(Gd,Lu)3Al5O12∶Tb3+,Eu3+透明陶瓷制备与发光性能

通过简单的化学沉淀法制备了纳米前驱体,结合真空烧结工艺,制备了一系列镥稳定钆铝石榴石{(Gd, Lu)₃Al₅O₁₂∶Tb,Eu}透明陶瓷。将透明陶瓷加工成1 mm厚的圆片,对透明陶瓷样品进行了X射线衍射、光致发光、透过率和衰减时间等表征。高温烧结过后,陶瓷样品仍保持稳定的石榴石相。选定313 nm作为透明陶瓷的激发波长,可获得最强的荧光发射。此外,通过对不同样品进行紫外可见荧光测试,获得了由绿光到红光的可调节发射。在313 nm激发,543 nm和591 nm的监测波长下,透明陶瓷样品均具有Eu³⁺的毫秒级衰减时间。     

Effects of land use patterns on soil aggregate stability in Sichuan Basin, China

Soil aggregate stability as a key indicator of soil structure, is a product of interactions between soil environment, management practices, and land use patterns. The objective of this study was to analyze the impact of various land use patterns on soil aggregate stability in Sichuan Basin of southwestern China. The dry- and water-stable aggregate size distributions were determined by manual dry sieving procedure and Yoder's wet sieving procedure, respectively, while microaggregates and its mechanical and chemical stabilities by Kachisky's method, oscillator method, and citrate-dithionate (C-D) reagent method, separately. The results indicated that fractal dimension and surface fractal dimension were useful indicators to reflect soil aggregate distribution. Land use patterns have an obvious influence on soil aggregate stability. In the study area, water stability, mechanical stability, and chemical stability followed the sequence, Barren landforestlandorchardcropland, and the original stability and collapse velocity were sensitive to soil properties and soil structure. The difference of aggregate stability under different land use patterns is mainly due to the intensity of human disturbance and cultivation. Improper land use patterns will lead to breakdown of unstable aggregates, producing finer and more-easily transportable particles and microaggregates. In the future, inappropriate cultivation and land use patterns should be changed to protect soil structure, to improve soil aggregate stability and soil fertility in Sichuan Basin.     

Traveling Fronts in Monostable Equations with Nonlocal Delayed Effects

In this paper, we study the existence, uniqueness and stability of traveling wave fronts in the following nonlocal reaction–diffusion equation with delay

基于波动模态耦合的铝电解槽磁流体稳定性傅立叶级数法分析

铝电解槽内磁流体稳定性对铝电解生产有重要影响。本文结合铝电解槽实体仿真的电磁场计算结果,应用傅立叶级数法对槽内磁流体波动稳定性进行数值计算,并对波动的模态耦合问题进行了重点分析。在此基础上,本文以某320kA铝电解槽为研究载体分析了槽长宽比设计对磁流体稳定性的影响,结果表明:波动的不稳定分量集中分布在频谱图中重力波模态密集的低频区域;不考虑母线对体系的影响,增大槽的长宽比,有利于提高磁流体的稳定性。     

激光多孔端面气体非接触机械密封稳定性分析

基于气体润滑理论,采用与螺旋槽端面密封的对比分析方法,研究了均匀分布激光加工多孔端面气体非接触机械密封的稳定性,数值分析了密封间隙、不对中角度和外界扰动对开启力、泄漏量、气膜刚度以及密封间隙扰动振幅等密封参数的影响规律.结果表明:多孔密封中的动压效应微弱,开启力与气膜刚度与转速无关,密封端面开启时容易发生接触磨损;多孔密封端面压力分布均匀,不对中引起的开启力波动幅度小,但是角向容易产生自激振动,密封环外侧容易发生接触磨损;多孔密封轴向气膜刚度较小,具有更小的扰动振幅,密封端面开启后有利于保持密封间隙的稳定,减少密封端面的接触摩擦.     

固定接触界面法向静弹性刚度

基于Hertz接触理论推导了两个微凸体之间互相作用的法向接触静弹性刚度.根据修正后的一个微接触点的平截面积尺寸分布,给出了界面的总法向接触静弹性条件刚度、总条件载荷的解析解.将法向静弹性刚度的解析解嵌入到有限元软件中,获得整机的理论模态.通过实验对解析解进行了定量验证.以机床结合部为研究对象,在理论振型与实验振型一致的...     

