New band systems of NiBr molecule in visible region

Thermal emission spectrum of NiBr molecule excited by vacuum graphite tube furnace revealed the existence of ten new band sub-systems in the region λλ 5540-4720 Å which were attributed toA→X,B→X,C→X andD→X transitions. Vibrational analysis was carried out for each of the systems mentioned above.A ² Δ has been suggested as the ground state of NiBr molecule with an electronic interval of about 533 cm^?1. Transitions responsible for NiBr spectrum appear to be of the type²π–²Δ and²Δ–²Δ.     

从平面角和立体角讨论静电场中的某些电场等价性

本文利用平面角的概念讨论了均匀带电的直线微元和圆弧微元在圆心处的场强等价性,并将结论推广到一些均匀带电的线几何体;然后利用立体角的概念进一步讨论带电的平面微元和球面微元在球心处的场强等价关系,结果表明,只有非均匀的电荷面密度才能使两者等价．     

直流固态继电器电磁脉冲失效模式实验研究

采用电流注入法对某型直流固态继电器输入端与输出端的电磁脉冲损伤机制及失效模式进行了实验研究,结果表明：输入端注入电磁脉冲信号时,输出端会产生误动作,并可造成输入电路中三极管BE节产生短路损伤,导致输入端施加控制信号时输出端无法导通;输出端注入电磁脉冲信号时,可造成输出电路中MOSFET管的栅极和漏极产生短路损伤,导致输出端短路。     

SrB4 O7 : Eu磷光粉的制备及其发光性能

采用高温固相法合成了SrB₄O₇ : Eu荧光粉,并研究了不同原料、掺杂浓度、煅烧温度等因素对其发光性能的影响。发射光谱测试结果表明:SrB₄O₇ : Eu荧光粉的最佳Eu掺杂浓度为2%左右,进一步增大掺杂浓度会导致浓度猝灭。煅烧温度对基质组成影响较大,随着温度的升高,基质中BO₄四面体所占比例增大,有利于Eu³⁺离子的还原。以水合硼酸锶为原料制得样品的发光强度高于以SrCO₃和H₃BO₃为原料制得样品的发光强度。     

损伤粘弹性力学的广义变分原理及应用

从粘弹性材料的Boltzmann迭加原理和带空洞材料的线弹性本构关系出发,提出了一种损伤粘弹性材料具有广义力场的本构模型．应用变积方法得到了以卷积形式表示的泛函,并建立了损伤粘弹性固体的广义变分原理和广义势能原理．把它们应用于带损伤的粘弹性Timoshenko梁,得到了Timoshenko梁的统一的运动微分方程、初始条件和边界条件． 这些广义变分原理为近似求解带损伤的粘弹性问题提供了一条途径．     

The role of OH ions in the stabilization of F colour centres in LiF

Thermally Stimulated Depolarisation Current (TSDC) and optical methods are applied to a range of alkali-fluoride crystals in order to establish a model for the stable F ₂ ⁺ - like colour centres in LiF:OH^-. The experimental results for LiF:OH^- suggest that the OH^- defects are partially destroyed under ionising irradiation or during crystal growth. The low-temperature dielectric relaxation signals in LiF:OH^- and LiF:Mg²⁺,OH^- are attributed to highly interacting hydroxide ions and products of their destruction located in extended lattice defects. In LiF:OH^-, in contrast to other alkali halides, the results advocate for a defect-structure model, which considers a neutral defect (ND, probably O₂ or H₂) sited at the anion vacancy of the O^2--V _a ⁺ dipole and which possibly is the “nucleus” for the F ₂ ⁺ centre. The proposed F ₂ ⁺ (ND, O^-) model seems to better explain the dielectric results, compared to the older F ₂ ⁺ (O^2-) and F ₂ ⁺ (O^-) models. The estimate for the electric dipole moment derived from the experimental TSDC bands, gives a value for the F ₂ ⁺ - like centre in LiF:OH^- between those of the F ₂ ⁺ (O^-) and F ₂ ⁺ (O^2-) defects, in good agreement with the proposed F ₂ ⁺ (ND,O^-) model. The reduction of the activation energy barrier of the (re)orientation process of the Mg²⁺V _c ^- (OH^-) complexes in LiF:Mg²⁺,OH^-, and the low-temperature shift of their TSDC band, compared to the single Mg ₂ ⁺ V _c ^- peak in LiF:Mg²⁺, are tentatively ascribed to an increase in the crystal-lattice parameters owing to the presence of OH^- and/or products of its destruction. Received 31 August 2001 / Received in final form 30 March 2002 Published online 9 July 2002     

