotone 141Eu in which two dipole bands have been confirmed as magnetic rotational bands.The close similarity between them suggests that the dipole bands in 139... 相似文献
170.