SURFACE STRESS EFFECT IN MECHANICS OF NANOSTRUCTURED MATERIALS

This review article summarizes the advances in the surface stress effect in mechanics of nanostructured elements,including nanoparticles,nanowires,nanobeams,and nanofilms,and heterogeneous materials containing nanoscale inhomogeneities.It begins with the fundamental formulations of surface mechanics of solids,including the definition of surface stress as a surface excess quantity,the surface constitutive relations,and the surface equilibrium equations.Then,it depicts some theoretical and experimental studies of the mechanical properties of nanostructured elements,as well as the static and dynamic behaviour of cantilever sensors caused by the surface stress which is influenced by adsorption.Afterwards,the article gives a summary of the analytical elasto-static and dynamic solutions of a single as well as multiple inhomogeneities embedded in a matrix with the interface stress prevailing.The effect of surface elasticity on the diffraction of elastic waves is elucidated.Due to the difficulties in the analytical solution of inhomogeneities of complex shapes and configurations,finite element approaches have been developed for heterogeneous materials with the surface stress.Surface stress and surface energy are inherently related to crack propagation and the stress field in the vicinity of crack tips.The solutions of crack problems taking into account surface stress effects are also included.Predicting the effective elastic and plastic responses of heterogeneous materials while taking into account surface and interface stresses has received much attention.The advances in this topic are inevitably delineated.Mechanics of rough surfaces appears to deserve special attention due to its theoretical and practical implications.Some most recent work is reviewed.Finally,some challenges are pointed out.They include the characterization of surfaces and interfaces of real nanomaterials,experimental measurements and verification of mechanical parameters of complex surfaces,and the effects of the physical and chemical processes on the surface properties,etc.     

大开口复合材料加筋壁板稳定性分析

运用大型有限元软件Patran/Nastran分析了大开口复合材料加筋壁板的稳定性,并对不同加筋方式下壁板屈曲特征值和屈曲模态图进行了比较。结果表明:补强提高了大开口复合材料壁板的稳定性,但往往无法达到很好的效果,需要通过加筋改善其稳定性;加筋复合材料壁板稳定性较原有模型有较大提高;加筋大开口复合材料壁板屈曲特征值随筋条距开口中心距离的增加而减小,其屈曲分界线均位于筋条布置处;纵筋大开口复合材料加筋壁板一阶屈曲特征值为2.13,而横筋只达到1.08;纵筋布置对复合材料壁板稳定性影响明显高于横筋布置,可在实际工程应用中适当增加纵筋的布置。     

表面形貌变形对塑性成形滑动接触界面摩擦的影响

为了更好地理解塑性成形滑动接触界面的摩擦行为,构建了一种新型的摩擦试验装置,运用表面纹理化技术制备了两类表面形貌的1050铝材试件,在不同的接触压力和滑动速度条件下进行一系列拉伸摩擦试验.对试验前后试件三维表面形貌进行了测量;提取真实接触面积比、封闭空体面积比和开放空体面积比等三维表面参数,来描述试件表面形貌的变化.试验发现:摩擦系数随名义接触压力和滑动速度增加而逐渐减小;试件初始表面形貌对摩擦有明显的影响;试件表面形貌和参数随接触条件出现了规律性变化.基于机械流变模型的分析表明:随着试件表面形貌变形,不同的机理决定界面摩擦行为,摩擦系数对名义接触压力和滑动速度的依赖性可分别归因于微观塑性流体动压润滑效应和入口区流体动压牵引效应.     

扩散型气柱界面R-M失稳中混合率的实验研究

Richtmyer-Meshkov(R-M)不稳定性普遍存在于众多工程问题中,激波管实验是研究R-M失稳问题的主要手段.高精度的平面激光诱导荧光(planar laser-induced fluorescence,PLIF)技术具有分子量级的示踪能力,可获得界面气体浓度(摩尔分数)分布,为研究界面失稳混合问题提供了有力工具.在弱激波(Ma=1.25)冲击扩散型气柱界面实验中,采用PLIF技术对R-M失稳引起的SF6-Air界面混合问题进行了研究.通过改变椭圆形初始界面的长短轴比,得到了3种扩散型初始界面失稳演化过程中气体摩尔分数,观察到了斜压机制下界面的简单拉伸、二次不稳定性、挤压射流等现象.利用浓度分布进一步得到了界面的瞬时混合率,通过瞬时混合率、界面整体平均混合率以及混合率的概率密度分布,分析了界面在不同演化阶段的界面混合特征,初步讨论了界面失稳混合的机制.演化初期,界面在斜压涡的作用下发生拉伸卷曲,通过增大浓度梯度来促进界面的混合.当演化进一步发展,二次不稳定性出现后,界面通过小尺度对流的方式达到湍流混合状态,而浓度梯度驱使的分子间混合逐渐减弱.由浓度梯度引起的扩散与由二次不稳定性引起的对流存在着"竞争"关系,二者共同主导了界面的混合.