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61.
Advances in the field of Femtosecond Stimulated Raman Spectroscopy (FSRS), a new time‐resolved structural technique that provides complete vibrational spectra on the ultrafast timescale, are reviewed. When coupled with a femtosecond optical trigger, the time evolution of a reacting species can be monitored with unprecedented <25 femtosecond temporal and 5 cm‐1 spectral resolution. New technological and theoretical advances including the development of tunable FSRS and a background‐free FSRS format are discussed. The most recent experimental studies focus on ultrafast reaction dynamics in electronically excited states: isomerization in cyanobacterial phytochrome, ultrafast spin flipping in a solar cell sensitizer, and excited state proton transfer in green fluorescent protein. The use of FSRS to directly map multidimensional reactive potential energy surfaces and to probe the mechanism of reactive internal conversion is prospectively discussed. 相似文献
62.
63.
D. Valenti L. Schimansky-Geier X. Sailer B. Spagnolo 《The European Physical Journal B - Condensed Matter and Complex Systems》2006,50(1-2):199-203
The dynamics of a spatially extended system of two competing
species in the presence of two noise sources is studied. A
correlated dichotomous noise acts on the interaction parameter and
a multiplicative white noise affects directly the dynamics of the
two species. To describe the spatial distribution of the species
we use a model based on Lotka-Volterra (LV) equations. By writing
them in a mean field form, the corresponding moment equations for
the species concentrations are obtained in Gaussian approximation.
In this formalism the system dynamics is analyzed for different
values of the multiplicative noise intensity. Finally by comparing
these results with those obtained by direct simulations of the
time discrete version of LV equations, that is coupled map lattice
(CML) model, we conclude that the anticorrelated oscillations of
the species densities are strictly related to non-overlapping
spatial patterns. 相似文献
64.
We present a review of our recent research in econophysics, and focus on the comparative study of Chinese and western financial markets. By virtue of concepts and methods in statistical physics, we investigate the time correlations and spatial structure of financial markets based on empirical high-frequency data. We discover that the Chinese stock market shares common basic properties with the western stock markets, such as the fat-tail probability distribution of price returns, the long-range auto-correlation of volatilities, and the persistence probability of volatilities, while it exhibits very different higher-order time correlations of price returns and volatilities, spatial correlations of individual stock prices, and large-fluctuation dynamic behaviors. Furthermore, multi-agent-based models are developed to simulate the microscopic interaction and dynamic evolution of the stock markets. 相似文献
65.
This paper is devoted to the study of the underlying linearities of the coupled
Harry--Dym (cHD) soliton hierarchy, including the well-known cHD equation. Resorting
to the nonlinearization of Lax pairs, a family of finite-dimensional Hamiltonian
systems associated with soliton equations are presented, constituting the
decomposition of the cHD soliton hierarchy. After suitably introducing the
Abel--Jacobi coordinates on a Riemann surface, the cHD soliton hierarchy can be
ultimately reduced to linear superpositions,
expressed by the Abel--Jacobi variables. 相似文献
66.
高成像质量Offner成像光谱仪的理论分析与研制 总被引:1,自引:0,他引:1
以双镜系统为基础构建了Offner成像光谱仪,并利用光程函数来获得一种Offner成像光谱仪的初始结构.通过光学设计软件Code V对该初始结构进行了仿真与优化,优化后的光谱仪具有高成像质量,其均方根点列图直径明显降低,调制传递函数曲线在子午像与弧矢像上都获得了好的成像效果.该研究免去了过于复杂的像差推导过程,并在宽光谱400~1 300nm条件下获得了具有高成像质量的Offner光谱仪结构,为光谱仪的搭建提供了理论基础. 相似文献
67.
Huang JR 《The European physical journal. E, Soft matter》2006,19(4):399-412
A new model is proposed to explain coiling of myelins composed of fluid bilayers. This model allows the constituent bilayer
cylinders of a myelin to be non-coaxial and the bilayer lateral tension to vary from bilayer to bilayer. The calculations
show that a myelin would bend or coil to lower its free energy when the bilayer lateral tension is sufficiently large. From
a mechanical point of view, the proposed coiling mechanism is analogous to the classical Euler buckling of a thin elastic
rod under axial compression. The analysis of a simple two-bilayer case suggests that a bilayer lateral tension of about 1
dyne/cm can easily induce coiling of myelins of typical lipid bilayers. This model signifies the importance of bilayer lateral
tension in determining the morphology of myelinic structures. 相似文献
68.
In this paper, we analyze the sum rate performance of multiuser multi-antenna downlink channel. We consider Rayleigh fading environment when regularized vector perturbation precoding (R-VPP) method is used at the transmitter. We derive expressions for the sum rate in terms of the variance of the received signal. We also provide a closed form approximation for the mean squared error (MSE) which is shown to work well for the whole range of SNR. Further, we also propose a simpler expression for R-VPP sum rate based on MSE. The simulation results show that the proposed expressions for R-VPP sum rate closely match the sum rate found by the entropy estimation. Our results show that when compared with other linear and non-linear precoding methods (like zero-forcing precoder, linear minimum mean square error (MMSE) precoder and VPP), R-VPP sum rate performance is very close to DPC for all SNR values. It is also noted that the sum rate performance of the linear MMSE precoder is very close to the R-VPP at low to medium SNR range. Finally we also compared the merits of performing regularization for VPP as compared to the greedy rate maximizing user scheduling. It turns out that the R-VPP with or without user selection performs better than the VPP systems with user selection. 相似文献
69.
Summary The purpose of this work is the numerical simulation of the ISO-LWS spectrometer output with a computer code aiming at obtaining
data similar as far as possible to those to be gained during the mission. With such data the processing and analysis programmes
will be tested in order to assess the instrument capabilities and limits. As an example we have simulated the realization
of a spectral and spatial map of the sky region with the outflow of L1551-IRS5.
Paper presented at the 6th Cosmic Physics National Conference, Palermo, 3–7 November 1992. 相似文献
70.
Thermoacoustic refrigerators have been developed during the last 15 years, employing quasi-standing resonant acoustic waves inside fluid-filled cavities to transfer heat along a stack region. Because higher efficiency can be reached when a significant travelling wave component exists in the resonator, specific resonant thermoacoustic devices have been designed allowing to adjust more or less the ratio of travelling and standing wave components. However, the acoustic pressure field and the particle velocity field do not appear to be the optimal ones, for the thermal quantities of interest. Thus, it is the aim of the paper to present a new kind of thermoacoustic standing wave-like device which allows to control easily and independently the pressure field and the particle velocity field, after investigating the optimal acoustic field, in the stack region, for the main parameters of interest, i.e. the temperature gradient, the thermoacoustic heat flow and the coefficient of performance. 相似文献