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171.
Fiber‐Based Flexible All‐Solid‐State Asymmetric Supercapacitors for Integrated Photodetecting System
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Xianfu Wang Bin Liu Rong Liu Qiufan Wang Xiaojuan Hou Prof. Di Chen Prof. Rongming Wang Prof. Guozhen Shen 《Angewandte Chemie (International ed. in English)》2014,53(7):1849-1853
Integrated nanodevices with the capability of storing energy are widely applicable and have thus been studied extensively. To meet the demand for flexible integrated devices, all‐solid‐state asymmetric supercapacitors that simultaneously realize energy storage and optoelectronic detection were fabricated by growing Co3O4 nanowires on nickel fibers, thus giving the positive electrode, and employing graphene as both the negative electrode and light‐sensitive material. The as‐assembled integrated systems were characterized by an improved energy storage, enhanced power density (at least by 1860 % enhanced) by improving the potential window from 0–0.6 V to 0—1.5 V, excellent photoresponse to white light, and superior flexibility of both the fiber‐based asymmetric supercapacitor and the photodetector. Such flexible integrated devices might be used in smart and self‐powered sensory, wearable, and portable electronics. 相似文献
172.
Dr. Marina Büchert Torben Steenbock Christian Lukaschek Marie C. Wolff Prof. Dr. Carmen Herrmann Prof. Dr. Jürgen Heck 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(44):14351-14361
Parallel alignment of dipolar electron‐donor–π‐bridge‐electron‐acceptor entities can strongly enhance their nonlinear optical properties. This favorable arrangement can be in principle achieved by linking these units covalently or through metal coordination. Four dipolar single‐strand chromophores decorated with a 5‐electron‐donor–5′‐electron‐acceptor‐modified 2,2′‐bipyridine functionality were synthesized. For two of these chromophores triple‐stranded dendritic structures were successfully formed. All of the compounds were characterized with respect to their linear and nonlinear optical properties. For the aldehyde derivatives an enhancement of the first hyperpolarizability of 4.5 rather than 3 was obtained when going from single to triple strands. Theoretical calculations with density functional theory suggest that interstrand transitions contribute to the optical properties of the dendritic structures. 相似文献
173.
采用密度泛函理论B3LYP方法得到了M@t-Bu-calix[4]arene和(M@t-Bu-calix[4]arene)Li′(M=Li,Na,K)体系的几何结构.其中(M@t-Bu-calix[4]arene)Li′(M=Li,Na,K)三个体系各有5个稳定异构体,在前三个异构体中,碱金属与t-Bu-calix[4]arene分子间具有很强的相互作用能,说明了体系的稳定性.在部分(M@t-Bucalix[4]arene)Li异构体中Li′原子以阴离子形式存在,整个体系表现出碱金属化物的特性.此外,使用CAMB3LYP方法计算了t-Bu-calix[4]arene及碱金属掺杂后体系的非线性光学性质.结果表明,t-Bu-calix[4]arene内部掺杂一个碱金属原子M后,体系的一阶超极化率(β0)有较大提高,而在配体外部又掺杂一个Li原子后,体系具有更大的β0值.其中(M@t-Bu-calix[4]arene)Li′体系的MLi′-4异构体表现出最高的β0值(41827-114354 a.u.),并且随着M原子序数的增加而逐渐增大.可见,碱金属掺杂是提高t-Bu-calix[4]arene非线性光学响应的一种有效策略. 相似文献
174.
Experimental and Theoretical Investigation of the First‐Order Hyperpolarizability of Octupolar Merocyanine Dyes
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Dr. Frédéric Castet Dr. Mireille Blanchard‐Desce Frédéric Adamietz Yevgen M. Poronik Prof. Dr. Daniel T. Gryko Prof. Dr. Vincent Rodriguez 《Chemphyschem》2014,15(12):2575-2581
Hyper‐Rayleigh scattering experiments and quantum chemical calculations are combined to investigate the second‐order nonlinear optical responses of a series of three‐arm merocyanine derivatives. They exhibit an octupolar hyperpolarizability response with lower amplitude than crystal violet due to a lower extent of the photoinduced charge transfer and reduced bond length alternation. Strong effects on the second‐order optical response measured close to the two‐photon absorption level are clearly evidenced; for example, the effective measured polarization ratio deviates below the ideal octupolar value of 3/2 even at very low excitation power. These effects are attributed to two‐photon absorption resonance, which we believe modifies dynamically the population of the ground state versus that of the excited state. 相似文献
175.
