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961.
962.
963.
Cloudpoint data for polystyrene/methylcyclohexane solutions extending over moderate ranges of pressure and molecular weight are available in the literature. Those data are supplemented with new results from this laboratory to fill in gaps and extend the MW range (to 761 ≤ MW/amu ≤ 2 × 107). The resulting data net is discussed and reasons to extend studies to higher pressure are presented. © 1996 John Wiley & Sons, Inc. 相似文献
964.
采用同步辐射能量色散X射线衍射技术、激光加热技术和金刚石对顶砧(DAC)高压装置,在温度为2 000 K和压力为23 GPa的范围内,对采自地幔二辉橄榄岩中的顽火斜方辉石,进行了原位的高温高压能量色散X射线衍射(EDXRD)测量。实验结果表明:当压力为15.3 GPa、温度为1 600 K时(相当于地球内部410 km处的地震波不连续界面的温压环境),顽火斜方辉石转变为橄榄石的β相——瓦兹利石(Wadsleyite)相;继续加温加压至2 000 K、23 GPa时(相当于地球内部670 km处的地震波不连续界面的温压环境),顽火斜方辉石相变为钛铁矿(Ilmenite)结构和钙钛矿(Perovskite)结构的混和相。实验结果进一步证明,在地幔中存在的两个地震波不连续界面是由橄榄石、顽火斜方辉石等矿物的相变引起的。 相似文献
965.
Juan Mentado-Morales Arturo Ximello-Hernndez Javier Salinas-Luna Vera L. S. Freitas Maria D. M. C. Ribeiro da Silva 《Molecules (Basel, Switzerland)》2022,27(2)
The thermochemical study of the 1,3-bis(N-carbazolyl)benzene (NCB) and 1,4-bis(diphenylamino)benzene (DAB) involved the combination of combustion calorimetric (CC) and thermogravimetric techniques. The molar heat capacities over the temperature range of (274.15 to 332.15) K, as well as the melting temperatures and enthalpies of fusion were measured for both compounds by differential scanning calorimetry (DSC). The standard molar enthalpies of formation in the crystalline phase were calculated from the values of combustion energy, which in turn were measured using a semi-micro combustion calorimeter. From the thermogravimetric analysis (TGA), the rate of mass loss as a function of the temperature was measured, which was then correlated with Langmuir’s equation to derive the vaporization enthalpies for both compounds. From the combination of experimental thermodynamic parameters, it was possible to derive the enthalpy of formation in the gaseous state of each of the title compounds. This parameter was also estimated from computational studies using the G3MP2B3 composite method. To prove the identity of the compounds, the 1H and 13C spectra were determined by nuclear magnetic resonance (NMR), and the Raman spectra of the study compounds of this work were obtained. 相似文献
966.
This work reported the discovery of N-triflimide (NTf)-based zwitter-ionic liquids (ZILs) that exhibit UCST-type phase transitions in water, and their further structural optimization in fine-tuning polarity to ultimately afford newfangled thermosensitive materials carrying attractive and biocompatible Tc values that clearly demonstrated the true value of the tunability of ZIL structure. This research established that with non-aromatic, acyclic ZILs as small-molecule thermoresponsive materials, their mixing and de-mixing with water triggered by temperatures are entirely reversible. 相似文献
967.
环形光纤声发射传感器的相位调制特性研究 总被引:4,自引:0,他引:4
提出了一种基于光纤Sagnac干涉仪的环形传感器,用于固体表面传播的超声波的检测.这种传感器的特点是能够精确地检测由固体表面传播的超声波产生的微弱振动.当超声波信号通过光纤传感器的两个臂到达探测器时,干涉仪的输出光强度受到了超声信号的调制.通过检测干涉仪的输出光强度并利用Fourier变换,测得了超声信号的振幅和频率.而且对传感系统的位相调制特性进行了仿真,并对实验结果进行了分析,结果表明该系统可用于固体表面传播的超声波频率特征的识别. 相似文献
968.
Anele Mpupa Azile Nqombolo Boris Mizaikoff Philiswa Nosizo Nomngongo 《Molecules (Basel, Switzerland)》2022,27(1)
A β-cyclodextrin-decorated magnetic activated carbon adsorbent was prepared and characterized using various analytical techniques (X-ray diffraction (XRD), scanning electron microscopy–electron diffraction spectroscopy (SEM-EDS) and transmission electron microscopy (TEM)), and the adsorbent was used in the development of a magnetic solid-phase microextraction (MSPE) method for the preconcentration of estrone, β-estradiol, hydrocortisone and progesterone in wastewater and river water samples. This method was optimized using the central composite design in order to determine the experimental parameters affecting the extraction procedure. The quantification of hormones was achieved using high-performance liquid chromatography equipped with a photodiode array detector (HPLC-DAD). Under optimum conditions, the linearity ranged from 0.04 to 300 µg L−1 with a correlation of determinations of 0.9969–0.9991. The limits of detection and quantification were between 0.01–0.03 and 0.033–0.1 µg L−1, with intraday and interday precisions at 1.1–3.4 and 3.2–4.2. The equilibrium data were best described by the Langmuir isotherm model, and high adsorption capacities (217–294 mg g−1) were obtained. The developed procedure demonstrated high potential as an effective technique for use in wastewater samples without significant interferences, and the adsorbent could be reused up to eight times. 相似文献
969.
970.