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61.
用转换器和IBMPC/XT微机与Dionex2020i型离子色谱仪连接组成自动控制与数据处理系统,转换器由8031及8255等芯片组成,其功能是采集数据和转送数据,软件由汇编及C语言编制。这套新系统增加了注入/记录同步,分级梯度淋洗,自动连续进样等功能以及很强的数据处理能力。 相似文献
62.
Results of permittivity measurements, electromagnetic interference shielding effectiveness, and heat generation due to microwave absorption in conducting polymer coated textiles are reported and discussed. The intrinsically conducting polymer, polypyrrole, doped with anthraquinone-2-sulfonic acid (AQSA) or para-toluene-2-sulfonic acid (pTSA) was applied on textile substrates and the resulting materials were investigated in the frequency range 1-18 GHz. The 0.54 mm thick conducting textile/polypyrrole composites absorbed up to 49.5% of the incident 30-35 W microwave radiation. A thermography station was used to monitor the temperature of these composites during the irradiation process, where absorption was confirmed via visible heat losses. Samples with lower conductivity showed larger temperature increases caused by microwave absorption compared to samples with higher conductivity. A sample with an average sheet resistivity of 150 Ω/sq. showed a maximum temperature increase of 5.27 °C, whilst a sample with a lower resistivity (105 Ω/sq.) rose by 3.85 °C. 相似文献
63.
Rudin M Mueggler T Allegrini PR Baumann D Rausch M 《Analytical and bioanalytical chemistry》2003,377(6):973-981
Modern drug development requires technologies that allow rapid translation from the preclinical to the clinical stage. It is obvious that non-invasive imaging modalities such as magnetic resonance imaging (MRI) will play a central role in this regard. This article reviews the use of structural and functional MRI readouts for characterization of central nervous system (CNS) disorders and evaluation of the efficacy of potential CNS drugs. Examples comprise dementia of Alzheimer's type, cerebral ischemia, and neuroinflammation covering both clinical and preclinical aspects. In these examples MRI has been used to obtain relevant structural information on brain atrophy, on the location and extent of ischemic brain areas, and on the number and distribution of demyelinated plaques. These structural data are complemented by readouts assessing the functional consequences associated with the pathomorphological changes. In the last decade, MRI has evolved into a standard tool for the development of CNS drugs. With regard to target-specific/molecular imaging applications MRI is limited by its inherently low sensitivity; complementary imaging modalities utilizing optical and radionuclear reporter systems will thus be required. 相似文献
64.
Masahiro Toyoda Yukio Hamaji Kunisaburo Tomono 《Journal of Sol-Gel Science and Technology》1997,9(1):71-84
The sol-gel processing was applied to the fabrication of PbTiO3 fibers. Pb(CH3COO)2·3H2O and Ti(OC3H
7
i
)4 were refluxed with stirring in 2-methoxyethanol to form Pb-methoxyethoxide and Ti-methoxyethoxide, respectively, followed
by mixing with stirring in 2-methoxyethanol to form Pb−Ti double alkoxide. The hydrolysis and polycondensation reaction of
this double alkoxide gave polymerized products, and as a result the viscosity of the solution increased, suggesting that linear
polymers were produced through the hydrolysis and polycondensation reaction. Homogeneous PbTiO3 gel fibers were drawn from the spinnable viscous solutions, which were wellcrystallized into perovskite type PbTiO3 at 650°C. The heat-treated fibers were a few centimeters long and from 10 to 100 μm in diameter. The fiber was made up of
extremely uniform grains. Electron diffraction revealed a preferred growth of (101) planes along the fiber axis, which might
be due to the linear molecular characteristics of the alkoxide. 相似文献
65.
顺磁性聚酯金属配合物的合成及其驰豫性能的研究 总被引:2,自引:0,他引:2
本文通过二乙三胺五乙酸(DTPA)或乙二胺四乙酸(EDTA)的双酸酐与二元醇或二元酚进行聚合反应,制备了两个系列共15种新的聚酯型大分子配体及其顺磁性金属配合物,用核磁、红外光谱以及元素分析表征了配体和配合物的结构。初步试验结果表明,与相应的小分子金属配合物相比,聚酯金属配合物具有较高的弛豫性能。 相似文献
66.