搭建了微流控芯片简易安培检测器,并用于市售药品烟酰胺片中烟酰胺含量的测定。由碳纳米管微圆盘电极和钛管组成集成双电极,中间的碳纳米管微圆盘电极作为安培检测的工作电极,外套的钛管既作为安培检测的对极,又充当分离高压电源的地极,使其结构更加简化和微型化。优化了缓冲溶液种类、浓度,分离电压及进样时间等实验条件。结果表明,在10 mmol·L-1磷酸盐缓冲液(pH 7.8)中,进样10 s,在2.0kV电压下分离,烟酰胺在2 min内可实现较好的分离和检测,其线性范围为10~600μmol·L-1,检出限(S/N=3)为5.0μmol·L-1,相对标准偏差(RSD)为3.0%,平均加标回收率为99.1%。该装置实现了微型化和集成化,并具有检测灵敏度较高、选择性好、成本低等特点,可用于药品的质量控制。 相似文献
176.
Polymer network liquid crystal (PNLC) spatial light modulators are attractive for display and photonic applications because they can achieve submillisecond response time while keeping a large phase change. However, their on-state scattering caused by the grain boundary of LC multidomains hinders their applications. In this article, we review recent progress on the development of scattering-free PNLCs extending from short-wavelength infrared to visible region by reducing the domain sizes to ∼200 nm through low temperature curing process. To reduce operation voltage, both transmissive and reflective modes, LC material properties (birefringence and dielectric anisotropy), polymer composition and concentration, and pretilt angle effect are analyzed. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2014 , 52, 183–192 相似文献
177.
Dr. Min Luo Dr. Chensheng Lin Donghong Lin Prof. Ning Ye 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(37):16112-16115
The first fluorosulfonic ultraviolet (UV) nonlinear optical (NLO) material, C(NH2)3SO3F, is rationally designed by taking KBe2BO3F2 (KBBF) as the parent compound. C(NH2)3SO3F features similar topological layers as KBBF by replacing inorganic (BO3)3− with organic C(NH2)3+ trigonal units and BeO3F with SO3F− tetrahedra. Therefore, C(NH2)3SO3F is a metal-free UV NLO crystal. Benefiting from the coplanar configuration of the C(NH2)3+ cationic groups, it possesses a large SHG response of 5×KDP and moderate birefringence of 0.133@1064 nm. Besides, it has a short UV cutoff edge of 200 nm. The calculated results reveal the shortest SHG phase-matching wavelengths can reach 200 nm. These findings highlight the exploration of metal-free compounds as nontoxic and low-cost UV NLO materials as a new research area. 相似文献
178.
Birgit Fuchs Prof. Dr. Gunter Heymann Xuefei Wang Abudukadi Tudi Dr. Lkhamsuren Bayarjargal Dr. Renée Siegel Adrian Schmutzler Prof. Dr. Jürgen Senker Dr. Bastian Joachim-Mrosko Dr. Andreas Saxer Prof. Dr. Zhihua Yang Prof. Dr. Shilie Pan Prof. Dr. Hubert Huppertz 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(30):6851-6861
La3B6O13(OH) was obtained by a high-pressure/high-temperature experiment at 6 GPa and 1673 K. The compound crystallizes in the space group P21 (no. 4) with the lattice parameters a=4.785(2), b=12.880(4), c=7.433(3) Å, and β=90.36(10)°, and is built up of corner- as well as edge-sharing BO4 tetrahedra. It represents the first acentric high-pressure borate containing these B2O6 entities. The compound develops borate layers of „sechser“-rings with the La3+ cations positioned between the layers. Single-crystal and powder X-ray diffraction, vibrational and MAS NMR spectroscopy, second-harmonic generation (SHG) and thermoanalytical measurements, as well as computational methods were used to affirm the proposed structure and the B2O6 entities. 相似文献
179.
In this study,two new dendronized nonlinear optical(NLO)polymers were synthesized with high FTC chromophore loading density by introduction of high generation chromophore dendrons on the side chains.Due to their suitable molecular weights,both of them possessed good solubility in common solvents.They also inherited the advantages of dendrimers(large NLO coefficient),especially for PG2 whose NLO coefficient d33 value was as high as 282 pm·V^–1.Also,PG2 had a good temporal stability with 80%of its maximum value being retained at the temperature as high as 129℃. 相似文献
180.
ABSTRACTA D-shaped photonic crystal fibre filled with liquid crystal was demonstrated as an amphibious sensor for detection of both temperature and refractive index, when combined with plasma materials. Specifically, the optical component is implanted into a complete optical system ensuring modulation of the external electric field. When the refractive index of the external solution changes from 1.0 to 1.6, the y-polarised mode has a loss spectrum with a wavelength sensitivity of up to 2275 nm/RIU, and the corresponding amplitude sensitivity is ?88.2RIU?1. When the perceived temperature changes from 15°C to 50°C, the temperature of the sensor is correspondingly expressed as the maximum wavelength sensitivity of 9.09 nm/°C and the amplitude sensitivity of ?0.311°C?1. In addition, the actual micro-operation processes have been studied in detail, such as polishing depth, coating thickness and coating method. This provides practical ideas for real-time sensing analysis that requires harsh environments. 相似文献