(NH4)Bi2(IO3)2F5: An Unusual Ammonium‐Containing Metal Iodate Fluoride Showing Strong Second Harmonic Generation Response and Thermochromic Behavior

An ammonium‐containing metal iodate fluoride compound, (NH₄)Bi₂(IO₃)₂F₅, featuring a two‐dimensional double‐layered framework constructed by [BiO₂F₅]^6? and [BiO₄F₄]^9? polyhedra, as well as [IO₃]^? groups, was successfully synthesized. The well‐ordered alignment of these SHG‐active units leads to an extraordinary strong SHG response of 9.2 times that of KDP. Moreover, this compound possesses a large birefringence (Δn=0.0690 at 589.3 nm), a wide energy band gap (E_g=3.88 eV), and a high laser damage threshold (LDT; 40.2×AgGaS₂). In particular, thermochromic behavior was observed for the first time in this type of compound. Such multifunctional crystals will expand the application of nonlinear optical materials.     

Lead Mixed Oxyhalides Satisfying All Fundamental Requirements for High‐Performance Mid‐Infrared Nonlinear Optical Materials

To design high‐performance mid‐infrared (mid‐IR) nonlinear optical (NLO) materials, we have focused on the combination of a heavy metal lone pair cation, Pb²⁺ and mixed oxyhalides. A systematic investigation in PbO‐PbCl₂‐PbBr₂ system led us to discover the first examples of NLO lead mixed oxyhalides, namely, Pb₁₃O₆Cl₄Br₁₀, Pb₁₃O₆Cl₇Br₇, and Pb₁₃O₆Cl₉Br₅. All the reported materials have remarkably comprehensive properties including broad IR transparency (up to 14.0 μm), qualified second harmonic generation (SHG) responses (0.6–0.9×AgGaS₂), wide band gaps (3.05–3.21 eV), and ease of crystal growth. Interestingly, a centimeter‐sized single crystal (2.9×1.3×0.5 cm³) of Pb₁₃O₆Cl₉Br₅ revealing a wide transparent range (0.384–14.0 μm) and high laser damage threshold (LDT) (14.6×AgGaS₂) has been successfully grown in an open system. The study suggests that all the reported mixed oxyhalides are outstanding candidates for mid‐IR NLO materials.     

测量光纤外腔Fabry-Perot干涉仪的白光干涉术

提出了一种基于白光干涉术测量低锐度光纤外腔Fabry Perot干涉仪（EFPI）的方法用宽带光源注入F P腔,在接收端用一高锐度的可调谐光纤F P滤波器对EFPI的反射光谱进行扫描,获得了周期性变化的光谱输出为了测量出EFPI的腔长,对光谱信号进行傅里叶变换,得到光谱的周期,由此求出EFPI的绝对腔长证明了用低锐度EFPI的测量准确度由腔长决定F P腔越长,测量准确度越高在腔长分别是200 μm,400 μm和600 μm时,测量的腔长与实际腔长相同.     

低偏振相关损耗全息光栅波分复用器的设计

对基于掺杂铌酸锂材料的体光栅波分复用器主要结构和光栅记录参量提出了一种优化设计方法.采用严格耦合波理论,对两种偏振不同入射角和不同记录晶体厚度下的器件关键性能参量,如插入损耗和偏振相关损耗等进行了优化.数值结果证明采用优化设计的晶体厚度和光栅记录时的入射角,在获得相当低的偏振相关损耗的同时,也能够获得较低的插入损耗,实现了综合性能优化的波分复用器设计.实验结果证明用优化设计的参量能有效降低波分复用器件的插入损耗和偏振相关损耗.     

转移矩阵法在负折射率介质材料平板波导中的应用研究

利用严格电磁理论,推导出了适用于负折射率介质材料光波导的转移矩阵,分析讨论了转移矩阵的性质和应用.利用转移矩阵方法,推导出导波层为负折射率介质材料、覆盖层和衬底为右手材料的三层对称介质光波导的本征色散方程.用图解法研究了负折射率介质波导中TE波的异常色散特性.在负折射材料介质波导中没有零阶模,最低阶为1阶模,并且有截止频率,只有波导参量满足一定条件的时候才会存在,导模的横向波数可以为实数和纯虚数,而正折射率介质波导导模的横向波数只能为实数.     

阵列波导光栅波分复用/解复用器光谱响应效率的理论模型

基于单模光波导的本征模场分布,瑞利－索末菲衍射积分公式和天线原理的互易定理,给出耦合器中两个非接触平面光波导耦合特性的描述.基此,根据等光程差不等振幅多光束干涉的光场叠加原理,推导出新颖的阵列波导光栅波分复用/解复用器的光谱响应效率的解析函数表达式,这些表达式可为快速精确分析阵列波导光栅波分复用/解复用器的特性提供理论基础.同时,介绍了一个计算阵列波导光栅波分复用/解复用器特性的例子,给出其光谱响应度和信号通道串扰.     

烷氧基取代聚对苯乙炔三阶非线性光学性能

通过双醚化反应、氯甲基化反应以及在强碱性条件下进行的脱氯化氢反应制备聚（2-甲氧基-5-丁氧基）对苯乙炔（PMOBOPV）、聚（2-甲氧基-5-己氧基）对苯乙炔（PMOHOPV）、聚（2,5-二丁氧基）对苯乙炔（PDBOPV）和聚（2,5-二己氧基）对苯乙炔（PDHOPV）等四种可溶性聚对苯乙炔（PPV）衍生物,通过紫外-可见吸收光谱对产物分子结构进行表征.结果显示,PMOBOPV、PMOHOPV、PDBOPV和PDHOPV的共轭π电子发生π → π* 跃迁的吸收峰分别位于491 nm、495nm、504nm和510nm处,相应的光学禁带宽度分别为2.23eV、2.18eV、2.12eV和2.07eV.利用简并四波混频技术测量PPV衍生物的三阶非线性光学性能,探讨了分子结构对PPV衍生物三阶非线性极化率（χ(3)）的影响.研究发现,激发波长为532 nm时,PMOBOPV、PMOHOPV、PDBOPV和PDHOPV的共振χ(3)值分别为3.45×10－10、5.13×10－10、7.15×10－10和9.61×10－10 esu;激发波长为1064 nm时,它们的非共振χ(3)值分别为1.09×10－11、1.42×10－11、1.62×10－11和2.14×10－11 esu.     

位移约束集成化处理的连续体结构拓扑优化

为解决多工况下多位移约束的连续体结构拓扑优化问题,引入了K-S函数对位移约束进行集成化处理.在建立优化模型时,基于莫尔定理按ICM方法导出约束点位移与设计变量之间的近似显函数关系,然后采用Lagrange乘子法进行求解.给出三个算例对该方法进行验证,并与ESO法、BESO法、MD法以及均匀化方法的结果进行比较.结果表明:该方法计算效率较高,并且能够计算出更合理的结构拓扑.