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991.
Rodolfo O. Esquivel Moyocoyani Molina-Espíritu Juan Carlos Angulo Juan Antolín Nelson Flores-Gallegos Jesús S. Dehesa 《Molecular physics》2013,111(19):2353-2365
In this work, we have investigated the complexity of the hydrogenic abstraction reaction by means of information functionals such as disequilibrium (D), exponential entropy (L), Fisher information (I), power entropy (J) and joint information-theoretic measures, i.e. the I–D, D–L and I–J planes and the Fisher–Shannon and López–Mancini–Calbet (LMC) shape complexities. The analysis of the information-theoretical functionals of the one-particle density was computed in position (r) and momentum (p) space. The analysis revealed that all of the chemically significant regions can be identified from the information functionals and most of the information-theoretical planes, i.e. the reactant/product regions (R/P), the transition state (TS), including those that are not present in the energy profile such as the bond cleavage energy region (BCER), and the bond breaking/forming regions (B–B/F). The analysis of the complexities shows that, in position as well as in the joint space, the energy profile of the abstraction reaction bears the same information-theoretical features as the LMC and FS measures. We discuss why most of the chemical features of interest, namely the BCER and B–B/F, are lost in the energy profile and that they are only revealed when particular information-theoretical aspects of localizability (L or J), uniformity (D) and disorder (I) are considered. 相似文献
992.
Yuzo Hosoya 《Annals of the Institute of Statistical Mathematics》1990,42(1):37-49
By means of second-order asymptotic approximation, the paper clarifies the relationship between the Fisher information of first-order asymptotically efficient estimators and their decision-theoretic performance. It shows that if the estimators are modified so that they have the same asymptotic bias, the information amount can be connected with the risk based on convex loss functions in such a way that the greater information loss of an estimator implies its greater risk. The information loss of the maximum likelihood estimator is shown to be minimal in a general set-up. A multinomial model is used for illustration. 相似文献
993.
J. Tervo M. Vauhkonen P. J. Vauhkonen J. P. Kaipio 《Mathematical Methods in the Applied Sciences》2000,23(4):357-377
This paper deals with the dynamics of non‐linear distributed parameter fixed‐bed bioreactors. The model consists of a pair of non‐linear partial differential (evolution) equations. The true spatially three‐dimensional situation is considered instead of the usual one‐dimensional approximation. This enables one to take into account the effects of flow profiles and the true location of the measurement transducer. The (output) evolution of the corresponding open‐loop control system is simulated. Furthermore, the associated closed‐loop system with respect to the relevant output function is considered. Especially, the asymptotic output tracking is found to be successful by applying the usual process based on the state feedback linearization. Copyright © 2000 John Wiley & Sons, Ltd. 相似文献
994.
组合利用统计和结构信息的道路提取算法 总被引:2,自引:0,他引:2
提出了一种组合利用统计和结构信息从遥感图像中提取道路的算法,这个算法包括三个处理步骤,利用道路的多种局部统计特性获得道路基元与道路段,以及利用能量函数提取道路边沿,在检测道路基元时,用统计分析来表达道路的结构信息,避免了提取线段来表达,增强了抗噪性与稳健性;在检测和拟合道路边沿时,能量函数中的参数由前面的运算结果确定,使算法具有自适应能力。 相似文献
995.
This letter presents a schematic circuit with capacitive coupling between the CPW Cavity Center Trace (resonated with electromagnetic mode) and the mechanical Nanoresonator mediated by Transmon, resulting in the Cross-Kerr electromechanical effect. Then we show the dynamics of quantum states, showing the generation of superposition states and bipartite entanglement of continuous variables through nonlinear quantum electrodynamics in the circuit. Finally, we calculated and estimated the parameter for mechanical outcome through phase measurements of the CPW Cavity Center Trace electromagnetic mode. 相似文献
996.
997.
998.
In a previous study, air sampling using vortex air samplers combined with species-specific amplification of pathogen DNA was carried out over two years in four or five locations in the Salinas Valley of California. The resulting time series data for the abundance of pathogen DNA trapped per day displayed complex dynamics with features of both deterministic (chaotic) and stochastic uncertainty. Methods of nonlinear time series analysis developed for the reconstruction of low dimensional attractors provided new insights into the complexity of pathogen abundance data. In particular, the analyses suggested that the length of time series data that it is practical or cost-effective to collect may limit the ability to definitively classify the uncertainty in the data. Over the two years of the study, five location/year combinations were classified as having stochastic linear dynamics and four were not. Calculation of entropy values for either the number of pathogen DNA copies or for a binary string indicating whether the pathogen abundance data were increasing revealed (1) some robust differences in the dynamics between seasons that were not obvious in the time series data themselves and (2) that the series were almost all at their theoretical maximum entropy value when considered from the simple perspective of whether instantaneous change along the sequence was positive. 相似文献
999.
1000.
声誉效应与经理报酬契约的关系研究 总被引:10,自引:1,他引:9
探讨了声誉对经理报酬契约的影响 .首先 ,分析了经理效用函数的组成 ,将声誉这个隐性激励约束因素引入经理的效用函数 .随后 ,建立了信息不对称下经理的报酬激励模型 .分析了声誉系数对契约中各要素的影响 ,说明了所有者可以利用经理的声誉效应来设计更加有利的报酬契约 .文章最后给出了主要结论 . 相似文献