The photo‐initiated cationic polymerization (PCP) of epoxides using diaryliodonium salt photoacid generators (PAGs) bearing alkyl groups and anions was investigated. The properties and reactivities of a series of iodonium salts containing various cations and anions were compared in the context of a PCP reaction. The products from the decomposition of the cations of these salts were analyzed using gas chromatography‐mass spectrometry (GC‐MS) spectra. The relationship between the molecular structure of the salts and their reaction mechanism in the PCP reaction was investigated. Based on the results of the investigation, it was concluded that the structures of the cations and anions of theiodonium salts affect the PCP reaction rate, which was controlled by the products from the diaryliodonium salts. As part of an additional investigation, the diaryliodonium salts‐epoxide materials were applied to 254 nm‐photo‐patterning. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
67.
The gold nanoprisms (GNPs) have exhibited special plasmonic properties for biomedical applications because of their unique shapes and dimensions. Based on their optical performance, the NIR dye IR780 not only enabled the GNPs-based nanosystem as SERRS nanoparticles for Raman-encoded molecular imaging, but also enhanced the plasmonic photothermal property by laser irradiation. Meanwhile, the GNPs/IR780-Lyp-1 by introduction of tumor-homing peptide segment LyP-1, which presents high affinity to p32 protein, demonstrated the increased enrichment in tumor region and enhanced photothermal therapy efficacy. 相似文献
68.
研究了高效液相色谱-火焰原子吸收光谱联用系统分析信号处理方法,比较了各种处理方法的优缺点,用积分与适应平滑法综合处理色谱峰分析信号,不仅能有效地消除噪声,而且能使分析信号得到加强,以测定镍为例,经积分与适应平滑法综合处理后,检出限改善了2.7倍。 相似文献
69.
Sandip?HalderEmail author Theodor?Schneller Rainer?Waser 《Journal of Sol-Gel Science and Technology》2005,33(3):299-306
A new chemical solution deposition (CSD) route for the fabrication of Ba0.7Sr0.3TiO3 (BST) thin films has been developed which completely prevents the formation of an intermediate oxo-carbonate phase. The latter has been reported previously by several authors to be responsible for increased crystallization temperatures. Barium and strontium diaminoethoxides were synthesized starting from pure barium and strontium metal and aminoethanol. These alkoxides were found to be readily soluble in a wide range of solvents and thus were excellent candidates for the CSD process. To prepare a stable precursor solution the aminoalkoxides were dissolved in 2-butoxyethanol and then used for the deposition of BST thin films. We conclude that the minimum crystallization temperature of 600C to be independent of the formation of the oxo-carbonate phase. DTA-TGA were performed on the precursors and their solutions to study their decomposition behaviour. All films annealed at different temperatures were physically characterized by XRD, IR, and SEM. The films prepared by this route at 650C were found to have high dielectric constant and the leakage currents were comparable to BST films prepared by normal carboxylate based routes at 750C. 相似文献
70.
As a consequence
of their excellent barrier properties vinyl chloride/vinylidene chloride copolymers
have long been prominent in the flexible packaging market. While these polymers
possess a number of superior characteristics, they tend to undergo thermally-
induced degradative dehydrochlorination at process temperatures. This degradation
must be controlled to permit processing of the polymers. Three series of N-substituted
maleimides (N-alkyl-, N-aralkyl, and N-aryl) have been synthesized, characterized
spectroscopically, and evaluated as potential stabilizers for a standard vinyl
chloride/vinylidene chloride (85 mass%) copolymer. As surface blends with
the polymer, these compounds are ineffective as stabilizers. However, significant
stabilization may be achieved by pretreatment of the polymer with N-substituted
maleimides. The most effective stabilization of the polymer is afforded by
N-aralkyl- or N-arylmaleimides, most notably, N-benzylmaleimide and N-p-methoxyphenylmaleimide. 相似文献