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81.
Mohamed Cherif Gaixia Zhang Yang Gao Shuhui Sun Franois Vidal 《Molecules (Basel, Switzerland)》2022,27(6)
We use computational materials methods to study the sequential appearance of zinc-based zeolitic imidazolate frameworks (ZIFs) generated in the mechanochemical conversion process. We consider nine ZIF topologies, namely RHO, ANA, QTZ, SOD, KAT, DIA, NEB, CAG and GIS, combined with the two ligands 2-methylimidazolate and 2-ethylimidazolate. Of the 18 combinations obtained, only six (three for each ligand) were actually observed during the mechanosynthesis process. Energy and porosity calculations based on density functional theory, in combination with the Ostwald rule of stages, were found to be insufficient to distinguish the experimentally observed ZIFs. We then show, using classical molecular dynamics, that only ZIFs withstanding quasi-hydrostatic pressure P ≥ 0.3 GPa without being destroyed were observed in the laboratory. This finding, along with the requirement that successive ZIFs be generated with decreasing porosity and/or energy, provides heuristic rules for predicting the sequences of mechanically generated ZIFs for the two ligands considered. 相似文献
82.
83.
Comparing analytical and numerical solution of nonlinear two and three‐dimensional hydrostatic flows
New test cases for frictionless, three‐dimensional hydrostatic flows have been derived from some known analytical solutions of the two‐dimensional shallow water equations. The flow domain is a paraboloid of revolution and the flow is determined by the initial conditions, the nonlinear advective terms, the Coriolis acceleration and by the hydrostatic pressure. Wetting and drying is also included. Some specific properties of the exact solutions are discussed under different hypothesis and relative importance of the forcing terms. These solutions are proposed for testing the stability, the accuracy and the efficiency of numerical models to be used for simulating environmental hydrostatic flows. The computed solutions obtained with a semi‐implicit finite difference—finite volume algorithm on unstructured grid are compared with the corresponding analytical solutions in both two and three space dimension. Excellent agreement are obtained for the velocity and for the resulting water surface elevation. Comparison of the computed inundation area also shows a good agreement with the analytical solution with degrading accuracy observed when the inundation area becomes relatively large and for long simulation time. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
84.
A numerical technique is presented for the approximation of vertical gradient of the non‐hydrostatic pressure arising in the Reynolds‐averaged Navier–Stokes equations for simulating non‐hydrostatic free‐surface flows. It is based on the Keller‐box method that take into account the effect of non‐hydrostatic pressure with a very small number of vertical grid points. As a result, the proposed technique is capable of simulating relatively short wave propagation, where both frequency dispersion and non‐linear effects play an important role, in an accurate and efficient manner. Numerical examples are provided to illustrate this; accurate wave characteristics are already achieved with only two layers. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
85.
86.
Abstract The main requirements of the quality of products are the homogeneity of technological and service properties, the improved characteristics of strength and plasticity, endurance and brittle failure resistance. In recent years many investigations into developing the High Hydrostatic Pressure Technologies (HHPT) and equipment to meet these requirements have been carried out by scientific schools of Academicians, L. F. Vereshchagin, G. V. Kurdyumov, A. I. Tselikov and A. A. Galkin in the USSR. The physical basis of these technologies is represented by the plastic deformation effects under high pressure: material plasticization’, strain ageing2, decrease of a carbide inhomogeneity3, use of a liquid as a machining tool4 etc. HHPT are widely spread and especially promising in metallurgy as the ferrous metals account for more than 96% of the total structural material consumption in machine building, while assortment of products is about 5000 profile sizes of bars, 30 000 profile sizes of tubes, 50 000 types of metalware. 相似文献
87.
Abstract Two high pressure X-band ESR resonators for sensitive measurements are described. Both systems have 100 kHz internal modulation coils and can cooperate with any standard ESR spectrometer. These cavities operate in two different temperature and pressure ranges: 77–400 K, up to 0.8 GPa and liquid helium temperature range, up to 1 GPa, respectively. Additionally, the cavity operating in the 77–400 K temperature range enables Photo-ESR measurements to be carried out. 相似文献
88.
Abstract Effect of hydrostatic pressure up to 250 MPa on structurization kinetics and morphology of network polymers based on epoxy oligomers has been studied using the methods of measurements of resistivity and optical microscopy. 相似文献
89.
Abstract An attempt is made to formulate the physical causes of the solid body plastification at deformation under high hydrostatic pressures. The nature of critical pressures above which the character of the given process changes qualitatively is discussed in this work. 相似文献
90.
Abstract Effect of hydrostatic pressure up to 250 MPa on structurization kinetics and morphology of network polymers based on epoxy oligomers has been studied using the methods of measurements of volume resistivity and optical microscopy. 相似文献