两侧有固体层负载时板中Lamb波的传播

本文研究了薄板二面有固体导负载时板中Ｌａｍｂ波的传播，从弹性波理论出发并结合应的边界条件，导出板中Ｌａｍｂ波的色散方程，数值计算表示，不管作为自由状态时板中Ｌａｍｂ波相速（板厚取定时）是大于或小于外层固体的声表面波波速，板中对称及反对称模式的Ｌａｍｂ波相速都随着外层固体层厚度增加而变化并且渐近于外层固体的声表面波波速，数值计算又表明，对很薄的板，板中对称及反对称模式的相速均随负载板的厚度呈线性变化     

金属薄膜中的量子尺寸效应

运用最子统计的方法，计算金属薄膜中电子的态密度、电子密度、弛豫时间、计算结果表明：这些物理量都是金属薄膜厚度的函数，且随着薄膜厚度作周期性振荡。     

Modeling of mixed liquor inorganic suspended solids and membrane flux at different ratio of SRT to HRT in a submerged membrane bioreactor

In order to investigate the influence of mixed liquor inorganic suspended solids (MLISS) on membrane flux at different ratio of sludge retention time (SRT) to hydraulic retention time (HRT) in a submerged membrane bioreactor (SMBR), a pilot scale test was conducted for 452 days using traditional Chinese medicine (TCM) wastewater as influent. SRT/HRT was controlled at 150, 480 and 750, respectively. The experimental results showed that the average values of MLISS were 1271.9, 1664.5 and 6898.8 mg/L at different SRT/HRT, respectively; MLISS were accumulated from 265.5 g/h to 4912.93 g/h, which indicated that SMBR could not steadily operate for a long period without sludge withdrawal. Sludge oxygen utilized rate (SOUR) decreased from 5.115 to 1.292 mgO₂/(gVSS h) and volume oxygen utilized rate (VOUR) increased from 10.84 to 18.13 mgO₂/(L h). Model of membrane flux and MLISS were developed under different temperature and operational pressure by regressions, which were then satisfactorily employed to predict the trend of membrane flux during the experiment.     

ZnO纳米棒／MEH-PPV异质结的复合电致隧穿发光

利用低温水热法生长的ZnO纳米棒（ZnO-NRs）,和p型有机半导体材料聚[2-甲氧基-5-（2-乙基己氧基）-1,4-苯撑乙烯撑]（MEH-PPV）复合制备了结构为“ITO/ZnO晶种/ZnO-NRs/MEH-PPV/Al”的发光器件。测试结果发现,该器件具有非常好的二极管整流特性。对ZnO-NRs/M EH-PPV异质结施加超过17 V的反向偏压时,可同时获得两种半导体材料的发光,且ZnO近紫外光（380 nm ）发射强度远大于 M EH-PPV的红橙光强度,发光功率随着反向偏压的增加迅速增强,然而施加正向偏压时未探测到发光。该器件的发光机理不同于其他文献报道的正偏压发光,而属于反偏压发光器件,其发光机理归因于有机无机复合异质结的界面特殊性和ZnO-NRs的纳米尺寸效应,反偏压下器件实现的是载流子隧穿发光,而正偏压时载流子以表面态的无辐射复合及漏电流方式消耗。